Linking chloride mass balance infiltration rates with chlorofluorocarbon and SF6groundwater dating in semi-arid settings: potential and limitations

2010 ◽  
Vol 46 (3) ◽  
pp. 312-324 ◽  
Author(s):  
Susanne Stadler ◽  
Karsten Osenbrück ◽  
Wilhelmus H.M. Duijnisveld ◽  
Martin Schwiede ◽  
Jürgen Böttcher
2018 ◽  
Author(s):  
Ferdinando Manna ◽  
Steven Murray ◽  
Daron Abbey ◽  
Paul Martin ◽  
John Cherry ◽  
...  

Abstract. With the aim to understand the spatial and temporal variability of groundwater recharge, a high-resolution, spatially-distributed numerical model (MIKE SHE) representing surface water and groundwater was used to simulate responses to precipitation in a 2.16 km2 upland catchment on fractured sandstone near Los Angeles, California. Exceptionally high temporal and spatial resolution was used for this catchment modeling: an hourly time-step, a 20 × 20 meter grid in the horizontal plane and 240 numerical layers distributed vertically within the thick vadose zone and in the upper part of the groundwater zone. The finest-practical spatial and temporal resolution were selected to accommodate the large degree of surface and subsurface variability of catchment features. Physical property values for the different lithologies were assigned based on previous on-site investigations whereas the parameters controlling streamflow and evapotranspiration were derived from literature information. The calibration of streamflow at the outfall and of transient and average hydraulic head provided confidence in the reasonableness of these input values and in the ability of the model to reproduce observed processes. Confidence in the calibrated model was enhanced by validation through, (i) comparison of simulated average recharge to estimates based on the applications of the chloride mass-balance method from data from the groundwater and vadose zones within and beyond the catchment (Manna et al., 2016; Manna et al., 2017) and, (ii) comparison of the water isotope signature (18O and 2H) in shallow groundwater to the variability of isotope signatures for precipitation events over an annual cycle. The average simulated recharge across the catchment for the period 1995–2014 is 16 mm y−1 (4 % of the average annual precipitation), which is consistent with previous estimates obtained by using the chloride mass balance method (4.2 % of the average precipitation). However, one of the most unexpected results was that local recharge was simulated to vary from 0 to > 1000 mm y−1 due to episodic precipitation and overland runoff effects. This recharge occurs episodically with the major flux events at the bottom of the evapotranspiration zone, as simulated by MIKE SHE and confirmed by the isotope signatures, occurring only at the end of the rainy season. This is the first study that combines MIKE SHE simulations with the analysis of water isotopes in groundwater and rainfall to determine the timing of recharge processes in semi-arid regions. The study advances the understanding of recharge and unsaturated flow processes in semi-arid regions and enhances our ability to predict the effects of surface and subsurface features on recharge rates. This is crucial in highly heterogeneous contaminated sites because different contaminant source areas have widely varying recharge and, hence, groundwater fluxes impacting their mobility.


2010 ◽  
Vol 45 (4) ◽  
pp. 451-461 ◽  
Author(s):  
Nandana Perera ◽  
Bahram Gharabaghi ◽  
Peter Noehammer ◽  
Bruce Kilgour

Abstract Occurrence of increasing chloride concentrations in urban streams of cold climates, mainly due to road salt application, has raised concerns on its adverse effects on aquatic and terrestrial ecosystems. Therefore, there is a need for a better understanding of processes associated with road salt application and subsequent discharge into the environment in order to develop management practices to minimize detrimental effects of chlorides. The chloride mass analysis for the Highland Creek watershed based on four years of hourly monitoring data indicates that approximately 60% of the chlorides applied on the watershed enter streams prior to subsequent salting period, 85% of which occurs during the period between November and March. Contribution of private de-icing operations on chloride mass input within Highland Creek watershed was estimated to be approximately 38%, indicating its significance in overall chloride mass balance. Salt application rates, as well as chloride output in the streams, vary spatially based on land use, influencing chloride concentrations in surface waters. The estimated groundwater chloride concentration of 275 mg/L indicates that some aquatic organisms in Highland Creek would potentially be at risk even outside the winter period under dry weather flow conditions.


2012 ◽  
Vol 16 (9) ◽  
pp. 3293-3307 ◽  
Author(s):  
M. J. Rossi ◽  
J. O. Ares

Abstract. Water infiltration and overland flow are relevant in considering water partition among plant life forms, the sustainability of vegetation and the design of sustainable hydrological models and management. In arid and semi-arid regions, these processes present characteristic trends imposed by the prevailing physical conditions of the upper soil as evolved under water-limited climate. A set of plot-scale field experiments at the semi-arid Patagonian Monte (Argentina) were performed in order to estimate the effect of depression storage areas and infiltration rates on depths, velocities and friction of overland flows. The micro-relief of undisturbed field plots was characterized at z-scale 1 mm through close-range stereo-photogrammetry and geo-statistical tools. The overland flow areas produced by controlled water inflows were video-recorded and the flow velocities were measured with image processing software. Antecedent and post-inflow moisture were measured, and texture, bulk density and physical properties of the upper soil were estimated based on soil core analyses. Field data were used to calibrate a physically-based, mass balanced, time explicit model of infiltration and overland flows. Modelling results reproduced the time series of observed flow areas, velocities and infiltration depths. Estimates of hydrodynamic parameters of overland flow (Reynolds-Froude numbers) are informed. To our knowledge, the study here presented is novel in combining several aspects that previous studies do not address simultaneously: (1) overland flow and infiltration parameters were obtained in undisturbed field conditions; (2) field measurements of overland flow movement were coupled to a detailed analysis of soil microtopography at 1 mm depth scale; (3) the effect of depression storage areas in infiltration rates and depth-velocity friction of overland flows is addressed. Relevance of the results to other similar desert areas is justified by the accompanying biogeography analysis of similarity of the environment where this study was performed with other desert areas of the world.


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