Thermodynamic Processes

Author(s):  
Robert H. Swendsen

This chapter begins by defining terms critical to understanding thermodynamics: reversible, irreversible, and quasi-static. Because heat engines are central to thermodynamic principles, they are described in detail, along with their operation as refrigerators and heat pumps. Various expressions of efficiency for such engines lead to alternative expressions of the second law of thermodynamics. A Carnot cycle is discussed in detail as an example of an idealized heat engine with optimum efficiency. A special case, called negative temperatures, where temperatures actually exceed infinity, provides further insights. In this chapter we will discuss thermodynamic processes, which concern the consequences of thermodynamics for things that happen in the real world.

Author(s):  
H Hassanzadeh ◽  
S H Mansouri

In this paper, we accept the fact that fuel cell and heat engine efficiencies are both constrained by the second law of thermodynamics and neither one is able to break this law. However, we have shown that this statement does not mean the two systems should have the same maximum thermal efficiency when being fed by the same amounts of chemical reactants. The intrinsic difference between fuel cells (electrochemical systems) and heat engines (combustion engines) efficiencies is a fundamental one with regard to the conversion of chemical energy of reactions into electrical work. The sole reason has been shown to be due to the combustion irreversibility of the latter. This has led to the statement that fuel cell efficiency is not limited by the Carnot cycle. Clarity is achieved by theoretical derivations and several numerical examples.


2017 ◽  
Vol 8 ◽  
Author(s):  
Tomaž Kranjc ◽  
Nada Razpet

Students at all levels of physics instruction have difficulties dealing with energy, work and heat in general and, in particular, with the concepts of efficiency and ideal heat engine, and the maximum performance of refrigerators and heat pumps (Cochran & Heron, 2006; Bucher, 1986). The reason for the difficulties is an insufficient understanding of the second law of thermodynamics (Kesidou & Duit, 1992). In order to make these topics less difficult, the concept of exergy — well established as a powerful analytical tool in technical thermodynamics — describing the “quality” of energy, seems in our judgment to be worthy of inclusion in the physics curriculum at all levels. Its introduction does not add another law. It facilitates the understanding of irreversibilities (as the destruction of exergy) and gives a deeper meaning to the second law. In the treatment of heat engines the second-law efficiency throws a new light on the notions of an ideal and a real engine (similarly for a refrigerator or a heat pump). Exergy introduces, in a natural way, a distinction between various forms of energy according to its quality — availability for performing work. “Energy reserves”, which can be better understood with the help of exergy, are of practical interest. From the thermodynamic point of view, a more correct term would be “availability reserves”; all around us, there are huge quantities of energy (in atmosphere, in oceans etc), but of very limited availability, i.e., of limited exergy. In order to identify common misconceptions and difficulties encountered by students in the learning of the first and second law of thermodynamics, particularly in connection with heat engines and similar cyclic devices, we conducted a combined research among students of the Primary School Education at the Faculty of Education (UPR PeF) and of Biodiversity, Bioinformatics and Mediterranean Agriculture at the Faculty of Mathematics, Natural Sciences and Information Technologies (UPR FAMNIT) of the University of Primorska. Based on interviews and questionnaires given to two groups of students — an experimental and a control group — in the beginning and the end of the semester, we investigated the influence (and possible advantages) of the introduction of the concept of exergy and the second-law ficiency. In the presentation, we show a few examples that were treated with the experimental group in order to motivate the students and to make them familiar with the concept of exergy: the “energy losses” of a car engine and an analysis of improvements still allowed by nature; exergy loss associated with heat conduction; a simple exergy analysis of a heating house system (considering energy and exergy fluxes). We list some of the problems encountered by the students and the most common misconceptions as could be identified from the tests, questionnaires and interviews. An additional goal of the investigation is to test a longer-term knowledge of students. From our research it would appear that exergy and the second-law efficiency are useful concepts which make it possible for students to get a better grasp of the material and to not only obtain a clearer understanding and knowledge of standard topics like heat engines, but also a broader view and insight into the meaning of energy and both the first and the second law, and their interrelation.


Entropy ◽  
2021 ◽  
Vol 23 (5) ◽  
pp. 573
Author(s):  
Alexey V. Melkikh

Quantum entanglement can cause the efficiency of a heat engine to be greater than the efficiency of the Carnot cycle. However, this does not mean a violation of the second law of thermodynamics, since there is no local equilibrium for pure quantum states, and, in the absence of local equilibrium, thermodynamics cannot be formulated correctly. Von Neumann entropy is not a thermodynamic quantity, although it can characterize the ordering of a system. In the case of the entanglement of the particles of the system with the environment, the concept of an isolated system should be refined. In any case, quantum correlations cannot lead to a violation of the second law of thermodynamics in any of its formulations. This article is devoted to a technical discussion of the expected results on the role of quantum entanglement in thermodynamics.


Author(s):  
Dennis Sherwood ◽  
Paul Dalby

A chapter that draws together, and compares and contrasts, the principal alternative formulations of the Second Law – The Clausius statement, the Kelvin-Planck statement, the Carathéodory statement, and the Carnot cycle. This includes a discussion of heat engines and heat pumps, and of the efficiency of devices that transform heat into work.


Author(s):  
Pierre Meystre

This chapter addresses topics in quantum thermodynamics, where optomechanics may contribute attractive experimental tests and additional understanding. Quantum thermodynamics can be defined as the study of thermodynamics when quantum mechanical noise coexists with thermal noise and has a significant impact on the dynamics. This chapter focuses on the example of an optomechanical quantum heat engine (QHE). Section 11.2 reviews some questions about quantum work. Section 11.3 then outlines the steps leading to the formulation of continuous measurements in terms of stochastic Schrödinger equations. Section 11.4 reviews the main characteristics of QHE, comparing thermodynamic processes and engine cycles in the classical and quantum regimes. The opportunities offered by quasiparticles in the operation of QHE justify reviewing their properties in some detail (section 11.5), before introducing the optomechanical QHE system (section 11.6). Section 11.7 discusses the properties of the engine, and section 11.8 expands the discussion to polariton based quantum heat pumps.


Entropy ◽  
2021 ◽  
Vol 23 (7) ◽  
pp. 860
Author(s):  
Ivan R. Kennedy ◽  
Migdat Hodzic

Despite the remarkable success of Carnot’s heat engine cycle in founding the discipline of thermodynamics two centuries ago, false viewpoints of his use of the caloric theory in the cycle linger, limiting his legacy. An action revision of the Carnot cycle can correct this, showing that the heat flow powering external mechanical work is compensated internally with configurational changes in the thermodynamic or Gibbs potential of the working fluid, differing in each stage of the cycle quantified by Carnot as caloric. Action (@) is a property of state having the same physical dimensions as angular momentum (mrv = mr2ω). However, this property is scalar rather than vectorial, including a dimensionless phase angle (@ = mr2ωδφ). We have recently confirmed with atmospheric gases that their entropy is a logarithmic function of the relative vibrational, rotational, and translational action ratios with Planck’s quantum of action ħ. The Carnot principle shows that the maximum rate of work (puissance motrice) possible from the reversible cycle is controlled by the difference in temperature of the hot source and the cold sink: the colder the better. This temperature difference between the source and the sink also controls the isothermal variations of the Gibbs potential of the working fluid, which Carnot identified as reversible temperature-dependent but unequal caloric exchanges. Importantly, the engine’s inertia ensures that heat from work performed adiabatically in the expansion phase is all restored to the working fluid during the adiabatic recompression, less the net work performed. This allows both the energy and the thermodynamic potential to return to the same values at the beginning of each cycle, which is a point strongly emphasized by Carnot. Our action revision equates Carnot’s calorique, or the non-sensible heat later described by Clausius as ‘work-heat’, exclusively to negative Gibbs energy (−G) or quantum field energy. This action field complements the sensible energy or vis-viva heat as molecular kinetic motion, and its recognition should have significance for designing more efficient heat engines or better understanding of the heat engine powering the Earth’s climates.


Quantum ◽  
2019 ◽  
Vol 3 ◽  
pp. 177 ◽  
Author(s):  
Mischa P. Woods ◽  
Nelly Huei Ying Ng ◽  
Stephanie Wehner

Sadi Carnot's theorem regarding the maximum efficiency of heat engines is considered to be of fundamental importance in thermodynamics. This theorem famously states that the maximum efficiency depends only on the temperature of the heat baths used by the engine, but not on the specific structure of baths. Here, we show that when the heat baths are finite in size, and when the engine operates in the quantum nanoregime, a revision to this statement is required. We show that one may still achieve the Carnot efficiency, when certain conditions on the bath structure are satisfied; however if that is not the case, then the maximum achievable efficiency can reduce to a value which is strictly less than Carnot. We derive the maximum efficiency for the case when one of the baths is composed of qubits. Furthermore, we show that the maximum efficiency is determined by either the standard second law of thermodynamics, analogously to the macroscopic case, or by the non increase of the max relative entropy, which is a quantity previously associated with the single shot regime in many quantum protocols. This relative entropic quantity emerges as a consequence of additional constraints, called generalized free energies, that govern thermodynamical transitions in the nanoregime. Our findings imply that in order to maximize efficiency, further considerations in choosing bath Hamiltonians should be made, when explicitly constructing quantum heat engines in the future. This understanding of thermodynamics has implications for nanoscale engineering aiming to construct small thermal machines.


Author(s):  
W. John Dartnall ◽  
John Reizes

In a recently developed simple particle mechanics model, in which a single particle represents the working fluid, (gas) in a heat engine, (exemplified by a piston engine) a new approach was outlined for the teaching of concepts to thermodynamic students. By mechanics reasoning, a model was developed that demonstrates the connection between the Carnot efficiency limitation of heat engines, and the Kelvin-Planck statement of Second Law, requiring only the truth of the Clausius statement. In a second paper the model was extended to introduce entropy. The particle’s entropy was defined as a function of its kinetic energy, and the space that it occupies, that is analogous to that normally found in classical macroscopic analyses. In this paper, questions are raised and addressed: How should temperature and entropy be perceived and defined? Should temperature be proportional to average (molecular) translational kinetic energy and should entropy be dimensionless?


Sign in / Sign up

Export Citation Format

Share Document