Synthesis and Physico-Chemical Properties of Polycyanurates of 2-(N,N-Diphenylhydrazino)4,6-Dichloro-s-Triazine with Various Aromatic Diols

1993 ◽  
Vol 5 (4) ◽  
pp. 307-316 ◽  
Author(s):  
B S Bhonsale ◽  
S N Kaula ◽  
B V Patel ◽  
K C Patel
Keyword(s):  
Thermal Stability ◽  
Chlorinated Solvents ◽  
Chemical Properties ◽  
Interfacial Polycondensation ◽  
Bisphenol S ◽  
Reaction Conditions ◽  
Reduced Viscosity ◽  
Physico Chemical ◽  
Optimum Reaction ◽  
Thermal Stability Of

Various polycynaurates were synhesised by stirred interfacial polycondensation of 2-(N.N-diphenynhydrazino)-4,6-dichloro-s-triaziae (DPHDCT) with each of the aromatic diols: bisphenol-A (BPA); bisphenol-C (BPC); bisphenol-S (BPS); phenolphthalein (Ph); catechol; resorcinol; 1,5and 2.7-dihydroxynaphthalene (DHN-1,5 and DHN-2,7) and 1,8-dihydroxyanthraquinone (DHA-1,8). Interfacial polycondensation of DPHDCT with BPA was investigated in detail in order to select optimum reaction conditions. The yield of polycyanurates varies from 6 I% to 79%. The polycyanurates are soluble in chlorinated solvents such as chloroform, dichloroethane. dichloromethane and chlorobenzene. The reduced viscosity for polycyanurates, determined with a 1 g disolution in chloroform at 25 + 3°C was found to be in the range 0.50-0.68 dl g. All the polycyanurates were characterized by IR spectra. The densities of the polycyanurates, determined using the suspension method at 25 3°C, range between 1.196 and 1.330 g cm. The overall reactivity of diols, based on reduced viscosity values, was found to decrease in the following order: PCBPA> PCPh> PCBPC> PCR>PCDHN-2,7 > PCDHN-I,5 > PCC > PCDHA-1.8 > PCBPS. The thermal stability of polycyanurates, derived from various temperature characteristics, was found to decrease in the following order: PCBPA> PCBPS> PCBPC > PCC PCR> PCDHN-2,7 PCDHN-.l 5 > PCDHA-1,8 > PCPh.

Synthesis and Physico-Chemical Properties of 2-Morpholino-4,6-Dichloro-S-Triazine with Various Aromatic Diols

1996 ◽  
Vol 8 (2) ◽  
pp. 265-273 ◽  
Author(s):  
K C Patel ◽  
S N Kaula ◽  
P S Patel
Keyword(s):  
Thermal Stability ◽  
Thermogravimetric Analysis ◽  
Ir Spectra ◽  
Chlorinated Solvents ◽  
Chemical Properties ◽  
Interfacial Polycondensation ◽  
Viscosity Measurements ◽  
Physico Chemical ◽  
Thermal Stability Of

Several homopolycyanurates were synthesized by stirred interfacial polycondensation of 2-morpholino-4,6-dichloro- s-triazine with various aromatic diols such as 1,5- dihydroxynaphthalene,(DHN-1,5),1,7-dihydroxynapthalene(DHN-1,7),2,7-dihydroxynapthalene resorcinol (R), catechol (C), hydroquinone (H) and phenolphthalein (Ph). They were characterized by density, viscosity measurements, IR spectra, solubility tests and thermogravimetric analysis. The polymer had reduced viscosities in the range 0.468 to 0.829 dl g−1 in chromoform at 30 °C. All the polymers were amorphous and soluble in chlorinated solvents. The thermal stability of polycyanurates decreases in the following matter: PCDHN-1,5 > PCDHN-1,7 > PCPh > PCR ≃ PCDHN-2,7 > PCHQ > PCC.

Effect of Phenylene Diamine Antioxidant on Physico-Chemical Properties of Methyl Grafted Natural Rubber Polymer Electrolytes

2017 ◽  
Vol 864 ◽  
pp. 48-53
Author(s):  
Ahmad Fairoz Aziz ◽  
Khuzaimah Nazir ◽  
S.F. Ayub ◽  
N.I. Adam ◽  
Muhd Zu Azhan Yahya ◽  
...  
Keyword(s):  
Thermal Stability ◽  
Natural Rubber ◽  
Polymer Electrolytes ◽  
Chemical Properties ◽  
Physico Chemical ◽  
Solution Cast ◽  
Deconvolution Techniques ◽  
Tga And Dsc ◽  
Thermal Stability Of ◽  
Aging Factor

0.5 wt.% of N-(1,3-dimethylbutyl)-N’-phenyl-p-phenylenediamine (6PPD) was introduced into polymer electrolytes based on 30% poly(methyl-methacrylate) grafted natural rubber (MG30) in order to reduce the aging factor of MG30. The polymer electrolyte without 6PPD was used as control. All samples were prepared by using solution cast techniques. The effect of 6PPD in the electrolytes was analysed by using TGA, DSC and FTIR. TGA and DSC results revealed the thermal stability of MG30 electrolytes with 6PPD have higher thermal stability but lower glass transition temperature value. FTIR studies confirmed the existence of LiTF in the sample and prove the occurrence of polymer-salt complexation. Deconvolution techniques analysis on FTIR spectra shows the electrolyte sample with 6PPD display more ion dissociation which reflects to higher ionic conductivity.

scholarly journals Features of the Structure and Physical-Chemical Properties of Poly-Ortho-Toluidine Doped with Toluenesulfonic Acid

2019 ◽  
Vol 20 (1) ◽  
pp. 77-82
Author(s):  
A.L. Stepura ◽  
O.I. Aksimentyeva ◽  
P.Yu. Demchenko
Keyword(s):  
Crystal Structure ◽  
Thermal Stability ◽  
Electrical Conductivity ◽  
Specific Resistance ◽  
Oxidative Polymerization ◽  
Chemical Properties ◽  
Conductivity Activation Energy ◽  
Physical Chemical ◽  
Physico Chemical ◽  
Thermal Stability Of

Features of crystal structure, electrical conductivity and thermal stability of poly-ortho-toluidine (PoTi) samples, obtained with method of oxidative polymerization in the environment of sulfuric and toluenesulfonic acids (TSA), were investigated. It was discovered that PoTi-TSA samples are characterized withhigh crystallinity. According to the physico-chemical analysis, doping samples with TSA causes increase of PoTi thermal stability, electrical conductivity and sensor sensitivity on the contrary to samples doped with sulfuric acid. Based on temperature dependence of specific resistance, were calculated the values of the conductivity activation energy, which are within the limits of 0.2-0.4 eV depending on the type of dopant.

Physico-chemical properties and thermal stability of microcrystalline cellulose isolated from Alfa fibres

2014 ◽  
Vol 104 ◽  
pp. 223-230 ◽  
Author(s):  
Djalal Trache ◽  
André Donnot ◽  
Kamel Khimeche ◽  
Riad Benelmir ◽  
Nicolas Brosse
Keyword(s):  
Thermal Stability ◽  
Microcrystalline Cellulose ◽  
Chemical Properties ◽  
Physico Chemical ◽  
Thermal Stability Of

scholarly journals Cross-Linked Chitosan/Multi-Walled Carbon Nanotubes Composite as Ecofriendly Biocatalyst for Synthesis of Some Novel Benzil Bis-Thiazoles

Polymers ◽  
2021 ◽  
Vol 13 (11) ◽  
pp. 1728
Author(s):  
Latifah A. Alshabanah ◽  
Sobhi M. Gomha ◽  
Laila A. Al-Mutabagani ◽  
Tariq Z. Abolibda ◽  
Nahed A. Abd El-Ghany ◽  
...  
Keyword(s):  
Thermal Stability ◽  
Alternative Methods ◽  
Reaction Conditions ◽  
Chemical Structures ◽  
Weight Losses ◽  
Recyclable Catalysts ◽  
Multi Walled Carbon Nanotubes ◽  
Walled Carbon Nanotubes ◽  
Thermal Stability Of ◽  
Heterogeneous Biocatalyst

Aminohydrazide cross-linked chitosan (CLCS) and its MWCNTs (CLCS/MWCNTs) were formulated and utilized as a potent ecofriendly basic heterogeneous biocatalyst under ultrasonic irradiation for synthesis of two novel series of benzil bis-aryldiazenylthiazoles and benzil bis-arylhydrazonothiazolones from the reaction of benzil bis-thiosemicarbazone with 2-oxo-N′-arylpropanehydrazonoyl chlorides and ethyl 2-chloro-2-(2-phenylhydrazono) acetates, respectively. The chemical structures of the newly synthesized derivatives were elucidated by spectral data and alternative methods, where available. Additionally, their yield % was estimated using a traditional catalyst as TEA and green recyclable catalysts as CLCS and CLCS/MWCNTs composite in a comparative study. We observed that, under the same reaction conditions, the yield % of the desired products increased by changing TEA to CLCS then to CLCS/MWCNT from 72–78% to 79–83% to 84–87%, respectively. The thermal stability of the investigated samples could be arranged as CLCS/MWCNTs composite > CLCS > chitosan, where the weight losses of chitosan, CLCS and CLCS/MWCNTs composite at 500 °C were 65.46%, 57.95% and 53.29%, respectively.

Organic solvent-free synthesis of phosphorus-containing polymers

2007 ◽  
Vol 79 (11) ◽  
pp. 1879-1884 ◽  
Author(s):  
Smaranda Iliescu ◽  
Gheorghe Ilia ◽  
Aurelia Pascariu ◽  
Adriana Popa ◽  
Nicoleta Plesu
Keyword(s):  
Thermal Stability ◽  
Thermal Analysis ◽  
Bisphenol A ◽  
Organic Solvent ◽  
Molar Mass ◽  
Interfacial Polycondensation ◽  
H Nmr ◽  
Phosphorus Containing ◽  
Solvent Free Synthesis ◽  
Thermal Stability Of

Direct, efficient, organic solvent- and catalyst-free synthesis of a series of polyphosphates was accomplished. The reaction involved a gas-liquid interfacial polycondensation between arylphosphoric dichlorides and bisphenol A. The polyphosphates were characterized by IR, 1H NMR, 31P NMR, inherent viscosity, thermal analysis, and molar mass. Yields in the range 70-90 % and inherent viscosities in the range 0.30-0.40 dl/g were obtained. The thermal stability of the polyphosphates was investigated by using thermogravimetry.

Synthese und Eigenschaften von Alkyloxi-und Aryloxi-substituierten Trithiadiborolanen / Synthesis and Properties of Alkoxi and Aryloxi Substituted Trithiadiborolanes

1981 ◽  
Vol 36 (11) ◽  
pp. 1444-1450 ◽  
Author(s):  
Max Schmidt ◽  
Erich Sametschek
Keyword(s):  
Thermal Stability ◽  
Nmr Spectra ◽  
Chemical Properties ◽  
Physical And Chemical Properties ◽  
H Nmr ◽  
New Compounds ◽  
Physical And Chemical ◽  
Thermal Stability Of ◽  
And Chemical Properties

Abstract The first examples of the hitherto unknown 1,2,4-Trithia-3,5-diborolanes with B-O-C-bonds have been synthesized and characterised. The diiodo substituted ring (2) reacts with 2,6-dimethylphenol, to form 3,5-bis-(2,6-dimethylphenyloxi)-1,2,4-trithia-3,5-di-borolane (3) and HI. 3,5-Diethoxi-1,2,4-trithia-3,5-diborolane, 5, and C2H5I are formed via the cleavage of diethylether by 2. From 2 and diisopropylether, the corresponding 3,5-diisopropyloxi-1,2,4-trithia-3,5-diborolane (6) is formed. The unsymmetrical ethers methyl-t-butylether and methylphenylether undergo reactions with 2 resulting in the formation of 3,5-dimethyloxi-1,2,4-trithia-3,5-diborolane (8) (besides t-C4H9I) and 3,5-diphenyloxi-1,2,4-trithia-3,5-diborolane (10) (besides CH3I). The thermal stability of the new compounds is increasing with increasing size of R in the -OR group and from aliphatic to aromatic R in this group. IR, Raman, 1H NMR and 11B NMR spectra of the compounds are reported as well as some physical and chemical properties.

Preparation and Characterization of Composite of Polyamide 6/Nickel Ferrite

2012 ◽  
Vol 727-728 ◽  
pp. 609-613
Author(s):  
P.C.F. Menezes ◽  
Taciana Regina de Gouveia Silva ◽  
Ana Cristina Figueiredo de Melo Costa ◽  
Edcleide Maria Araújo
Keyword(s):  
Thermal Stability ◽  
Nickel Ferrite ◽  
Polyamide 6 ◽  
Hydraulic Press ◽  
Good Dispersion ◽  
Distributed Load ◽  
Physico Chemical ◽  
The Matrix ◽  
Thermal Stability Of

The research in composites attempt to predict the physico-chemical and mechanical a given mixture of materials. In this work, a composite was produced using as the polyamide 6 matrix and how the burden of nickel ferrite was incorporated as powders calcined at 1200°C and concentration of 50 wt.%. This mixture was compacted in a hydraulic press with heating and characterized by XRD, SEM and TG. XRD results showed the characteristic peaks of polyamide 6 and ferrite. SEM results showed a good dispersion of nickel ferrite loading in the matrix, the presence of larger clusters and evenly distributed load for the composite calcined at 1200 ° C. TG curves showed that the addition of loading of calcined nickel ferrite promoted an increase in thermal stability of the composite compared to pure polyamide.

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