Freeze-drying preparation of porous diatomite ceramics with high porosity and low thermal conductivity

2020 ◽  
Vol 119 (4) ◽  
pp. 195-203
Author(s):  
Lei Han ◽  
Faliang Li ◽  
Haijun Zhang ◽  
Yuantao Pei ◽  
Longhao Dong ◽  
...  
2016 ◽  
Vol 678 ◽  
pp. 88-98 ◽  
Author(s):  
Harpal Singh

Rigid polyurethane foam (RPUF) is typically prepared by the reaction of an isocyanate, such as methyl diphenyl diisocyanate (MDI) with a polyol blend. During the polymerization reaction, a blowing agent expands the reacting mixture. The finished product is a solid, cellular polymer with a high thermal resistance. RPUF is an outstanding material for different applications. It has many desirable properties such as low thermal conductivity, low density, low water absorption, low moisture permeability, excellent dimensional stability, high strength to weight ratio. So, it is the best insulating material for industrial buildings, cold storages, telecom and defense shelters due to low thermal conductivity, low density, low moisture permeability and high porosity. It works to reduce heating and cooling loss, improving the efficiency of the building envelope. Thus, RPUF insulation in building envelopes brings additional benefits in energy savings, resulting in lower energy bills and protecting the environment by cutting CO2 emissions.


2017 ◽  
Vol 113 ◽  
pp. 246-253 ◽  
Author(s):  
Yuelei Pan ◽  
Song He ◽  
Lunlun Gong ◽  
Xudong Cheng ◽  
Congcong Li ◽  
...  

2019 ◽  
Vol 3 (11) ◽  
pp. 971-976 ◽  
Author(s):  
M. Grott ◽  
J. Knollenberg ◽  
M. Hamm ◽  
K. Ogawa ◽  
R. Jaumann ◽  
...  

2020 ◽  
Author(s):  
Imed Beghoura ◽  
Joao Castro-Gomes

Aim of this study was to produce alkali-activated foams with low thermal conductivity. Different precursors’ maximum particles sizes of 150μm, 300μm, and 500μm using a blend of 70% tungsten mining waste mud (TWM), 20% grounded waste glass (WG) and 10 % metakaolin (MK) with sodium silicate (SS) and sodium hydroxide (SH) as original material. Aluminium powder (Al) was used as a blowing agent and added first to the dry mix by changing content from 0.1g to 0.5g. Precursors and activators were mixed together to produce a homogeneous mixture, which was placed into a mould (100x200x60 mm3), and cured in the oven at 60∘C for 24 hours. The effect on foaming properties of different precursors maximum particles sizes were studied. The AAFs exhibited 28 day compressive strengths ranging from 2.28 to 16.1 MPa with the different densities from 913 to 1647 kg/m3 achieved through alteration of the foaming content. The thermal conductivity of AAFs was in the range 0.21– 0.33 W/m*K. Open celled hardened of the AAFs with 0.5g Al shows a high porosity of 58% with the mix made with 500μm. Therefore, tungsten mining waste-based alkali-activated foams shows a promise as thermal insulation material in some situations.


2021 ◽  
Vol 10 (1) ◽  
pp. 178-186
Author(s):  
Xueming Yang ◽  
Jixiang Cui ◽  
Ke Xue ◽  
Yao Fu ◽  
Hanling Li ◽  
...  

Abstract Sintered carbon nanotube (CNT) blocks and porous CNT sponges were prepared, and their thermoelectric properties were measured. The maximum dimensionless thermoelectric figure-of-merit, ZT, at room temperature of the sintered single-walled carbon nanotube (SWCNT) block is 9.34 × 10−5, which is twice higher than that of the sintered multi-walled carbon nanotube (MWCNT) block in this work and also higher than that of other sintered MWCNT blocks reported previously. In addition, the porous MWCNT sponge showed an ultra-low thermal conductivity of 0.021 W/(m K) and significantly enhanced ZT value of 5.72 × 10−4 at room temperature and 1 atm. This ZT value is higher than that of other 3D macroscopic pure CNT materials reported. The pronounced enhancement of the ZT in the porous MWCNT sponge is attributed to the ultra-low density, ultra-high porosity, and interconnected structure of the material, which lead to a fairly low thermal conductivity and better Seebeck coefficient. The finding of this work provides an understanding for exploring potential enhancement mechanisms and improving the thermoelectric properties of CNT-based thermoelectric composites.


2018 ◽  
Vol 56 (2A) ◽  
pp. 118-125 ◽  
Author(s):  
Nguyen Truong Son

In this study, cellulose was obtained from rice straw by dewaxing with Soxhlet extraction and treating with sodium hydroxide and hydrogen peroxide. The obtained cellulose was used to successfully fabricate cellulose aerogels with a binder by freeze drying technique. The materials were then functionalized with methyltrimethoxysilane (MTMS) to achieve hydrophobicity. The morphology, pore structure and other properties of the aerogels were characterized by scanning electron microscopy (SEM), X-ray powder diffraction (XRD), Fourier-transform infrared spectroscopy (FTIR), thermogravimetrical analysis (TGA), thermal conductivity and water contact angle (WCA) measurements. The rice straw cellulose aerogels exhibited very low specific density (0.0412-0.0470 g/cm3), high porosity (> 96 %), superhydrophobicity (WCA > 137o) and low thermal conductivity (0.034-0.036 W/(m.K)). The aerogels showed good oil adsorption capacity of 15.66-16.09 g/g. 


Nanomaterials ◽  
2019 ◽  
Vol 9 (4) ◽  
pp. 657 ◽  
Author(s):  
Fuxian Wang ◽  
Shiyuan Gao ◽  
Jiachuan Pan ◽  
Xiaomei Li ◽  
Jian Liu

Organic phase change materials (PCMs) have great potential in thermal protection applications but they suffer from high volumetric change and easy leakage, which require “leak-proof” packaging materials with low thermal conductivity. Herein, we successfully modify SiO2 through a simple 2-step method consisting of n-hexane activation followed by short-chain alkane silanization. The modified SiO2 (M-SiO2) exhibits superior hydrophobic property while maintaining the intrinsic high porosity of SiO2. The surface modification significantly improves the absorption rate of RT60 in SiO2 by 38%. The M-SiO2/RT60 composite shows high latent heat of 180 J·g−1, low thermal conductivity of 0.178 W·m−1·K−1, and great heat capacity behavior in a high-power thermal circuit with low penetrated heating flow. Our results provide a simple approach for preparing hydrophobic SiO2 with high absorption of organic PCM for thermal protection applications.


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