Cation-Exchange Study on a Crystalline and Thermally Stable Phase of Antimony Silicate. Effect of Irradiation on Ion-Exchange Behavior and Separation of Cd(II) from Zn(II) and Mn(II) and of Mg(II) from Ba(II), Ca(II), and Sr(II)

1982 ◽  
Vol 17 (13-14) ◽  
pp. 1527-1543 ◽  
Author(s):  
K. G. Varshney ◽  
Uma Sharma ◽  
Sima Rani ◽  
A. Premadas
Membranes ◽  
2021 ◽  
Vol 11 (3) ◽  
pp. 217
Author(s):  
AHM Golam Hyder ◽  
Brian A. Morales ◽  
Malynda A. Cappelle ◽  
Stephen J. Percival ◽  
Leo J. Small ◽  
...  

Electrodialysis (ED) desalination performance of different conventional and laboratory-scale ion exchange membranes (IEMs) has been evaluated by many researchers, but most of these studies used their own sets of experimental parameters such as feed solution compositions and concentrations, superficial velocities of the process streams (diluate, concentrate, and electrode rinse), applied electrical voltages, and types of IEMs. Thus, direct comparison of ED desalination performance of different IEMs is virtually impossible. While the use of different conventional IEMs in ED has been reported, the use of bioinspired ion exchange membrane has not been reported yet. The goal of this study was to evaluate the ED desalination performance differences between novel laboratory‑scale bioinspired IEM and conventional IEMs by determining (i) limiting current density, (ii) current density, (iii) current efficiency, (iv) salinity reduction in diluate stream, (v) normalized specific energy consumption, and (vi) water flux by osmosis as a function of (a) initial concentration of NaCl feed solution (diluate and concentrate streams), (b) superficial velocity of feed solution, and (c) applied stack voltage per cell-pair of membranes. A laboratory‑scale single stage batch-recycle electrodialysis experimental apparatus was assembled with five cell‑pairs of IEMs with an active cross-sectional area of 7.84 cm2. In this study, seven combinations of IEMs (commercial and laboratory-made) were compared: (i) Neosepta AMX/CMX, (ii) PCA PCSA/PCSK, (iii) Fujifilm Type 1 AEM/CEM, (iv) SUEZ AR204SZRA/CR67HMR, (v) Ralex AMH-PES/CMH-PES, (vi) Neosepta AMX/Bare Polycarbonate membrane (Polycarb), and (vii) Neosepta AMX/Sandia novel bioinspired cation exchange membrane (SandiaCEM). ED desalination performance with the Sandia novel bioinspired cation exchange membrane (SandiaCEM) was found to be competitive with commercial Neosepta CMX cation exchange membrane.


1977 ◽  
Vol 23 (10) ◽  
pp. 1921-1924 ◽  
Author(s):  
G J Alexander ◽  
S Machiz

Abstract A convenient screening procedure for presence of drugs of abuse in urine consists of two steps: adsorption of the drugs from urine onto a paper loaded with cation-exchange resin and detection of the adsorbed drugs by direct radioimmunoassay. The first step can be performed in the field, the second in a central laboratory. Storage and transport to the laboratory are simplified because specimens adsorbed on dried paper are stable and can be sent in letter-mail. In the laboratory, a small disc of the ion-exchange paper is exposed to antigen and antibody, rinsed, and tested for radioactivity. Discs treated with positive urines are more radioactive than discs from negative urines.


2008 ◽  
Vol 45 (4) ◽  
pp. 281-288 ◽  
Author(s):  
Jaimin R. Patel ◽  
Mitesh G. Patel ◽  
Hetal J. Patel ◽  
Kirit H. Patel ◽  
Rajni M. Patel

2021 ◽  
Vol 17 ◽  
Author(s):  
Amita Somya ◽  
Mamata Singh

Background: With increasing population and decreased quality of drinking water, there is a great demand for the development of new materials and methods that can find applications in the purification of water. This paper presents our small effort from pollution to solution by presenting the synthesis method of new sodium lauryl sulphate supported thorium(IV) phosphate, its characterization, and disquisition of analytical applications by executing some dual separations of calcium. Methods: Sodium lauryl sulphate thorium(IV) phosphate was synthesized by sol gel method. The synthesized exchanger was characterized by some physico-chemical studies like powdered X-ray diffraction, Scanning electron microscopy, Thermo gravimetric-differential thermal analysis, EDAX and Fourier transform-infrared study and was also checked for its competency towards the ion exchange processes and in analytical chemistry. Results: The prominent characteristic of Sodium lauryl sulphate supported Thorium(IV) phosphate has been its tremendously high ion exchange capacity for sodium ions (3.10 meq/g) which is almost two and half times more than the exchange capacity of Thorium(IV) phosphate (ThP), i.e., 1.3 meq/g. The material was resulted in fibrous sheet which is quite thermally, mechanically stable and poorly crystalline. The material has shown selectivity towards Ca2+ and Hg2+ ions. Conclusion: The synthesized cation exchange material has been found quite thermally stable, showing drastically high exchange capacity and selectivity towards Hg2+ and Ca2+ metal ions which might be because of the use of an anionic surfactant, sodium lauryl sulphate while synthesis of Th(IV) phosphate which has played a key role in enhancing the exchange capacity and adsorption of specific metals as well. Therefore, based on the results obtained, the above said materials can find applications in water purification processes and also, in environmental pollution control where removal of Hg2+ and Ca2+ is required.


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