One pot fabrication of graphene-bimetallic nanoparticles-based acetylcholinesterase electrochemical biosensor with ultralow detection limit toward methyl parathion

2019 ◽  
Vol 6 (10) ◽  
pp. 105093 ◽  
Author(s):  
Xianzhe Chen ◽  
Jianfang Wang ◽  
Zhuoliang Liu ◽  
Yujiao Li ◽  
Jian Huang ◽  
...  
2018 ◽  
Vol 72 (11) ◽  
pp. 1645-1652 ◽  
Author(s):  
Kailong Dong ◽  
Jiasheng Zhou ◽  
Taiqun Yang ◽  
Shan Dai ◽  
Hao Tan ◽  
...  

In this study, we report a straightforward strategy for Hg2+ ion detection. Fluorescent Au nanoparticles (NPs) were one-pot synthesized using a polymer (polyvinyl pyrrolidone [PVP]) as both capping and fluorescence agent. The as-synthesized PVP-Au NPs showed a remarkably rapid response selectively for Hg2+ ions compared to 14 other metal ions. The detection limit of Hg2+ was estimated at 100 nM. We discuss the emission and quenching mechanism of the PVP-Au NPs, the former being attributed to metal enhanced fluorescence and the latter being related to static quenching by Hg2+. The fluorescence of PVP-Au NPs offers an efficient and reliable strategy for Hg2+ ions detection. They therefore have a great potential for applications in health and environmental monitoring.


2015 ◽  
Vol 3 (7) ◽  
pp. 3450-3455 ◽  
Author(s):  
Wei Wu ◽  
Mei Lei ◽  
Shuanglei Yang ◽  
Li Zhou ◽  
Li Liu ◽  
...  

Copper-based alloy nanoparticles (NPs) have recently triggered much research interest for the development of low-cost and high-performance bimetallic catalysts that have industrial applications.


CrystEngComm ◽  
2012 ◽  
Vol 14 (20) ◽  
pp. 7036 ◽  
Author(s):  
Jishu Han ◽  
Ziwei Zhou ◽  
Yue Yin ◽  
Xintao Luo ◽  
Jing Li ◽  
...  

2020 ◽  
Vol 609 ◽  
pp. 113908 ◽  
Author(s):  
Anu Bharti ◽  
Sakshi Mittal ◽  
Shilpa Rana ◽  
Divya Dahiya ◽  
Navneet Agnihotri ◽  
...  

2013 ◽  
Vol 11 (2) ◽  
pp. 320-323 ◽  
Author(s):  
Dimitrios Nikolelis ◽  
Nikolas Psaroudakis ◽  
Antonis Michaloliakos ◽  
Georgia-Paraskevi Nikoleli ◽  
Michael Scoullos

AbstractAn electrochemical biosensor based on a supported polymerized lipid film with incorporated sheep anti-3,3′,4,4′ tetrachlorobiphenyl (PCB congener 77) antibody using flow injection analysis was developed. The polymerized lipid film contained 85% (w/w) dipalmitoylphosphatidylcholine (DPPC) and 15% (w/w) dipalmitoylphosphatidic acid (DPPA), methacrylic acid, ethylene glycol dimethacrylate, AIBN and sheep anti-congener 77 antiserum. Congener 77 was injected into flowing carrier electrolyte and the flow stopped to detect the antigen. These membranes gave only a single transient proportional to log [congener 77] from 10−8 to 10−5 M, with a detection limit of ca. 10−8 M. A membrane containing 35% (w/w) DPPA was used to examine regeneration. The maximum number of cycles was about 5.


2003 ◽  
Vol 33 (2) ◽  
pp. 325-338 ◽  
Author(s):  
Nicolas SOUMIS ◽  
Marc LUCOTTE ◽  
Delaine SAMPAIO ◽  
Diane C. ALMEIDA ◽  
Dalie GIROUX ◽  
...  

Trace levels of three organophosphate insecticides (OPI) were detected in eight fish species from the region of Santarém, State of Pará, Brazil. Individual concentrations of OPI in fish ranged from less than the detection limit to 2,1 ppb. Mean concentrations of chlorpyrifos, malathion, and methyl-parathion were 0,3 ± 0,3, 0,1 ± 0,1, and 0,3 ± 0,3 ppb, respectively. Pellona flavipinnis, the largest and fattest piscivorous species analyzed, was the most contaminated. Since an inhabitant of this Amazonian region consumes 220 g of fish per day on average, ingested doses of chlorpyrifos, malathion, and methyl-parathion may reach up to 308, 220, and 462 ng·d-1, respectively. Compared to acceptable daily intakes (ADI), quantities of OPI absorbed via fish consumption on a daily basis are far below deleterious levels. We estimated that even considering the highest OPI contents detected, the average daily fish consumption of anadult of 60 kg would have to increase by ca. 1 950, 5 450, and 2 600 times to reach ADI of chlorpyrifos, malathion, and methyl-parathion, respectively. Neither fish diet nor fish lipid content enabled us to completely explain the interspecific differences observed.


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