1H NMR, mass spectroscopic studies and color fastness properties of methyl-4,6-dihydroxy-2-oxo-1-phenyl-5-arylazopyridine-3-carboxylate, part III: new disperse dyes

2007 ◽  
Vol 21 (1) ◽  
pp. 7-12 ◽  
Author(s):  
Rasheeda Parveen ◽  
Shahnaz Perveen ◽  
Ausaf Aleem ◽  
Khalid M. Khan ◽  
Mahwish
Keyword(s):  
1H Nmr ◽  
Spectroscopic Studies ◽  
Disperse Dyes ◽  
Color Fastness ◽  
Fastness Properties

scholarly journals Dyeing of Polyester with 4-Fluorosulfonylphenylazo-5-pyrazolone Disperse Dyes and Application of Environment-Friendly Aftertreatment for Their High Color Fastness

Materials ◽  
2019 ◽  
Vol 12 (24) ◽  
pp. 4209 ◽  
Author(s):  
Sanghyun Yoon ◽  
Byunghun Choi ◽  
Md Morshedur Rahman ◽  
Santosh Kumar ◽  
Shekh Md Mamun Kabir ◽  
...  
Keyword(s):  
Nitro Group ◽  
Oxygen Demand ◽  
Biological Oxygen Demand ◽  
Disperse Dyes ◽  
Color Fastness ◽  
Fastness Properties ◽  
Environment Friendly ◽  
Dyeing Process ◽  
Pyrazolone Derivatives ◽  
Dyeing Effluent

Dyeing and fastness properties of a series of 4-fluorosulfonylphenylazo-5-pyrazolone dyes on polyester were investigated in this study. The 4-nitrophenylazo-5-pyrazolone dyes were also synthesized to compare their dyeing and fastness properties on polyester with those of fluorosulfonyl-substituted analogues. The substantivity of 4-arylazo-5-pyrazolone derivatives containing a p-fluorosulfonyl group in the diazo component was lower than that of their nitro analogues which have a higher extinction coefficient and higher affinity because of the polar nitro group. They showed relatively hypsochromic color and lower chroma on polyester compared with their nitro analogues because of the relatively weaker electron-accepting power of the fluorosulfonyl group compared to the nitro group. Disperse dyeing of polyester with 4-fluorosulfonylphenylazo-5-pyrazolone disperse dyes achieved high color fastness and reduces the adverse environmental impact of the dyeing process by providing the option of performing alkali clearing instead of reductive clearing, which has high biological oxygen demand when discharged into the dyeing effluent and generates carcinogenic aromatic amines.

Utilization of Old Coconut (Cocos nucifera) Husk Waste as Potential Source of Natural Dye and its Dyeing Properties on Cotton Cloth

2021 ◽  
Vol 882 ◽  
pp. 280-286
Author(s):  
Aris Sugih Arto Kholil ◽  
Husniyyah Ulfah Adani ◽  
Annisa’ Mufsihah ◽  
Achmad Chafidz
Keyword(s):  
Cocos Nucifera ◽  
Natural Dye ◽  
Natural Dyes ◽  
Cotton Cloth ◽  
Color Fastness ◽  
Fastness Properties ◽  
Binding Agent ◽  
Binding Agents ◽  
Colored Cotton ◽  
Brown Color

Coconut husk is considered waste and its fibers can be used as a source of natural dyes for textiles. The objective of this research is to obtain natural dyes from old coconut (Cocos nucifera) husk waste fibers through the extraction process. Brown color was produced in the liquid-liquid extraction method. The brown color natural dyes were then used to dye cotton cloth. Three different binding agents were used during the fixation process, i.e. tunjung, naphtol salt, and alum. The coloring results of the natural dye on the cotton cloth were as follow: with alum binding agent the resulting color was light brown (cream), whereas tunjung binding agent produced a greenish brown color, and using napthol salt binding agent produced yellow color. The colored cotton cloths were tested for their color fastness properties against rubbing, soap washing, and sunlight exposure. The measurement scale used was grey scales, which was used to evaluate the color change (color fading) and color staining (color transfer) during color fastness testing. In general, based on the results, the colored cotton cloth using alum as binding agent showed better color fastness properties against rubbing, soap washing, and sunlight exposure compared to the ones using tunjung and naphtol salt binding agents.

scholarly journals Synthetic utility of 5-amino-6-cyano-2-phenylthieno[2,3-d] oxazole

2005 ◽  
Vol 70 (11) ◽  
pp. 1249-1253 ◽  
Author(s):  
V.R. Kanetkar ◽  
R.R. Walavalkar
Keyword(s):  
Ir Spectroscopy ◽  
Absorption Spectra ◽  
Polyester Fabric ◽  
Disperse Dyes ◽  
Fastness Properties ◽  
Visible Absorption ◽  
Synthetic Utility ◽  
Azo Disperse Dyes

This paper describes the synthesis of 5-amino-6-cyano-2-phenylthieno[ 2,3-d]oxazole and its utilization for the preparation of a range of azo disperse dyes. These aryl azo disperse dyes were applied on polyester fabric and their fastness properties were evaluated. The dyes were characterized by NMR and IR spectroscopy. The visible absorption spectra of these dyes were Recorded.

scholarly journals Dyeing of Polyester Fabric with Natural Colorants Extracted from Mahogany (Swieteniamahagoni) Seed Pods

2020 ◽  
Vol 11 (1) ◽  
pp. 37-42
Author(s):  
Md Abdullah Al Mamun ◽  
Mohammad Mamun Hossain ◽  
Mubarak Ahmad Khan
Keyword(s):  
Crude Extract ◽  
Polyester Fabric ◽  
Disperse Dyes ◽  
Color Fastness ◽  
Color Strength ◽  
Uv And Ir Spectra ◽  
Natural Colorants ◽  
Dyeing Method ◽  
Exhaust Dyeing ◽  
Dyed Fabric

Polyester fabric is usually dyed with disperse dyes which has severe limitations specially toxicity and environmental issues. The aim of the present research is to introduce an ecofriendly dyeing process for polyester fabric with natural dyes. The natural colorants were extracted from mahogany seed pods using the simple acid boiling method. The spectroscopic analysis of the crude extract was carried out by UV and IR spectra of the extracted dyes and illuminated the presence of natural tannins as coloring materials in the crude extract. 10g fabric was dyed in 200cc extracted solution at 130⁰C for 60 minutes in exhaust dyeing method followed by neutralization and soaping. Finally, a light brown dyed fabric was obtained. The dyed fabric exhibited color strength in terms of k/s value of 0.63 (λmax 360nm), lightness of 80.565 and chromaticity value of 12.002 CIE units. Different samples were dyed by fluctuating the dyeing period. The dyeing traits of the dyed materials were judged in terms of their color strength and fatness properties. All testes were carried out following the ISO standards. From the results, it is lucid that the dyed fabric showed acceptable color fastness properties in case of all fastness except color fastness to light. It is observed that dyeing time had profound influence on the color strength (k/s value) of the dyed material. The k/s value increases with the increase of dyeing period up to 120 minutes. The maximum color strength (0.76) was noted for the fabric. The shorter dyeing time produces lighter samples and the longer dyeing time produced colorful samples. Journal of Engineering Science 11(1), 2020, 37-42

scholarly journals Extraction and Optimization of Natural Dye from Hambo Hambo(Cassia singueana)Plant Used for Coloration of Tanned Leather Materials

2017 ◽  
Vol 2017 ◽  
pp. 1-5 ◽  
Author(s):  
Taame Berhanu ◽  
Saminathan Ratnapandian
Keyword(s):  
Aloe Vera ◽  
Natural Dye ◽  
International Standards ◽  
Bark Extract ◽  
Color Fastness ◽  
Fastness Properties ◽  
Visible Spectroscopy ◽  
Color Strength ◽  
Uv Visible ◽  
Temperature Time

This investigation was aimed at introducing natural dye extracted from the bark ofCassia Singueanaplant for dyeing chrome tanned sheep skin crust leather. The colorant was extracted by aqueous extraction and its strength evaluated using UV-Visible spectroscopy. The extraction with the highest strength (3.9 atλmaxof 400 nm) was obtained at temperature of 95°C, concentration of 60 g/l, and time of 60 minutes. The possibility of using aloe vera juice and mango bark extract as natural mordants for leather coloration was investigated. Dyeing was conducted with and without mordant using different combinations of temperature, time, pH, and concentration of mordants. All three mordanting techniques were evaluated. The color strength(K/S), CIEL⁎a⁎b⁎values, and fastness properties (light, rubbing, and perspiration) of dyed leather samples were evaluated using appropriate instruments and according to international standards. Majority of samples exhibited that fastness result was in the range of good-excellent. Significantly better color fastness was obtained in case of leather samples premordanted with aloe vera. This study leads to the conclusion that dye extracted from bark ofCassia singueanacan be used as colorant for tanned leather with the selected natural mordants.

scholarly journals Investigations on Terminalia Arjuna Fruits: Part 1- Isolation of Comounds from Petroleum Ether Fractions

1970 ◽  
Vol 43 (1) ◽  
pp. 123-130 ◽  
Author(s):  
M Zahurul Haque ◽  
M Abdullah As Saki ◽  
M Umar Ali ◽  
M Yusuff Ali
Keyword(s):  
Petroleum Ether ◽  
Key Words ◽  
1H Nmr ◽  
13C Nmr ◽  
Chromatographic Separation ◽  
Spectroscopic Studies ◽  
Biologically Active ◽  
Terminalia Arjuna ◽  
Pure Compounds ◽  
Column Chromatographic

Arjun (Terminalia arjuna) is a source of many potent, biologically active compounds, planned all over Bangladesh. The chemical examinations of its fruits were taken up to isolate and identify active principles. For this purpose fresh fruits of Terminalia arjuna were extracted with rectified spirit. The extract was then triturated with petroleum ether (40-60°C), which was then subjected to column chromatographic separation followed by PTLC. Such separation led to the isolation of some new pure compounds, TA-1 to TA-5. The structures of compounds were characterized through spectroscopic studies (IR, 1H-NMR and 13C-NMR). Key words: Arjun, TA-1, TA-5, Spectroscopic studies DOI: 10.3329.bjsir.v43i1.863 Bangladesh J. Sci. Ind. Res. 43(1),123-130, 2008

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