Study results of the choice of barium salts reagents for wastewater treatment from sulfates

Abstract The research on the removal of sulfates from mine wastewater is presented in the article. A new purification method has been proposed that allows removing a significant part of sulfates by precipitation in the form of barium sulfate. The present studies were devoted to the removal of sulfates from mine wastewater with a sulfate content of 1050 mg/l by introducing various doses of barium-containing reagents, namely barium chloride, hydroxide and barium carbonate. Among the listed reagents, the best results were obtained, using barium chloride and hydroxide. The use of barium chloride with a dose of 2700 mg/l and barium hydroxide with a dose of 3200 mg/l made it possible to reduce the concentration of sulfates below the maximum permissible (100 mg/l) when discharged into a reservoir for fishery purposes. A reliable in operation technological scheme for removing sulfates from highly concentrated mine wastewater has been developed, which makes it possible to reduce sulfates in the treated waste liquid discharged into the reservoir to 100 mg/l and below. In this case, the purification is carried out with separation of streams - in a smaller part (about 26% of the incoming); barium chloride is introduced, in the second - barium hydroxide. After that, the streams are mixed again, settled, sent to the calciner and to the post-treatment facilities and discharged into the reservoir. The resulting sludge is stored in special landfills or is processed to extract valuable components.

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Purification of Industrial Copper Electrolyte from Bismuth Impurity

Minerals ◽

10.3390/min12010036 ◽

2021 ◽

Vol 12 (1) ◽

pp. 36

Author(s):

Patrycja Kowalik ◽

Dorota Kopyto ◽

Mateusz Ciszewski ◽

Michał Drzazga ◽

Katarzyna Leszczyńska-Sejda

Keyword(s):

Barium Sulfate ◽

Barium Carbonate ◽

Lead Sulfate ◽

Strontium Carbonate ◽

Barium Hydroxide ◽

Process Time ◽

Purification Process ◽

Copper Electrolyte ◽

Bismuth Concentration ◽

Main Components

This work focused on purifying copper electrolytes from a bismuth impurity on a laboratory scale. The electrolyte came from Polish copper electrorefineries with the content of main components, g/dm3: 49.6 Cu, 160 H2SO4. The electrolyte was enriched in bismuth by Bi2O3 addition. Purification of bismuth contamination was carried out using selected agents with adsorbing effects, such as barium hydroxide octahydrate, strontium carbonate, barium carbonate, barium and lead sulfates. The trials were performed until achieving the Bi level—below 0.1 g/dm3. During the experiments, it was noticed that electrolyte purification degree depends on initial Bi concentration in electrolyte, time and temperature, as well as on the type and amount of the bismuth-lowering agent. The most satisfactory results of Bi impurity removal were with additions of barium hydroxide octahydrate, strontium carbonate and barium carbonate to electrolyte at 60 °C for 1 h. These parameters revealed the highest electrolyte purification degree. Bismuth is not removed effectively from electrolytes by barium sulfate or lead sulfate addition. The efficiency of the purification process is much higher when the agents are added to the solution in the form of carbonates or hydroxides. Extending the electrolyte purification process time may cause dissolution of bismuth from the resulting precipitate and increase of bismuth concentration in electrolytes.

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Improvement of Existing Wastewater Treatment Facilities with Microbial Products and Chemicals to Control Offensive Odor

JAPAN TAPPI JOURNAL ◽

10.2524/jtappij.67.149 ◽

2013 ◽

Vol 67 (2) ◽

pp. 149-153

Author(s):

Kenji Hayashi

Keyword(s):

Wastewater Treatment ◽

Treatment Facilities ◽

Microbial Products

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Appraisal of ground-water quality near wastewater-treatment facilities, Glacier National Park, Montana

10.3133/wri824 ◽

1982 ◽

Keyword(s):

Water Quality ◽

Wastewater Treatment ◽

Ground Water ◽

National Park ◽

Glacier National Park ◽

Ground Water Quality ◽

Treatment Facilities

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Технологические аспекты обезвоживания осадков промышленно-дождевых сточных вод автотранспортных предприятий

Vodosnabzhenie i sanitarnaia tehnika ◽

10.35776/mnp.2019.12.04 ◽

2019 ◽

pp. 25-30

Author(s):

G. Variushina

Keyword(s):

Wastewater Treatment ◽

Moisture Content ◽

Vacuum Filter ◽

Operational Parameters ◽

Technological Parameters ◽

Wastewater Treatment Process ◽

Motor Transport ◽

Cationic Flocculant ◽

Residual Sludge ◽

Treatment Facilities

Приводятся сведения об условиях формирования, объемах, химическом составе и свойствах осадков очистных сооружений производственных сточных вод автотранспортных предприятий. Даны примеры технологических решений по обезвоживанию образующихся в процессе очистки шламов. Рассмотрены технологические аспекты процесса интенсификации механического обезвоживания уплотненных осадков с использованием высокомолекулярных полиэлектролитов. Представлены данные лабораторных экспериментов по выбору типа флокулянта, его дозы, технологических параметров процесса, а также результаты определения влажности обезвоженных осадков, полученные на модели барабанного вакуум-фильтра. Приведены примеры эффективных обезвоживающих аппаратов отечественного производства и их технические характеристики, рекомендации и критерии их выбора, а также факторы, оказывающие влияние на эксплуатационные параметры обезвоживающего оборудования. Установлено, что наилучшая обезвоживающая способность барабанных вакуум-фильтров (остаточная влажность шламов от 66 до 83) может быть достигнута при применении катионного флокулянта ВПК-402 для осадков различных производственных цехов автотранспортного предприятия.Information on the conditions of generation, volumes, chemical composition and properties of sludge generated at the industrial wastewater treatment facilities of motor transport enterprises is provided. Examples of process engineering solutions for dewatering sludge generated during the wastewater treatment process are given. The technological aspects of enhancing mechanical dewatering of thickened sludge using high-molecular polyelectrolytes are considered. The data of laboratory experiments on choosing the type of flocculant, its dose, technological parameters of the process, as well as the results of determining the moisture content of dewatered sludge obtained in a model of a drum vacuum filter are presented. Examples of effective domestically produced dewatering apparatus and their technical characteristics, recommendations and criteria for their selection, as well as factors influencing the operational parameters of the dewatering equipment are given. It is found that the highest dewatering capacity of drum vacuum filters (residual sludge moisture content from 66 to 83) can be achieved by using VPK-402 cationic flocculant for processing sludge generated at the workshop premises of a motor transport enterprise.

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Обезвреживание поверхностного стока – важный вклад в охрану водных объектов

Vodosnabzhenie i sanitarnaia tehnika ◽

10.35776/mnp.2019.08.05 ◽

2019 ◽

pp. 48-54

Author(s):

G. Variushina

Keyword(s):

Wastewater Treatment ◽

Russian Federation ◽

Surface Runoff ◽

Commercial Fishing ◽

Research Activity ◽

Educational Work ◽

Industrial Enterprises ◽

Retention Basin ◽

Treatment Facilities ◽

The Russian Federation

Приводятся сведения о разработанных специалистами АО МосводоканалНИИпроект научных исследованиях и проектных решениях в области очистки поверхностных сточных вод с территории Москвы, причинах загрязнения водоисточников неочищенными поверхностными стоками в 1970х годах. Представлены основные характеристики комплексов глубокой очистки поверхностных стоков, разработанных проектов очистных сооружений для промышленных предприятий с площадью водосбора 0,3 1 5 10 и 15 га. Показано, что эффективность очистки поверхностных сточных вод соответствует требованиям, предъявляемым к водоемам рыбохозяйственного значения. При этом для обезвоживания осадка, образующегося в накопительном резервуаре очистных сооружений, в технологической схеме предусмотрена песковая площадка, а для сбора плавающих нефтепродуктов нефтеразделитель. Новизна разработанной технологии обезвреживания поверхностного стока и обработки осадка была подтверждена пятью патентами РФ, одобрена Госстроем РФ, Центральным управлением по рыбохозяйственной экспертизе и нормативам по сохранению, воспроизводству водных биологических ресурсов и акклиматизации, Городской санитарной службой Москвы и области, службами Москомприроды и Мосгосэкспертизы. Показан вклад специалистов лаборатории обработки природных, промышленнодождевых сточных вод и осадка в решение проблем очистки поверхностного стока. Приведена информация об истории развития и перспективных направлениях научной деятельности лаборатории, ее планах в организационнометодической и воспитательной работе с молодыми специалистами.Information on the research and design solutions developed by the experts of MosvodokanalNIIproject JSC in the field of surface runoff treatment from the territory of Moscow, the causes of water sources pollution with raw surface runoff in the 1970s. The basic characteristics of the complexes for the enhanced treatment of surface runoff, the developed projects of wastewater treatment facilities for industrial enterprises with a catchment area of 0.3 1 5 10 and 15 ha. It is shown that the effectiveness of surface runoff treatment meets the requirements to water bodies of commercial fishing importance. At the same time, for dewatering of sludge generated in the retention basin of wastewater treatment facilities, a grit dewatering bay is included into the process flow scheme, and an oil separator is used to collect floating oil products. The novelty of the developed technology for neutralization of surface runoff and sludge treatment has been acknowledged by five patents of the Russian Federation, approved by Gosstroy of the Russian Federation, the Central Department of Fisheries Examination and Review and Protection and Renewal and Acclimatization Standards, the Moscow City and Moscow Region Sanitary Service, Moskompriroda and Mosgosekspertiza services. The contribution of the research workers of the laboratory for the treatment of natural, industrialstorm wastewater and sludge processing to the solution of problems of surface runoff treatment is demonstrated. The information about the history of development and promising areas of research activity of the laboratory, its plans in the organizational, methodological and educational work with young professionals is given.

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Comprehensive Planning of Urban Drainage and Wastewater Treatment

Water Science & Technology ◽

10.2166/wst.1993.0302 ◽

1993 ◽

Vol 27 (12) ◽

pp. 205-208

Author(s):

Dirk-Th Kollatsch

Keyword(s):

Wastewater Treatment ◽

Transport Model ◽

Drainage System ◽

Simulation Models ◽

Urban Drainage ◽

Sewer Systems ◽

Priority Task ◽

Treatment Facilities ◽

Receiving Waters ◽

Pollution Impacts

For upgrading the urban drainage system (UDS) the reduction of pollution impacts is the priority task concerning the environmental protection of the receiving waters. With simulation models the interactions between surface, sewer systems, overflow structures and treatment facilities within the UDS can be shown. Models to simulate the pollutant impacts, transport and the effects on the receiving waters are available. In a first step a pollutant transport model of sewer systems and a model to simulate the wastewater treatment processes are connected. With these models the efficiency of upgrading measures can be checked in all parts of urban drainage systems.

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