scholarly journals Synthesis of silver nanoparticles from electronic scrap by chemical reduction

2021 ◽  
Author(s):  
Abolhassan Najafi ◽  
Mahdi Khoeini ◽  
Gholamreza Khalaj ◽  
Amirhossein Sahebgharan
Keyword(s):  
Silver Nanoparticles ◽  
Silver Nitrate ◽  
Chemical Reduction ◽  
Electronic Waste ◽  
Nitrate Solution ◽  
Silver Nitrate Solution ◽  
Main Peak ◽  
Fcc Structure ◽  
Uniform Particle Size

Abstract In the present research, the use of electronic waste in the synthesis of silver nanoparticles was investigated. For this purpose, electronic scraps were used as a consumable part to synthesize silver nanoparticles. The results revealed that by optimizing the time and temperature of the dissolution process using nitric acid solution up to 90%, silver can be extracted from these parts. The temperature of 60°C and the duration of one hour were determined as the optimum conditions for this phase. Afterward, the synthesis of silver nanoparticles was checked using silver nitrate solution. The results indicated that the concentration of initial silver nitrate had a significant impact on the quality of the final product so that the best conditions for the synthesis of silver nanoparticles with suitable properties were provided at 1 molar concentration. Phase studies indicated that the main phase of the synthesized silver particles had an FCC structure and no unwanted phase was observed. Ultraviolet-visible analysis of the synthesized powder revealed that the main peak for the silver nanoparticles appeared in the wavelength range of 400 to 450 nm. DLS analysis revealed that precursor's particles inside the sol were below 15 nm. Based on AFM and TEM investigations, the particles synthesized under these conditions had nanometric spherical morphology with uniform particle size distribution.

Controlling the Surface Plasmon Absorption of Silver Nanoparticles via Green Synthesis Using Pennisetum purpureum Leaf Extract

2018 ◽  
Vol 772 ◽  
pp. 73-77
Author(s):  
Ruelson S. Solidum ◽  
Arnold C. Alguno ◽  
Rey Capangpangan
Keyword(s):  
Silver Nanoparticles ◽  
Green Synthesis ◽  
Silver Nitrate ◽  
Surface Plasmon ◽  
Leaf Extract ◽  
Nitrate Solution ◽  
Silver Nitrate Solution ◽  
Absorption Peak ◽  
Plasmon Absorption ◽  
Surface Plasmon Absorption

We report on the green synthesis of silver nanoparticles utilizing theP.purpureumleaf extract. Controlling the surface plasmon absorption of silver nanoparticles was achieved by regulating the amount of extract concentration and the molarity of silver nitrate solution. The surface plasmon absorption peak is found at around 430nm. The surface plasmon absorption peak have shifted to lower wavelength as the amount of extract is increased, while plasmon absorption peak shifts on a higher wavelength as the concentration of silver nitrate is increased before it stabilized at 430nm. This can be explained in terms of the available nucleation sites promoted by the plant extract as well as the available silver ions present in silver nitrate solution.

scholarly journals The Synthesis and Stability Study of Silver Nanoparticles Prepared by Using p-Aminobenzoic Acid as Reducing and Stabilizing Agent

2018 ◽  
Vol 18 (3) ◽  
pp. 421 ◽  
Author(s):  
Dian Susanthy ◽  
Sri Juari Santosa ◽  
Eko Sri Kunarti
Keyword(s):  
Silver Nanoparticles ◽  
Reaction Time ◽  
Silver Nitrate ◽  
Tap Water ◽  
Nitrate Solution ◽  
Silver Nitrate Solution ◽  
Stability Study ◽  
Synthesis Process ◽  
Aminobenzoic Acid ◽  
Stabilizing Agent

A study to examine the performance of p-aminobenzoic acid as both reducing agent for silver nitrate to silver nanoparticles (AgNPs) and stabilizing agent for the formed AgNPs has been done. The synthesis of AgNPs was performed by mixing silver nitrate solution as precursor with p-aminobenzoic acid solution and heating it in a boiling water bath. After the solution turned to yellow, the reaction stopped by cooling it in tap water. The formed AgNPs were analyzed by using UV-Vis spectrophotometry to evaluate their SPR absorption in wavelength range of 400–500 nm. The synthesis process was highly depend on the pH, reaction time, and mole ratios of the reactants. The synthesis only occur in pH 11 and at reaction time 30 min, the particle size of the formed AgNPs was 12 ± 7 nm. Longer reaction time increased the reducing performance of p-aminobenzoic acid in AgNPs synthesis but decreased its stabilizing performance. The increase of silver nitrate amount relative to p-aminobenzoic acid in the synthesis increased the reducing and stabilizing performance of p-aminobenzoic acid and the optimum mole ratio between AgNO3 and p-aminobenzoic acid was 5:100 (AgNO3 to p-aminobenzoic acid).

Pretreated Lignocellulosic Waste Mediated Biosynthesis of Silver Nanoparticles Under Room Temperature

2016 ◽  
Vol 15 (05n06) ◽  
pp. 1660001 ◽  
Author(s):  
V. P. Manjamadha ◽  
Karuppan Muthukumar
Keyword(s):  
Silver Nanoparticles ◽  
Silver Nitrate ◽  
Room Temperature ◽  
Nitrate Solution ◽  
Silver Ions ◽  
Silver Nitrate Solution ◽  
Morphological Characterization ◽  
Alternative Source ◽  
X Ray ◽  
Antibacterial Performance

The current work elucidates the utilization of biowaste as a valuable reducing agent for the synthesis of silver nanoparticles. In this study, the wastewater generated during the alkaline pretreatment of lignocellulosic wastes (APLW) was used as a bioreductant to reduce silver nitrate under room temperature. Synthesis of stable silver nanoparticles (AgNPs) was achieved rapidly on addition of APLW into the silver nitrate solution (1[Formula: see text]mM). The morphological characterization of AgNPs was performed using field emission scanning electron microscopy (FESEM). The micrograph clearly depicted the presence of spherical AgNPs. The presence of elemental silver along with biomoilties was determined using energy dispersive X-ray spectroscopy (EDAX) analysis. The X-ray diffraction (XRD) study proved the crystalline form of stable AgNPs. The AgNPs exhibited excellent antibacterial performance against Gram negative organism. The immediate bioreduction of silver ions using APLW was well illustrated in the present study. Thus, APLW serve as an alternative source for reducing agents instead of utilizing valuable medicinal plants for nanoparticles synthesis.

Fast colourimetric detection of H2O2 by biogenic silver nanoparticles synthesised using Benincasa hispida fruit extract

2016 ◽  
Vol 5 (2) ◽  
Author(s):  
Kaushik Roy ◽  
Chandan K. Sarkar ◽  
Chandan K. Ghosh
Keyword(s):  
Silver Nanoparticles ◽  
Silver Nitrate ◽  
Nitrate Solution ◽  
Silver Nitrate Solution ◽  
Single Step ◽  
Fruit Extract ◽  
Biogenic Silver Nanoparticles ◽  
Benincasa Hispida

AbstractThis study reports a single-step, fast and eco-friendly procedure for preparing silver nanoparticles from silver nitrate solution using fruit extract of

Biosynthesis of Silver Nanoparticles Using Banana Raja (Musa paradisiaca var. raja) Peel Extract: Effect of Different Concentrations of the AgNO3 Solution

2021 ◽  
Vol 872 ◽  
pp. 61-66
Author(s):  
Hidayat Pratikno ◽  
Pramita Basuki Anggya ◽  
Febrianti Fadhila ◽  
Achmad Chafidz ◽  
Dyah Pita Rengga Wara
Keyword(s):  
Silver Nanoparticles ◽  
Silver Nitrate ◽  
Nitrate Solution ◽  
Silver Nitrate Solution ◽  
Banana Peel ◽  
Musa Paradisiaca ◽  
Result Show ◽  
Ft Ir ◽  
The Difference ◽  
Peel Extract

This study focuses on the biosynthesis of silver nanoparticles using Banana Raja (Musa Paradisiaca Var. Raja) peel extract. The aim is to determine the effect of concentration differences of silver nitrate (AgNO3) as the precursor on the production of silver nanoparticles. In this study, banana peel extract (BPE) was reacted with AgNO3 solution at several concentrations of silver nitrate solution i.e. 0.125; 0.1; 0.075 and 0.05 M at temperature of 50 °C. The ratio of banana peel extract and AgNO3 solution used was 5:500 (v/v). The stirring was done by using a magnetic stirrer. The reaction took place when the color of the mixture (extract and AgNO3) changed until the color of the mixture became constant. The results of the colloidal silver nanoparticles were characterized using UV-Vis Spectrometer, while the functional groups of the banana extract was analyzed using a Fourier Transform Infra-Red (FT-IR) apparatus. Whereas, the morphology of the silver nanoparticles was studied using a Scanning Electron Microscopy (SEM). The UV-Vis Spectrometer result show that the concentration of AgNO3 which gave the highest absorbance value was at 0.1 M. The SEM micrographs could not clearly show the difference in the morphology of silver nanoparticles samples at different concentrations of AgNO3 solution.

Microwave Assisted Green Synthesis of Silver Nanoparticles Using Mulberry Leaves Extract and Silver Nitrate Solution

2018 ◽  
Author(s):  
Liem Le ◽  
The Nguyen ◽  
Dieu Nguyen
Keyword(s):  
Silver Nanoparticles ◽  
Silver Nitrate ◽  
Nitrate Solution ◽  
Average Particle Size ◽  
Silver Nitrate Solution ◽  
Spherical Particles ◽  
Average Particle ◽  
Mulberry Leaves ◽  
Microwave Assisted ◽  
Microwave Assisted Method

In this work, silver nanoparticles (AgNPs) were synthesized rapidly and eco-friendlily using the extract of Mulberry leaves and aqueous solution of silver nitrate without any toxic chemical [1,2]. The Mulberry leaves extract acts as both reducing agent and stabilizing agent. The UV-Vis spectrum shows peak at 430 nm. The TEM image of synthesized AgNPs sample shows spherical shaped particles whose size range from 15 to 20 nm. TEM image of nano silver solution sample synthesized by microwave assisted method shows nearly spherical particles with an average particle size of 10 nm. The absorption UV-vis spectrum of silver nanoparticles synthesized by microwave assisted method (AgNPsmw) shows a sharp absorption band around 415 nm. After two month storage of AgNPsmw, the absorption spectrum of AgNPsmw was taken again. The UV-Vis spectrum shows negligible peak changes of silver nanoparticles have occurred after two months of storage. The synthesized AgNPs material could be used as an antimicrobial, used in the field of textile and in wastewater treatment.

A simple route for manufacturing highly dispersed silver nanoparticles

2007 ◽  
Vol 22 (9) ◽  
pp. 2488-2496 ◽  
Author(s):  
Daniel Andreescu ◽  
Christopher Eastman ◽  
Krishna Balantrapu ◽  
Dan V. Goia
Keyword(s):  
Silver Nanoparticles ◽  
Silver Nitrate ◽  
Ag Nanoparticles ◽  
Nitrate Solution ◽  
Reduction Rate ◽  
Silver Nitrate Solution ◽  
Metallic Phase ◽  
Simple Route ◽  
Dispersing Agent ◽  
Highly Dispersed

Highly dispersed uniform silver nanoparticles were prepared by reducing silver diamine ions [Ag(NH3)2]+ with D-glucose in the presence of a stabilizing agent. Along with the nature of the dispersing agent, the pH and the temperature of the reaction had the most pronounced effect on the reduction rate, the nucleation of the metallic phase, and ultimately the size and dispersion of the resulting particles. Through suitable manipulations of these parameters, it was possible to prepare uniform Ag nanoparticles ranging in size from 30 to 120 nm. A rapid and complete reduction of the silver species was possible only at elevated pH and temperatures above 50 °C. The reduction of silver diamine ions in these conditions caused the complete cleavage of the C–C bond, resulting in the release of 12 electrons per molecule of D-glucose. It was also found that the addition of ammonia to an already acidified silver nitrate solution leads to the formation of a much more stable and safe-to-handle diamine complex.

Green Synthesis of Nanostructured Silver Metal Particals and Catalytic Degradation of Toxic Methylene Blue Dye

2020 ◽  
Author(s):  
Jyoti Kedar ◽  
Ajinkya Kasar ◽  
Neha Pardeshi ◽  
Pradhumna Tiwari ◽  
Suyash Bhosale
Keyword(s):  
Methylene Blue ◽  
Silver Nanoparticles ◽  
Silver Nitrate ◽  
Silver Nanoparticle ◽  
Nitrate Solution ◽  
Silver Nitrate Solution ◽  
Noble Metal Nanoparticles ◽  
Blue Dye ◽  
Methylene Blue Dye ◽  
Uv Visible

Abstract The growth and development of bio-synthesized noble metal nanoparticles have attracted great amount of interest in field of nanotechnology due to their potential use for human benefits. The fungal synthesis of noble metal nanoparticles like silver nanoparticle is a sustainable, eco- friendly and green chemistry approach that amalgamate Mycology, Biotechnology and nanotechnology. Accordingly silver nanoparticles (silver nanoparticles) can be synthesized by physical, chemical and biological methods respectively. The aim of this research is to carry green synthesis of silver nanoparticles (silver nanoparticle) i.e. biological method using aqueous fungal extract of penicillium rubens. The aqueous fungal extract was added to silver nitrate solution where the color of the silver nitrate reaction medium was changed from Pale yellow to brown which indicates reduction of silver ions to silver nanoparticles. Thus synthesized silver nanoparticles were characterized by UV-Visible spectroscopy, which shows characterized peak between 400-420 nm. In order to classify the effective functional molecules responsible for the reduction and stabilization of fungal synthesized silver nanoparticles, the FTIR spectrum was examined. Optimization of production of silver nanoparticles was done by changing parameters such as pH, temperature and concentration of silver nitrate solution and determined by absorbance in UV-Visible spectrophotometer. Thus, it is concluded that the biosynthesis of silver nanoparticles using extracellular fungal filtrate was simple, eco-friendly and robust. Also the dye reduction capabilities of silver nanoparticles were examined. Effective degradation of Methylene blue dye was observed giving 97 % efficiency in 90 minutes of exposure time.

Ag Nanoparticles Adsorption on Diatom-Montmorillonite Clays

2013 ◽  
Vol 755 ◽  
pp. 91-96
Author(s):  
A. Ruíz-Baltazar ◽  
R. Esparza ◽  
R. Pérez ◽  
G. Rosas
Keyword(s):  
Silver Nanoparticles ◽  
Porous Material ◽  
Ag Nanoparticles ◽  
Diatomaceous Earth ◽  
Chemical Reduction ◽  
Nitrate Solution ◽  
Silver Nitrate Solution ◽  
X Ray Diffraction ◽  
Montmorillonite Clays ◽  
Complementary Techniques

In this work, a spectroscopic and structural characterization of diatomaceous earth-montmorillonite clays after impregnated with silver nanoparticles were carried out. The silver nanoparticles were synthesized by chemical reduction with sodium borohydride starting from silver nitrate solution. The obtained nanoparticles were stabilized with polyvinyl-pyrrolidone as a surface agent. In order to perform the homogeneous nucleation process, Ag nanoparticles solutions at concentrations of 1, 2 and 4 parts per million were magnetically mixed in the porous material. Additionally, we assessed the porous material adsorption ability of silver by atomic absorption spectroscopy. The quantity of Ag nanoparticles adsorbed by the diatomaceous earth and the adsorption rate as function of the concentration of Ag nanoparticles were established. Other complementary techniques such as X-ray diffraction, infrared spectroscopy and transmission and scanning electron microscopy were used.

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