Direct ink writing of 3D conductive polyaniline structures and rheological modelling

2017 ◽  
Vol 27 (1) ◽  
pp. 015006 ◽  
Author(s):  
F Benjamin Holness ◽  
Aaron D Price
2018 ◽  
Author(s):  
alireza razaghi

In this research aniline polymerization conditions were optimized in presence of pre-treated polyester textile to achieve as high electrical conductivity as 100 S/Cm. Alkaline activation of the polyester textile was followed by immersion in to aqueous acidic solution of aniline monomer. Then the oxidant solution was used to initiate the polymerization. Finally, the prepared product was washed and dried prior to ant test. Functional groups were studied by Fourie-transformed infrared spectrometry (FTIR) from the surface of the polyaniline coated textile. Also, morphological structure of synthesized conductive polyaniline was studied by scanning electron microscopy (SEM). The synthesized cloth was used in a closed circuit in order to light up alight emitting diode to emphasis the conductivity of the textile and fibres that synthesised by this method.


2018 ◽  
Author(s):  
alireza razaghi

In this research aniline polymerization conditions were optimized in presence of pre-treated polyester textile to achieve as high electrical conductivity as 100 S/Cm. Alkaline activation of the polyester textile was followed by immersion in to aqueous acidic solution of aniline monomer. Then the oxidant solution was used to initiate the polymerization. Finally, the prepared product was washed and dried prior to ant test. Functional groups were studied by Fourie-transformed infrared spectrometry (FTIR) from the surface of the polyaniline coated textile. Also, morphological structure of synthesized conductive polyaniline was studied by scanning electron microscopy (SEM). The synthesized cloth was used in a closed circuit in order to light up alight emitting diode to emphasis the conductivity of the textile and fibres that synthesised by this method.


2021 ◽  
Vol 23 ◽  
pp. 101005
Author(s):  
Kai Huang ◽  
Hamada Elsayed ◽  
Giorgia Franchin ◽  
Paolo Colombo

Polymers ◽  
2020 ◽  
Vol 13 (1) ◽  
pp. 77
Author(s):  
Enric Casanova-Batlle ◽  
Antonio J. Guerra ◽  
Joaquim Ciurana

Bioresorbable cardiovascular applications are increasing in demand as fixed medical devices cause episodes of late restenosis. The autologous treatment is, so far, the gold standard for vascular grafts due to the similarities to the replaced tissue. Thus, the possibility of customizing each application to its end user is ideal for treating pathologies within a dynamic system that receives constant stimuli, such as the cardiovascular system. Direct Ink Writing (DIW) is increasingly utilized for biomedical purposes because it can create composite bioinks by combining polymers and materials from other domains to create DIW-printable materials that provide characteristics of interest, such as anticoagulation, mechanical resistance, or radiopacity. In addition, bioinks can be tailored to encounter the optimal rheological properties for the DIW purpose. This review delves into a novel emerging field of cardiovascular medical applications, where this technology is applied in the tubular 3D printing approach. Cardiovascular stents and vascular grafts manufactured with this new technology are reviewed. The advantages and limitations of blending inks with cells, composite materials, or drugs are highlighted. Furthermore, the printing parameters and the different possibilities of designing these medical applications have been explored.


2021 ◽  
Vol 45 (1) ◽  
pp. 162-168
Author(s):  
Tao Li ◽  
Jiandong Cui ◽  
Yezhan Lin ◽  
Kecheng Liu ◽  
Rui Li ◽  
...  

The enhanced photocatalytic hydrogen evolution performance of g-C3N4–Co3O4 2D–1D Z-scheme heterojunctions was achieved through the synergistic effect of the cobalt ion redox, conductive polyaniline, and a Co3O4 nanobelt.


2021 ◽  
Vol 13 (1) ◽  
Author(s):  
Xinyu Wu ◽  
Tingxiang Tu ◽  
Yang Dai ◽  
Pingping Tang ◽  
Yu Zhang ◽  
...  

Highlights 3D printing of MXene frames with tunable electromagnetic interference shielding efficiency is demonstrated. Highly conductive MXene frames are reinforced by cross-linking with aluminum ions. Electromagnetic wave is visualized by electromagnetic-thermochromic MXene patterns. Abstract The highly integrated and miniaturized next-generation electronic products call for high-performance electromagnetic interference (EMI) shielding materials to assure the normal operation of their closely assembled components. However, the most current techniques are not adequate for the fabrication of shielding materials with programmable structure and controllable shielding efficiency. Herein, we demonstrate the direct ink writing of robust and highly conductive Ti3C2Tx MXene frames with customizable structures by using MXene/AlOOH inks for tunable EMI shielding and electromagnetic wave-induced thermochromism applications. The as-printed frames are reinforced by immersing in AlCl3/HCl solution to remove the electrically insulating AlOOH nanoparticles, as well as cross-link the MXene sheets and fuse the filament interfaces with aluminum ions. After freeze-drying, the resultant robust and porous MXene frames exhibit tunable EMI shielding efficiencies in the range of 25–80 dB with the highest electrical conductivity of 5323 S m−1. Furthermore, an electromagnetic wave-induced thermochromic MXene pattern is assembled by coating and curing with thermochromic polydimethylsiloxane on a printed MXene pattern, and its color can be changed from blue to red under the high-intensity electromagnetic irradiation. This work demonstrates a direct ink printing of customizable EMI frames and patterns for tuning EMI shielding efficiency and visualizing electromagnetic waves.


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