Quantum confinement and monolayer semiconductors

2020 ◽  
pp. 649-698
Author(s):  
Sandip Tiwari

This chapter brings together several themes and perspectives by exploring them in quantum-confined conditions or in monolayer crystals. In it, confinement of electrons and holes at heterostructure interfaces, in inversion layers, in quantum wells and in superlattices is analyzed using the envelope function to illustrate the variety of interactions that must be properly accounted for. The formation of subbands in confinement, minibands in superlattices, and transmission, reflection and resonance at confined barriers and wells is discussed. Propagation, screening, scattering and the behavior of shallow dopants are discussed to illustrate changes with reduction of dimensions. Particular emphasis is placed on optical transitions to illustrate the changes in selection rules for interband and intraband transitions. Confined semiconductors are contrasted with monolayer semiconductors, using graphene and nanotubes as examples whose analysis and electronic properties are discussed, to compare them with the semiconductor discussions in earlier chapters.

Author(s):  
Vurgaftman Igor

The chapter shows how the bulk theory described in Part I can be generalized within the envelope-function framework to model the band structure of layered materials with quantum confinement of carriers such as quantum wells or superlattices. In practice, the approach amounts to substituting derivatives for wavevector components in suitably chosen Hamiltonians as well as augmenting them with interface terms. It also discusses the spin splitting of the states of the quantum structures that arises from structural and intrinsic asymmetries.


1995 ◽  
Vol 379 ◽  
Author(s):  
Kamakhya P. Ghatak ◽  
B. Nag ◽  
G. Mazumder

ABSTRACTIn this paper we have studied the photoemission from quantum wells (QW), quantum wells wires (QWWs) and quantum dots (QDs) of quantum confined strained III–V compounds on the basis of a newly formulated electron dispersion law. It is found taking such quantum confined Hg1–xCdxTe and In1–xGaxAsyP1–y lattice matched InP as examples that the photoemission increases with increasing energy of the incident photons in a ladder like manner and also exhibits oscillatory dependences with changing electron concentration and film thickness respectively for all types quantum confinement. The photoemitted current is greatest in strained QDs and least in unstrained QWs. In addition the theoretical results are in agreement with the experimental datas as given elsewhere.


1992 ◽  
Vol 281 ◽  
Author(s):  
N. Saidi ◽  
K. Zitouni ◽  
A. Kadri

ABSTRACTUsing the envelope function formalism and the effective mass thecry, we have studied the E(k) energy dispersion and the confinement energies of the lower lying conduction band and the higher lying valence bands states in GaAs /GaAlAs Single Qantum Well (SQW) structures grown on GaAs substrates with different orientations of the growth axis :(001),(111),and (113). Then, the valence subbands dispersions are calculated away from the zone center for a given well width and under uniaxial stress for the three different growth directions


2021 ◽  
Author(s):  
Marius Buerkle ◽  
Mickäel Lozac’h ◽  
Davide Mariotti ◽  
Vladimir Svrcek

Abstract We discuss the electronic properties of quantum-confined nanocrystals. In particular, we show how, starting from the discrete molecular states of small nanocrystals, an approximate band structure (quasi-band structure) emerges with increasing particle size. Finite temperature is found to broaden the discrete states in energy space forming even for nanocrystals in the quantum-confinement regime quasi-continuous bands in k-space. This bands can be, to a certain extend, interpreted along the lines of standard band structure theory, while taking also finite size and surface effects into account. We discuss this on various prototypical nanocrystal systems.


2008 ◽  
Vol 93 (15) ◽  
pp. 152105 ◽  
Author(s):  
F. Stokker-Cheregi ◽  
A. Vinattieri ◽  
E. Feltin ◽  
D. Simeonov ◽  
J. Levrat ◽  
...  

1999 ◽  
Vol 09 (PR2) ◽  
pp. Pr2-37 ◽  
Author(s):  
O. Krebs ◽  
P. Voisin ◽  
D. Rondi ◽  
J. L. Gentner ◽  
L. Goldstein ◽  
...  

2005 ◽  
Vol 38 (4-6) ◽  
pp. 455-463 ◽  
Author(s):  
C. Morhain ◽  
X. Tang ◽  
M. Teisseire-Doninelli ◽  
B. Lo ◽  
M. Laügt ◽  
...  

Author(s):  
Jose Eduardo Barcelon ◽  
Marco Smerieri ◽  
Giovanni Carraro ◽  
Pawel Wojciechowski ◽  
Luca Vattuone ◽  
...  

Graphene nanoribbons (GNRs) are at the frontier of research on graphene materials since the 1D quantum confinement of electrons allows for the opening of an energy gap.


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