Cadmium removal from dilute aqueous solutions under galvanostatic mode in a flow-through cell

2015 ◽  
Vol 57 (48-49) ◽  
pp. 22809-22817 ◽  
Author(s):  
Ma. de Lourdes Llovera-Hernández ◽  
Alberto Álvarez-Gallegos ◽  
J.A. Hernández ◽  
Susana Silva-Martínez
2009 ◽  
Vol 59 (12) ◽  
Author(s):  
Adrian Turtureanu

The paper presents the removal of cadmium by flotation from dilute aqueous solutions, at a laboratory scale, using an anionic collector (oleic acid). The optimum values of the main parameters influencing this process were determined: pH of Cd(II) solutions, molar ratio collector:Cd(II), air flow rate, flotation time and initial concentration of Cd(II). Using these optimal conditions, a very high removal degree of cadmium (over 99%) was obtained.


1967 ◽  
Vol 71 (677) ◽  
pp. 381-383
Author(s):  
Y. Goren ◽  
P. O. Kane ◽  
J. F. Norbury

A technique has been devised for measuring the concentration of “Polyox” in dilute aqueous solutions. “Poly-ox”* is one of those polymers whose addition to water in low concentrations causes a reduction in skin friction (if the Reynolds number is sufficiently high) in turbulent flow through a pipe or boundary layer. (See, for example, ref. 1.) The analytical method is probably applicable to other polymers having this property, and it should be generally useful in this field of research. For example, in any experiment in which a polymer solution is injected at a point in a boundary layer, the method could be used to determine the distribution of polymer concentration at downstream sections. It is based on polarography, a well-established tool of chemical analysis of which an excellent account is given in ref. 2.


1978 ◽  
Vol 100 (4) ◽  
pp. 493-499 ◽  
Author(s):  
R. O¯ba ◽  
Y. Ito¯ ◽  
K. Uranishi

The cavitation behavior and the shock pressure were experimentally investigated in dilute aqueous solutions of polymer flowing through an orifice, and the following facts were observed: (i) Very small quantities of polymer additives effectively suppressed both the inception and the development of cavitation, (ii) nonspherical cavitation bubbles were observed at any polymer concentration tested here, and the nonsphericity tended to increase with concentration, (iii) the spectral frequencies of shock pressures were principally confined within the audio frequency range. With an increase in concentration, the energy of the pressures drastically decreased and the frequency range shifted downwards.


1980 ◽  
Vol 45 (10) ◽  
pp. 2645-2655 ◽  
Author(s):  
Antonín Mikan ◽  
Miloš Bartušek

The reactions of sorbitol, mannitol, adonitol, dulcitol, glucose and glycerol with H3AsO4, H3AsO3, H3BO3 and GeO2 acids in dilute aqueous solutions were studied by potentiometric neutralization titrations. The formation of the following chelates was demonstrated: As(V)L3-, As(III)L(OH)2-, HAs(III)L(OH)2, BL2-, GeL2(OH)- and GeL32- and the equilibrium constants for their formation were found. Conditions for formation of these chelates of organic oligohydroxy compounds are discussed.


1990 ◽  
Vol 55 (2) ◽  
pp. 345-353 ◽  
Author(s):  
Ivan Halaša ◽  
Milica Miadoková

The authors investigated periodic potential changes measured on oriented sections of Al single crystals during spontaneous dissolution in dilute aqueous solutions of KOH, with the aim to find optimum conditions for the formation of potential oscillations. It was found that this phenomenon is related with the kinetics of the reaction investigated, whose rate also changed periodically. The mechanism of the oscillations is discussed in view of the experimental findings.


Energies ◽  
2021 ◽  
Vol 14 (12) ◽  
pp. 3481
Author(s):  
Joanna Lach ◽  
Agnieszka Ociepa-Kubicka ◽  
Maciej Mrowiec

The aim of the work was to evaluate the possibility of using commercial and modified activated carbons for the removal of oxytetracycline from aqueous solutions. The kinetics and statics of adsorption as well as the effect of the activated carbon dose and solution pH on the efficiency of the oxytetracycline adsorption were analyzed. Based on the study of oxytetracycline adsorption isotherms, the activated carbons were ranked in the following order: F-300 > WG-12 > Picabiol > ROW08 > WACC 8 × 30 > F-100 > WAZ 0.6–2.4. The most effective activated carbons were characterized by large specific surfaces. The best matching results were obtained for: Redlich–Peterson, Thot and Jovanovic models, and lower for the most frequently used Freundlich and Langmuir models. The adsorption proceeded better from solutions with pH = 6 than with pH = 3 and 10. Two ways of modifying activated carbon were also assessed. A proprietary method of activated carbon modification was proposed. It uses the heating of activated carbon as a result of current flow through its bed. Both carbons modified at 400 °C in the rotary kiln and on the proprietary SEOW (Joule-heat) modification stand enabled to obtain adsorbents with higher and comparable monolayer capacities. The advantage of the proposed modification method is low electricity consumption.


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