Hume-Rothery electron concentration rule across a whole solid solution range in a series of gamma-brasses in Cu–Zn, Cu–Cd, Cu–Al, Cu–Ga, Ni–Zn and Co–Zn alloy systems

2010 ◽  
Vol 90 (15) ◽  
pp. 1985-2008 ◽  
Author(s):  
U. Mizutani ◽  
T. Noritake ◽  
T. Ohsuna ◽  
T. Takeuchi
Keyword(s):  
Solid Solution ◽  
Electron Concentration ◽  
Solid Solution Range ◽  
Zn Alloy ◽  
Alloy Systems

Phase Relation and Microstructure of NbCr2 Laves Intermetallics in Ternary Nb-Cr-X Alloy Systems

1996 ◽  
Vol 460 ◽  
Author(s):  
M. Yoshida ◽  
T. Takasugi
Keyword(s):  
Solid Solution ◽  
Alloy System ◽  
X Ray Diffraction ◽  
Laves Phases ◽  
Characteristic Structure ◽  
X Ray ◽  
Intermediate Phases ◽  
Transmission Electron ◽  
Solid Solution Range ◽  
Alloy Systems

ABSTRACTThe isothermal phase diagrams of ternary alloy systems Nb-Cr-V and Nb-Cr-Mo are determined by metallography, X-ray diffraction (XRD) and transmission electron microscopy (TEM) equipped with energy dispersive X-ray (EDX). In two alloy systems, the C15 NbCr2 Laves phases are equilibrated directly with bcc solid solution without forming any intermediate phases. Relatively large amount of ternary elements V and Mo are soluble in the C15 NbCr2 Laves phases. It is shown that the C15 Laves phases extend along directions so that V occupies Cr site while Mo occupies Nb site. Also, characteristic structure containing micro twins and stacking faults is observed in the C15 Laves phase alloyed with Mo. Bcc phase has a wider solid solution range in the X(=V and Mo)-rich side than the Nb-rich and Cr-rich sides. A variety of duplex microstructures are observed depending on alloy system and alloy composition.

scholarly journals Mechanical Properties of Solder-Jointed Copper Rods with Electrodeposited Sn-Zn Alloy Films

Materials ◽  
2020 ◽  
Vol 13 (6) ◽  
pp. 1330 ◽  
Author(s):  
Tatsuya Tsurusaki ◽  
Takeshi Ohgai
Keyword(s):  
Solid Solution ◽  
Equilibrium Phase ◽  
Alloy System ◽  
Equilibrium Phase Diagram ◽  
Solid Solution Phase ◽  
Alloy Films ◽  
Cu Substrate ◽  
Soldering Process ◽  
Fracture Elongation ◽  
Zn Alloy

Enforced solid solution type Sn-Zn alloy films were electrochemically synthesized on Cu substrate from an aqueous solution containing citric acid complexes. The electrodeposition behavior of Sn-Zn alloys was classified to a normal co-deposition type, in which electrochemically nobler Sn deposits preferentially compared to Zn. Electrodeposited Sn-Zn alloy films were composed of a non-equilibrium phase, like an enforced solid solution, which was not observed in an equilibrium phase diagram of an Sn-Zn binary alloy system. By applying a thermal annealing process at 150 °C for 10 minutes, a pure Zn phase was precipitated from an electrodeposited Sn-based solid solution phase with excessively dissolved Zn atoms. During the soldering process, intermetallic phases such as Cu3Sn and Cu5Zn8 were formed at the interface between an Sn-Zn alloy and Cu substrate. Tensile strength and fracture elongation of solder-jointed Cu rods with Sn-8 at.%Zn alloy films reached ca. 40 MPa and 12%, respectively.

Effects of Cation Substitution on the Thermoelectric Properties in Ca-Co-O

2001 ◽  
Vol 691 ◽  
Author(s):  
Ichiro Matsubara ◽  
Ryoji Funahashi ◽  
Masahiro Shikano ◽  
Kei Sasaki ◽  
Hiroyuki Enomoto
Keyword(s):  
Thin Films ◽  
Solid Solution ◽  
Thermoelectric Power ◽  
Compressive Stress ◽  
Thermoelectric Properties ◽  
Plane Stress ◽  
Solution Process ◽  
Cation Substitution ◽  
Combinatorial Approach ◽  
Solid Solution Range

ABSTRACTWe have prepared (Ca1−x−yMxBiy)3Co4Oz (M = Mg, Sr, and Ba) thin films by a combinatorial approach using a solution process. In the systems of (Ca1−x−yMxBiy)3Co4Oz (M = Mg, Sr, and Ba), solid solution range was determined to be × < 0.8 (M = Sr, y = 0), x < 1.0 (M = Mg, y = 0), x = 0.0 (M = Ba, y = 0), and x < 0.4 (M = Bi, x = 0). No solid solution range was obtained for the substitution of Ba for Ca site. The in-plane compressive stress in the CoO2 sublattice is controllable by the cation substitution for Ca in the (Ca2CoO3) sublattice. With increasing in-plane stress, the magnitude of thermoelectric power and resistivity increased.

On the extension of the α-SiAlON solid solution range and anisotropic grain growth in Sm-doped α-SiAlON ceramics

1997 ◽  
Vol 17 (4) ◽  
pp. 575-580 ◽  
Author(s):  
Lars-Olov Nordberg ◽  
Zhijian Shen ◽  
Mats Nygren ◽  
Thommy Ekström
Keyword(s):  
Solid Solution ◽  
Grain Growth ◽  
Solid Solution Range

Solid solution range of boron and properties of the perovskite-type NdRh3B

2002 ◽  
Vol 335 (1-2) ◽  
pp. 191-195 ◽  
Author(s):  
Toetsu Shishido ◽  
Takahiko Sasaki ◽  
Kunio Kudou ◽  
Shigeru Okada ◽  
Akira Yoshikawa ◽  
...  
Keyword(s):  
Solid Solution ◽  
Solid Solution Range ◽  
Perovskite Type

Congruent composition and solid solution range of Li2B4O7 crystal

1997 ◽  
Vol 171 (3-4) ◽  
pp. 458-462 ◽  
Author(s):  
Satoshi Uda ◽  
Ryuichi Komatsu ◽  
Kouichi Takayama
Keyword(s):  
Solid Solution ◽  
Solid Solution Range

Variations of zinc content in solid solution during reversion treatment in an Al-4.4 At. Pct Zn Alloy

1981 ◽  
Vol 12 (5) ◽  
pp. 903-905 ◽  
Author(s):  
J. M. Pelletier ◽  
G. Vigier ◽  
F. Livet ◽  
C. Mai
Keyword(s):  
Solid Solution ◽  
Zinc Content ◽  
Zn Alloy ◽  
Reversion Treatment

X-ray powder diffraction characterization of Bi14(Sr,Ca)12O33 solid solutions

1996 ◽  
Vol 11 (4) ◽  
pp. 268-275 ◽  
Author(s):  
Winnie Wong-Ng ◽  
F. Jiang ◽  
Bryan R. Jarabek ◽  
Gregory J. McCarthy
Keyword(s):  
Solid Solution ◽  
Powder Diffraction ◽  
Solid Solutions ◽  
Cell Parameter ◽  
X Ray Diffraction ◽  
Powder Diffraction File ◽  
X Ray ◽  
Solid Solution Range

Powder X-ray diffraction was used to investigate the solid solution range of the Bi14SrxCa12−xO33 series in the Bi–Sr–Ca–O system. Solid solution forms over the range 1≤x≤7 in Bi14SrxCa12−xO33. Experimental X-ray reference patterns of selected members with x=1, 3, 5, and 7 have been prepared for the powder diffraction file (PDF). These phases are monoclinic, C2/m, with cell parameter a ranging from 21.473(4) to 21.868(4) Å, b from 4.3564(9) to 4.3898(9) Å, c from 12.753(2) to 12.962(2) Å, β from 102.91(2)° to 102.79(1)°, and V from 1162.9(3) to 1213.5(3) Å3, respectively. These parameters increase monotonically as Ca is continuously replaced by the larger Sr.

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