Quantum confinement and monolayer semiconductors
This chapter brings together several themes and perspectives by exploring them in quantum-confined conditions or in monolayer crystals. In it, confinement of electrons and holes at heterostructure interfaces, in inversion layers, in quantum wells and in superlattices is analyzed using the envelope function to illustrate the variety of interactions that must be properly accounted for. The formation of subbands in confinement, minibands in superlattices, and transmission, reflection and resonance at confined barriers and wells is discussed. Propagation, screening, scattering and the behavior of shallow dopants are discussed to illustrate changes with reduction of dimensions. Particular emphasis is placed on optical transitions to illustrate the changes in selection rules for interband and intraband transitions. Confined semiconductors are contrasted with monolayer semiconductors, using graphene and nanotubes as examples whose analysis and electronic properties are discussed, to compare them with the semiconductor discussions in earlier chapters.