scholarly journals The effect of thermoplastic starch on the properties of polypropylene/high density polyethylene blend reinforced by nano-clay

2020 ◽  
Vol 7 (2) ◽  
pp. 025308
Author(s):  
Yassine Hammache ◽  
Aicha Serier ◽  
Saliha Chaoui
2020 ◽  
Vol 11 (1-2) ◽  
pp. 3-14
Author(s):  
Cassiano MN Romagnolli ◽  
Gabriela P Leite ◽  
Tiago AR Rodrigues ◽  
Carolina L Morelli

Plastic packagings are widely used for several food products. Considering the relatively short service lifetime of this application, it is important to perceive in the search of eco-friendly alternatives to this market, such as polymers from renewable sources, as thermoplastic starch and “green” polyethylene. The incorporation of an antibacterial agent to the packaging can extend food shelf life. Camellia sinensis is a plant with known antibacterial properties used in the preparation of “green tea.” In the present work, green tea was incorporated to a blend of cassava thermoplastic starch and high-density polyethylene (HDPE) by melt extrusion, aiming application as active packaging. Films were obtained by thermopressing and characterized through infrared spectroscopy, thermogravimetric analysis, scanning electron microscopy and tensile tests. Their antibacterial properties were evaluated against Staphylococcus aureus and Escherichia coli. The results indicated that the material developed has potential for food packaging applications. Moreover, the methodology applied for green tea incorporation in the Starch/HDPE films can be extended for many extracts from natural components, contributing to the advancement of research in the development of active packaging for food products. To the best of our knowledge, no previous work studied the properties of starch/HDPE blend with green tea.


2020 ◽  
Vol 137 (48) ◽  
pp. 49602
Author(s):  
Muhammad Harris ◽  
Johan Potgieter ◽  
Sudip Ray ◽  
Richard Archer ◽  
Khalid Mahmood Arif

Nanomaterials ◽  
2019 ◽  
Vol 9 (3) ◽  
pp. 361 ◽  
Author(s):  
Kartik Behera ◽  
Mithilesh Yadav ◽  
Fang-Chyou Chiu ◽  
Kyong Rhee

In this study, a graphene nanoplatelet (GNP) was used as a reinforcing filler to prepare poly(vinylidene fluoride) (PVDF)/high density polyethylene (HDPE) blend-based nanocomposites through a melt mixing method. Scanning electron microscopy confirmed that the GNP was mainly distributed within the PVDF matrix phase. X-ray diffraction analysis showed that PVDF and HDPE retained their crystal structure in the blend and composites. Thermogravimetric analysis showed that the addition of GNP enhanced the thermal stability of the blend, which was more evident in a nitrogen environment than in an air environment. Differential scanning calorimetry results showed that GNP facilitated the nucleation of PVDF and HDPE in the composites upon crystallization. The activation energy for non-isothermal crystallization of PVDF increased with increasing GNP loading in the composites. The Avrami n values ranged from 1.9–3.8 for isothermal crystallization of PVDF in different samples. The Young’s and flexural moduli of the blend improved by more than 20% at 2 phr GNP loading in the composites. The measured rheological properties confirmed the formation of a pseudo-network structure of GNP-PVDF in the composites. The electrical resistivity of the blend reduced by three orders at a 3-phr GNP loading. The PVDF/HDPE blend and composites showed interesting application prospects for electromechanical devices and capacitors.


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