Spectral emission of flames from laboratory-scale vegetation fires

2009 ◽  
Vol 18 (7) ◽  
pp. 875 ◽  
Author(s):  
P. Boulet ◽  
G. Parent ◽  
A. Collin ◽  
Z. Acem ◽  
B. Porterie ◽  
...  

Outdoor experiments were conducted on a laboratory scale to study the infrared radiation emission of vegetation flames. Measurements were made in the spectral range 1000–4500 cm–1, using a compact and portable Fourier-transform infrared spectrometer including an HgCdTe/InSb dual detector. Flame emission was compared with the reference signal emitted by a blackbody surface at 1000 K. We carried out two different series of fire experiments: a series of fires in a 0.45 m-diameter steel tray and a series of wind-tunnel fires. Various types of wildland fuels were used: wood wool, vine branches, dry wood, and Kermes oak branches. From a qualitative observation of emission spectra, it appears that the main contribution comes from the hot gaseous combustion products, with a low-intensity background radiation from soot, as the small-scale flames in these experiments were optically thin. It was also found that, in the flaming combustion zone of the fuel bed, both phases contribute to infrared emission. Our results, in combination with existing data on the absorptivity of vegetation, give a better understanding of radiative transfer in vegetation fires and show how total radiative properties could be deduced from spectral measurements. We believe that this preliminary study provides pilot data for future studies in this area.

1996 ◽  
Vol 254 (3-4) ◽  
pp. 197-202 ◽  
Author(s):  
Kenneth J. Smit ◽  
Leo V. De Yong ◽  
Rodney Gray

1997 ◽  
Vol 51 (9) ◽  
pp. 1400-1404 ◽  
Author(s):  
Kenneth J. Smit ◽  
Ronald J. Hancox ◽  
David J. Hatt ◽  
Shane P. Murphy ◽  
Leo V. De Yong

Measurement of infrared emission spectra for boron-based pyrotechnic combustion has enabled the elucidation of a number of boron oxidation products. The raw spectra were corrected for instrument responsivity and atmospheric attenuation for the region 1500 to 3000 cm−1. The alkali metal metaborates and boron oxide (B2O3) were among the principal combustion products depending on which of three different oxidants were used. In addition, thermochemical modeling studies were undertaken on each composition to predict the combustion products. The thermochemical modeling data were qualitatively in agreement with the identified combustion products.


1992 ◽  
Vol 46 (11) ◽  
pp. 1673-1684 ◽  
Author(s):  
Yunke Zhang ◽  
Marianna A. Busch ◽  
Kenneth W. Busch

A computer-controlled, dispersive, scanning spectrometer with a wavelength range from 1 to 15 μm is described and used to study the flame/furnace infrared emission (FIRE) spectra of combustion products formed in a small analyte/air flame and in an electrically heated furnace (570°C), operated with and without a column of heated hopcalite (370°C). When lead selenide was used as the detector, the emission spectra of the combustion products of pentane, benzene, dichloromethane, and methanol could be measured over the wavelength range from 2 to 5 μm. In addition to discrete emission bands from terminal combustion products such as CO2, H2O, and HCl, discrete emission from CO (4.6–4.9 μm) and continuum emission associated with soot formation were also observed under oxygen-limited combustion of benzene, dichloromethane, and possibly pentane. Bands centered at approximately 3.3 μm (3030 cm−1) and 3.5 μm (2857 cm−1) were observed in several spectra and attributed to C-H stretching in intermediate combustion products, with the 3.5- μm band being assigned to the stretching of the carbonyl hydrogen of aldehydes (formaldehyde, in particular). On the basis of these results, the “anomalous emission” observed at 3.8 μm in previous studies employing electrothermal excitation is attributed either to the presence of formaldehyde or to the formation of particulate carbon, which are both associated with conditions favoring the incomplete combustion of hydrocarbons.


1975 ◽  
Vol 29 (6) ◽  
pp. 496-500 ◽  
Author(s):  
D. Kember ◽  
N. Sheppard

Infrared emission spectra from metal samples with oxide surface layers are shown to be very advantageously studied using the spectrum-ratioing facility of a recording infrared interferometer. The emission from a given sample is ratioed against that from a black-body emitter at the same temperature so as to give emittance as a function of wavenumber directly. This method has very useful application to irregularly shaped metal emitters. In the absence of selective reflection there is a direct correspondence between emission and absorption spectra for thin layers of an emitting substance. However, the presence of selective reflection leads to reduced emission and to considerable differences in the appearance of “absorption” and emission spectra in regions of strong absorption. Emission spectra obtained from copper plates heated, above 150°C, for different periods in air are shown clearly to indicate the presence of cuprous, Cu(I), and cupric, Cu(II), oxides in the surface layer.


2003 ◽  
Vol 118 (8) ◽  
pp. 3622-3627 ◽  
Author(s):  
A. Shayesteh ◽  
K. Tereszchuk ◽  
P. F. Bernath ◽  
R. Colin

1981 ◽  
Vol 103 (1) ◽  
pp. 65-73 ◽  
Author(s):  
V. W. King ◽  
J. L. Lauer

Partial and complete emission band reversals have been observed in the infrared emission spectra from portions of operating sliding contacts. An elementary analysis has been carried out to show that partial reversals are due to temperature gradients in the fluid film—the film acts both as a radiation-emitter and absorber, and that total reversals—an emission spectrum appears as an absorption spectrum—are likely to be due to a continuum source, such as hot solid asperities. The total energy radiated under the latter conditions exceeds that under the others. A decrease in gap width with increased load was accompanied by a dramatic spectral change in the case of 5P4E polyphenyl ether, which is indicative of molecular alignment.


2013 ◽  
Vol 17 (4) ◽  
pp. 1093-1106 ◽  
Author(s):  
Soraya Trabelsi ◽  
Wissem Lakhal ◽  
Ezeddine Sediki ◽  
Mahmoud Moussa

Combined convection and radiation in simultaneously developing laminar flow and heat transfer is numerically considered with a discrete-direction method. Coupled heat transfer in absorbing emitting but not scattering gases is presented in some cases of practical situations such as combustion of natural gas, propane and heavy fuel. Numerical calculations are performed to evaluate the thermal radiation effects on heat transfer through combustion products flowing inside circular ducts. The radiative properties of the flowing gases are modeled by using the absorption distribution function (ADF) model. The fluid is a mixture of carbon dioxide, water vapor, and nitrogen. The flow and energy balance equations are solved simultaneously with temperature dependent fluid properties. The bulk mean temperature variations and Nusselt numbers are shown for a uniform inlet temperature. Total, radiative and convective mean Nusselt numbers and their axial evolution for different gas mixtures produced by combustion with oxygen are explored.


2020 ◽  
pp. 95-102
Author(s):  
M. Basire ◽  
P. Parneix ◽  
T. Pino ◽  
Ph. Bréchignac ◽  
F. Calvo

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