STUDIES ON HIGH-COORDINATION COMPLEXES OF DIOXOURANIUM(VI) WITH A SCHIFF BASE

2002 ◽  
Vol 32 (5) ◽  
pp. 913-922 ◽  
Author(s):  
Kishor Arora ◽  
Sharma K.P.
2015 ◽  
Vol 12 (2) ◽  
pp. 13
Author(s):  
Muhamad Faridz Osman ◽  
Karimah Kassim

The coordination complexes of Co(II) and Zn(II) with Schiff bases derived from o-phenylenediamine and substituted 2-hydroxybenzaldehyde were prepared All compounds were characterized by Fourier transform infrared (FTIR) spectroscopy and Nuclear magnetic resonance (NMR) spectroscopy elemental analyzers. They were analyzed using impedance spectroscopy in the frequency range of 100Hz-1 MHz. LI and L2 showed higher conductivity compared to their metal complexes, which had values of 1.3 7 x 10-7 and 6.13 x 10-8 S/cm respectively. 


2018 ◽  
Vol 42 (8) ◽  
pp. 5834-5843 ◽  
Author(s):  
József Magyari ◽  
Berta Barta Holló ◽  
Ljiljana S. Vojinović-Ješić ◽  
Mirjana M. Radanović ◽  
Stevan Armaković ◽  
...  

There is a complex interplay between the structural and other physicochemical properties of new compounds and the molecules in living organisms.


2008 ◽  
Vol 5 (3) ◽  
pp. 529-538 ◽  
Author(s):  
Vidyavati Reddy ◽  
Nirdosh Patil ◽  
Tukaram Reddy ◽  
S. D. Angadi

Coordination complexes of Cu(II),Co(II), Ni(II), Mn(II) and Fe(III)with Schiff bases derived from 3-(4-chlorophenoxymethyl)-4-amino-5-mercapto-1, 2, 4-triazole and substituted aldehydes have been synthesized. The complexes were characterized by elemental analysis, conductivity measurements, magnetic susceptibility data, electronic, IR, ESR and1H NMR spectral data. On the basis spectroscopic studies, the Schiff base is monobasic bidentate ligand having the composition ML2(2H2O) Where M = Cu(II), Co(II), Ni(II) ,Mn(II), ML2(H2O)Cl Where M = Fe(III). Various physicochemical data suggest a six coordinated octahedral geometry for Cu(II),Co(II), Ni(II), Mn(II) and Fe(III) complexes. The antibacterial activities of ligand and its complexes were screened by cup plate method.


2015 ◽  
Vol 12 (2) ◽  
pp. 13
Author(s):  
Muhamad Faridz Osman ◽  
Karimah Kassim

The coordination complexes of Co(II) and Zn(II) with Schiff bases derived from o-pheny/enediamine and substituted 2-hydroxybenza/dehyde were prepared All compounds were characterized by Fourier transform infrared (FTIR) spectroscopy and Nuclear magnetic resonance (NMR.) spectroscopy elemental analyzers. They were analyzed using impedance spectroscopy in the frequency range of 100 Hz - 1 MHz. L1 and L2 showed higher conductivity compared to their metal complexes, which had values of 1.3 7 x 10-7 and 6.13 x 10-8 S/cm respectively.


2021 ◽  
Vol 0 (0) ◽  
Author(s):  
Samik Gupta

Abstract Pyridoxal and Pyridoxal 5-phosphate are two among the six aqua soluble vitamers of vitamin B6. They can form Schiff bases readily due to the presence of aldehyde group. Schiff bases can offer diverse coordination possibilities for many transition metals as has been found in a large volume of research till now. The coordination complexes thus formed gives insight into the active core structure and enzymatic activities of vit B6 containing enzymes. Apart from that, these complexes have been found useful as catalysts for synthesis of fine chemicals, as sensors and for their diverse biological activities.


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