NiO/C3N4: hybrid photocatalyst for the enhanced photodegradation of organic pollutant under visible light

2018 ◽  
Vol 5 (11) ◽  
pp. 115503 ◽  
Author(s):  
Kamatchi Thiyagarajan ◽  
Stanly Samuel ◽  
Sundaram Ganesh Babu
2021 ◽  
Vol 0 (0) ◽  
Author(s):  
Khee Chung Hui ◽  
Hazwani Suhaimi ◽  
Nonni Soraya Sambudi

Abstract Titanium dioxide (TiO2) is commonly used as a photocatalyst in the removal of organic pollutants. However, weaknesses of TiO2 such as fast charge recombination and low visible light usage limit its industrial application. Furthermore, photocatalysts that are lost during the treatment of pollutants create the problem of secondary pollutants. Electrospun-based TiO2 fiber is a promising alternative to immobilize TiO2 and to improve its performance in photodegradation. Some strategies have been employed in fabricating the photocatalytic fibers by producing hollow fibers, porous fibers, composite TiO2 with magnetic materials, graphene oxide, as well as doping TiO2 with metal. The modification of TiO2 can improve the absorption of TiO2 to the visible light area, act as an electron acceptor, provide large surface area, and promote the phase transformation of TiO2. The improvement of TiO2 properties can enhance carrier transfer rate which reduces the recombination and promotes the generation of radicals that potentially degrade organic pollutants. The recyclability of fibers, calcination effect, photocatalytic reactors used, operation parameters involved in photodegradation as well as the commercialization potential of TiO2 fibers are also discussed in this review.


Materials ◽  
2021 ◽  
Vol 14 (15) ◽  
pp. 4079
Author(s):  
Radhalayam Dhanalakshmi ◽  
Nambi Venkatesan Giridharan ◽  
Juliano C. Denardin

Magnetic-field-accelerated photocatalytic degradation of the phenol red (PR) as a model organic pollutant was studied using rare-earth elements modified BiFeO3 (Bi1−xRxFeO3 (R = Ce, Tb; x = 0.0, 0.05, 0.10 and 0.15); BFO: RE) nanostructures. The nanostructures were prepared via the hydrothermal process and their morphological, structural, functional, optical and magnetic features were investigated in detail. The effect of magnetic fields (MFs) on photocatalysis were examined by applying the different MFs under visible light irradiation. The enhanced photodegradation efficiencies were achieved by increasing the MF up to 0.5T and reduced at 0.7T for the compositions x = 0.10 in both Ce and Tb substituted BFO. Further, mineralization efficiencies of PR, reproducibility of MF-assisted photocatalysis, stability and recyclability of BFO: RE nanostructures were also tested.


2017 ◽  
Vol 418 ◽  
pp. 128-137 ◽  
Author(s):  
R. Rameshbabu ◽  
R. Vinoth ◽  
M. Navaneethan ◽  
S. Harish ◽  
Y. Hayakawa ◽  
...  

2017 ◽  
Vol 16 (12) ◽  
pp. 1792-1800 ◽  
Author(s):  
Minki Baek ◽  
Eun-Ju Kim ◽  
Seok Won Hong ◽  
Wooyul Kim ◽  
Kijung Yong

CuInS2(CIS)/ZnO is a superb photocatalyst for organic dye and bacteria decomposition. In this paper, photocatalytic mechanism of the heterostructure is investigated through controlled experiments under various scavenging conditions.


Minerals ◽  
2018 ◽  
Vol 8 (10) ◽  
pp. 437 ◽  
Author(s):  
Zhiming Sun ◽  
Fang Yuan ◽  
Xue Li ◽  
Chunquan Li ◽  
Jie Xu ◽  
...  

A novel kind of cyanuric-acid-modified graphitic carbon nitride (g-C3N4)/kaolinite (m-CN/KA) composite with enhanced visible light-driven photocatalytic performance was fabricated through a facile two-step process. Rhodamine B (RhB) was taken as the target pollutant to study the photocatalytic performance of the synthesized catalysts. It is indicated that the cyanuric acid modification significantly enhanced photocatalytic activity under visible light illumination in comparison with the other reference samples. The apparent rate constant of m-CN/KA is almost 1.9 times and 4.0 times those of g-C3N4/kaolinite and bare g-C3N4, respectively. The superior photocatalytic performance of m-CN/KA could be ascribed, not only to the generation of abundant pore structure and reactive sites, but also to the efficient separation of the photogenerated electron-hole pairs. Furthermore, the possible photocatalytic degradation mechanism of m-CN/KA was also presented in this paper. It could be anticipated that this novel and efficient, metal-free, mineral-based photocatalytic composite has great application prospects in organic pollutant degradation.


NANO ◽  
2016 ◽  
Vol 11 (05) ◽  
pp. 1650054 ◽  
Author(s):  
Bin Zeng ◽  
Yang Yin

CuS hexagonal nanosheet/graphene was fabricated by a facile one-pot microwave-thermal method. The samples possess excellent photocatalytic activity for degradation of organic pollutant under visible light. The high photocatalytic activity was attributed to the deposition of CuS hexagonal nanosheet onto graphene. CuS nanosheet serves as a transporter which efficiently inhibits the recombination of the photo-induced charge carriers in the nanocomposites. The developed method demonstrates a facile approach towards the synthesis of two-dimensional semiconductor-graphene nanocomposites with excellent photocatalytic performance under visible light.


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