The Amount of Organic Matter, Kerogen Type, and Source Rock Potential of Bituminous Shales (Beydili, Nallıhan/Turkey)

2014 ◽  
Vol 32 (16) ◽  
pp. 2020-2030
Author(s):  
D. Koca ◽  
A. Sarı
GeoArabia ◽  
2005 ◽  
Vol 10 (4) ◽  
pp. 17-34
Author(s):  
Fowzia H. Abdullah ◽  
Bernard Carpentier ◽  
Isabelle Kowalewski ◽  
Frans van Buchem ◽  
Alain-Yves Huc

ABSTRACT The purpose of this study is to identify the source rock, reservoirs and nonproductive zones in the Lower Cretaceous Mauddud Formation in Kuwait, using geochemical methods. This formation is one of the major Cretaceous oil reservoirs. It is composed mainly of calcarenitic limestone interbedded with marl and glauconitic sands. Its thickness ranges from almost zero in the south to about 100 m (328 ft) in the north. A total of 99 core samples were collected from six oil fields in Kuwait: Raudhatain, Sabiriyah and Bahra in the north, and from the Burgan, Ahmadi and Magwa in the south. Well logs from these fields (gamma ray GR, sonic, resistivity, density) were correlated and used in the study. The core samples were screened for the amount and nature of the organic matter by Rock-Eval 6 pyrolysis (RE6) using reservoir mode. A set of samples was selected to study the properties of the organic matter including the soluble and insoluble organic parts. The geochemical characterisation was performed using different methods. After organic solvent extraction of rock samples, the solvent soluble organic matter or bitumen was characterised in terms of saturates, aromatics and heavy compounds (resins and asphaltenes). Then the hydrocarbon distribution of saturates was studied using gas chromatography (GC/FID) and gas chromatography-mass spectrometry (GC/MS) for tentative oil-source rock correlation. After mineral matrix destruction of previously extracted rocks, insoluble organic matter or kerogen was analysed for its elemental composition to identify kerogen type. The geology and the analytical results show similarities between the wells in the southern fields and the wells in the northern fields. Average Total Organic Matter (TOC) in the carbonate facies is 2.5 wt.% and the highest values (8.0 wt.%) are in the northern fields. The clastic intervals in the northern fields show higher total organic matter (1.3 wt.%) relative to the southern fields (0.6 wt.%). The total Production Index is higher in the carbonate (0.6) than the clastic section (0.3). This reflects the amount of extractable hydrocarbons, which are usually associated with the carbonate section in this formation, representing its reservoir section. Although the carbonate rocks are dominated by richer total organic matter, there are some intervals, with low total organic matter values (0.07 wt.%), representing its poor reservoir sections. The kerogen type varies between type II-III and III in the shales with a slightly better quality in the carbonate section. It is immature in almost all the studied fields. The composition of the rock extract has no relation with the rock type. Some sandstone show similar extract composition to the carbonate rocks in the reservoir intervals. The extracts from these intervals show different genetic nature than those in the shales. The maturity level in the reservoir extract is much higher than in the shale intervals. Thus, the oil accumulated in the reservoir might be largely related to migrated oil from a more mature source rock deposited in a clearly different environment than the associated shaly intervals. The best candidates being a more deeply buried Early Cretaceous Sulaiy Formation and Upper Jurassic Najmah Formation.


2018 ◽  
Vol 5 (1) ◽  
pp. 8-14
Author(s):  
Jan I. Ismael

In this study, organic geochemical characteristics and potential of Upper Oxfordian–Lower Kimmeridgian aged bituminous shale beds in Naokelekan formation (North Iraq) were investigated by using TOC and pyrolysis analyses. The Total Organic Carbon (TOC) contents for the studied samples varying between from 0.46-21.33%, average 7.06% and Taq Taq-1 well as good hydrocarbon potential (0.85-1.66 %, with average of 1.06%), whereas Jk-1 well can be rated as an very good hydrocarbon potential from 1.04-4.16 %, with average of 2.15 %. The low Hydrogen Index (HI = 24-605 mg HC/g TOC) for Bj-1 well, (HI = 147-673 mg HC/g TOC) in the Jk-1 well while in Taq Taq-1 well (HI = 9-48 mg HC/g TOC) indicate that kerogen type for the vast majority of the studied samples is Type II/I for Bj-1 well and Type IV with few samples, Type of I and II kerogens in the Taq Taq-1 and Jk-1 well. Consequently most of the organic matter of Bj-1 and Jk-1 well tends to generate petrol, even though a small portion of them exhibit a tendency to generate gas. While all samples of Taq Taq-1 well tends to generate gas. The studied bituminous rock samples characterized by low Tmax (434-602 °C) for Bj-1,Taq Taq-1 (344-429 °C) and (419-602 °C) for Jk-1 well. These values show, in terms of potential of hydrocarbon generation, that the studied samples have a source rock potential of organic matter from immature to over mature. Additionally, the S1 hydrocarbon type values indicate no external contribution of migrated hydrocarbons to the bituminous rocks of the studied area.


GeoArabia ◽  
2002 ◽  
Vol 7 (4) ◽  
pp. 675-696
Author(s):  
Mohamed I. A. Ibrahim ◽  
Hamad Al-Saad ◽  
Suzan E. Kholeif

ABSTRACT Strontium isotope, palynological, and total organic carbon (TOC) analyses were made on core samples from the Izhara, Araej, and Hanifa formations of three wells in onshore Qatar. Eleven samples were analyzed for their 87Sr/86Sr ratios. The results gave a chronostratigraphic range of Early Jurassic (Hettangian) to Late Jurassic (Oxfordian), with an overall age range of 202.4 Ma to 157.8 Ma. Maximum flooding surfaces MFS J10 to MFS J50 occur in the Izhara, Araej, and Hanifa formations. The organic matter in the carbonate sediments of the Izhara, Araej, and Hanifa formations was almost exclusively of marine algal origin dominated by marine microplankton. Organic matter obtained from the Izhara Formation was mature to over-mature kerogen type-III to IV, gas-prone to inert material (mean TOC 0.31%). In the Araej Formation, mature oil-prone and gas-prone kerogen type-II and type-III organic matter occurred in both the lower and upper Araej members (TOC 0.13-0.69%). The stylolitic limestone of the Uwainat member of the Araej Formation has poor potential as a source rock for petroleum (TOC 0.03-0.13%), but is considered to be the main reservoir rock of the Middle Jurassic in Qatar. Mature, highly oil-prone organic matter (type-I and type-II kerogen) was present in black limestone of the Hanifa Formation (mean TOC 0.60%; maximum 0.93%). The limestone is considered to be the most likely petroleum source rock for the underlying and overlying limestone reservoirs of the Uwainat member of the Araej Formation (Bathonian) and the Arab-D member of the Arab Formation (Kimmeridgian) units, respectively.


Author(s):  
S., R. Muthasyabiha

Geochemical analysis is necessary to enable the optimization of hydrocarbon exploration. In this research, it is used to determine the oil characteristics and the type of source rock candidates that produces hydrocarbon in the “KITKAT” Field and also to understand the quality, quantity and maturity of proven source rocks. The evaluation of source rock was obtained from Rock-Eval Pyrolysis (REP) to determine the hydrocarbon type and analysis of the value of Total Organic Carbon (TOC) was performed to know the quantity of its organic content. Analysis of Tmax value and Vitrinite Reflectance (Ro) was also performed to know the maturity level of the source rock samples. Then the oil characteristics such as the depositional environment of source rock candidate and where the oil sample develops were obtained from pattern matching and fingerprinting analysis of Biomarker data GC/GCMS. Moreover, these data are used to know the correlation of oil to source rock. The result of source rock evaluation shows that the Talangakar Formation (TAF) has all these parameters as a source rock. Organic material from Upper Talangakar Formation (UTAF) comes from kerogen type II/III that is capable of producing oil and gas (Espitalie, 1985) and Lower Talangakar Formation (LTAF) comes from kerogen type III that is capable of producing gas. All intervals of TAF have a quantity value from very good–excellent considerable from the amount of TOC > 1% (Peters and Cassa, 1994). Source rock maturity level (Ro > 0.6) in UTAF is mature–late mature and LTAF is late mature–over mature (Peters and Cassa, 1994). Source rock from UTAF has deposited in the transition environment, and source rock from LTAF has deposited in the terrestrial environment. The correlation of oil to source rock shows that oil sample is positively correlated with the UTAF.


2021 ◽  
Vol 18 (2) ◽  
pp. 398-415
Author(s):  
He Bi ◽  
Peng Li ◽  
Yun Jiang ◽  
Jing-Jing Fan ◽  
Xiao-Yue Chen

AbstractThis study considers the Upper Cretaceous Qingshankou Formation, Yaojia Formation, and the first member of the Nenjiang Formation in the Western Slope of the northern Songliao Basin. Dark mudstone with high abundances of organic matter of Gulong and Qijia sags are considered to be significant source rocks in the study area. To evaluate their development characteristics, differences and effectiveness, geochemical parameters are analyzed. One-dimensional basin modeling and hydrocarbon evolution are also applied to discuss the effectiveness of source rocks. Through the biomarker characteristics, the source–source, oil–oil, and oil–source correlations are assessed and the sources of crude oils in different rock units are determined. Based on the results, Gulong and Qijia source rocks have different organic matter primarily detrived from mixed sources and plankton, respectively. Gulong source rock has higher thermal evolution degree than Qijia source rock. The biomarker parameters of the source rocks are compared with 31 crude oil samples. The studied crude oils can be divided into two groups. The oil–source correlations show that group I oils from Qing II–III, Yao I, and Yao II–III members were probably derived from Gulong source rock and that only group II oils from Nen I member were derived from Qijia source rock.


Author(s):  
Sebastian Grohmann ◽  
Susanne W. Fietz ◽  
Ralf Littke ◽  
Samer Bou Daher ◽  
Maria Fernanda Romero-Sarmiento ◽  
...  

Several significant hydrocarbon accumulations were discovered over the past decade in the Levant Basin, Eastern Mediterranean Sea. Onshore studies have investigated potential source rock intervals to the east and south of the Levant Basin, whereas its offshore western margin is still relatively underexplored. Only a few cores were recovered from four boreholes offshore southern Cyprus by the Ocean Drilling Program (ODP) during the drilling campaign Leg 160 in 1995. These wells transect the Eratosthenes Seamount, a drowned bathymetric high, and recovered a thick sequence of both pre- and post-Messinian sedimentary rocks, containing mainly marine marls and shales. In this study, 122 core samples of Late Cretaceous to Messinian age were analyzed in order to identify organic-matter-rich intervals and to determine their depositional environment as well as their source rock potential and thermal maturity. Both Total Organic and Inorganic Carbon (TOC, TIC) analyses as well as Rock-Eval pyrolysis were firstly performed for the complete set of samples whereas Total Sulfur (TS) analysis was only carried out on samples containing significant amount of organic matter (>0.3 wt.% TOC). Based on the Rock-Eval results, eight samples were selected for organic petrographic investigations and twelve samples for analysis of major aliphatic hydrocarbon compounds. The organic content is highly variable in the analyzed samples (0–9.3 wt.%). TS/TOC as well as several biomarker ratios (e.g. Pr/Ph < 2) indicate a deposition under dysoxic conditions for the organic matter-rich sections, which were probably reached during sporadically active upwelling periods. Results prove potential oil prone Type II kerogen source rock intervals of fair to very good quality being present in Turonian to Coniacian (average: TOC = 0.93 wt.%, HI = 319 mg HC/g TOC) and in Bartonian to Priabonian (average: TOC = 4.8 wt.%, HI = 469 mg HC/g TOC) intervals. A precise determination of the actual source rock thickness is prevented by low core recovery rates for the respective intervals. All analyzed samples are immature to early mature. However, the presence of deeper buried, thermally mature source rocks and hydrocarbon migration is indicated by the observation of solid bitumen impregnation in one Upper Cretaceous and in one Lower Eocene sample.


Georesursy ◽  
2021 ◽  
Vol 23 (4) ◽  
pp. 66-72
Author(s):  
R.S. Khisamov ◽  
Natalia Skibitskaya ◽  
Nikita Samokhvalov ◽  
Kazimir Kovalenko ◽  
Oleg Navrotsky

This study introduces results of lithological, petrophysical and geochemical investigation of Lower Cretaceous (K1) and Middle Jurassic (J2a-b) rocks of East Pre-Caucasian basin. According to pyrolytic and bituminological studies method of separate determination of kerogen and bitumen concentration been developed. In accordance with this method differentiation of organic matter components in different lithotypes of rocks been described. Also relationship between bitumen and kerogen concentrations been revealed. The majority of samples have poor to fair organic richness and poor source potential. Kerogen type is commonly presented by type III and stages of maturity characterized by stages PC3 to MC3. Bitumen compounds have low concentrations of asphaltenes and aromatic hydrocarbons and mainly contains light and heavy resins. Based on petrophysical and geochemical studies a close relationship between the concentration of organic carbon and the weight concentration of potassium nuclides was obtained. This relationship indicates that kerogen in the sediments under consideration is associated with clay minerals, which is also confirmed by the mineral composition of the rocks.


2006 ◽  
Vol 23 (2) ◽  
pp. 261-279 ◽  
Author(s):  
Leszek Marynowski ◽  
Aleksandra Gawe¸da ◽  
Paweł Poprawa ◽  
Michał M. Zywiecki ◽  
Beata Ke¸pińska ◽  
...  

2018 ◽  
Vol 36 (5) ◽  
pp. 1157-1171
Author(s):  
Agostinho Mussa ◽  
Deolinda Flores ◽  
Joana Ribeiro ◽  
Ana MP Mizusaki ◽  
Mónica Chamussa ◽  
...  

The Mozambique Basin, which occurs onshore and offshore in the central and southern parts of Mozambique, contains a thick sequence of volcanic and sedimentary rocks that range in age from the Jurassic to Cenozoic. This basin, along with the Rovuma basin to the north, has been the main target for hydrocarbon exploration; however, published data on hydrocarbon occurrences do not exist. In this context, the present study aims to contribute to the understanding of the nature of the organic matter of a sedimentary sequence intercepted by the Nemo-1X exploration well located in the offshore area of the Mozambique Basin. The well reached a depth of 4127 m, and 33 samples were collected from a depth of 2219–3676 m ranging in age from early to Late Cretaceous. In this study, petrographic and geochemical analytical methods were applied to assess the level of vitrinite reflectance and the organic matter type as well as the total organic carbon, total sulfur, and CaCO3 contents. The results show that the total organic carbon content ranges from 0.41 to 1.34 wt%, with the highest values determined in the samples from the Lower Domo Shale and Sena Formations, which may be related to the presence of the solid bitumens that occur in the carbonate fraction of those samples. The vitrinite random reflectances range from 0.65 to 0.86%Rrandom, suggesting that the organic matter in all of the samples is in the peak phase of the “oil generation window” (0.65–0.9%Rrandom). The organic matter is mainly composed of vitrinite and inertinite macerals, with a minor contribution of sporinite from the liptinite group, which is typical of kerogen type III. Although all of the samples have vitrinite reflectances corresponding to the oil window, the formation of liquid hydrocarbons is rather limited because the organic matter is dominated by gas-prone kerogen type III.


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