Performance Measures of Heat Pumps Based on The Second Law of Thermodynamics

Author(s):  
K. Ozaki ◽  
N. Endo ◽  
A. Yabe
Author(s):  
Robert H. Swendsen

This chapter begins by defining terms critical to understanding thermodynamics: reversible, irreversible, and quasi-static. Because heat engines are central to thermodynamic principles, they are described in detail, along with their operation as refrigerators and heat pumps. Various expressions of efficiency for such engines lead to alternative expressions of the second law of thermodynamics. A Carnot cycle is discussed in detail as an example of an idealized heat engine with optimum efficiency. A special case, called negative temperatures, where temperatures actually exceed infinity, provides further insights. In this chapter we will discuss thermodynamic processes, which concern the consequences of thermodynamics for things that happen in the real world.


2017 ◽  
Vol 8 ◽  
Author(s):  
Tomaž Kranjc ◽  
Nada Razpet

Students at all levels of physics instruction have difficulties dealing with energy, work and heat in general and, in particular, with the concepts of efficiency and ideal heat engine, and the maximum performance of refrigerators and heat pumps (Cochran & Heron, 2006; Bucher, 1986). The reason for the difficulties is an insufficient understanding of the second law of thermodynamics (Kesidou & Duit, 1992). In order to make these topics less difficult, the concept of exergy — well established as a powerful analytical tool in technical thermodynamics — describing the “quality” of energy, seems in our judgment to be worthy of inclusion in the physics curriculum at all levels. Its introduction does not add another law. It facilitates the understanding of irreversibilities (as the destruction of exergy) and gives a deeper meaning to the second law. In the treatment of heat engines the second-law efficiency throws a new light on the notions of an ideal and a real engine (similarly for a refrigerator or a heat pump). Exergy introduces, in a natural way, a distinction between various forms of energy according to its quality — availability for performing work. “Energy reserves”, which can be better understood with the help of exergy, are of practical interest. From the thermodynamic point of view, a more correct term would be “availability reserves”; all around us, there are huge quantities of energy (in atmosphere, in oceans etc), but of very limited availability, i.e., of limited exergy. In order to identify common misconceptions and difficulties encountered by students in the learning of the first and second law of thermodynamics, particularly in connection with heat engines and similar cyclic devices, we conducted a combined research among students of the Primary School Education at the Faculty of Education (UPR PeF) and of Biodiversity, Bioinformatics and Mediterranean Agriculture at the Faculty of Mathematics, Natural Sciences and Information Technologies (UPR FAMNIT) of the University of Primorska. Based on interviews and questionnaires given to two groups of students — an experimental and a control group — in the beginning and the end of the semester, we investigated the influence (and possible advantages) of the introduction of the concept of exergy and the second-law ficiency. In the presentation, we show a few examples that were treated with the experimental group in order to motivate the students and to make them familiar with the concept of exergy: the “energy losses” of a car engine and an analysis of improvements still allowed by nature; exergy loss associated with heat conduction; a simple exergy analysis of a heating house system (considering energy and exergy fluxes). We list some of the problems encountered by the students and the most common misconceptions as could be identified from the tests, questionnaires and interviews. An additional goal of the investigation is to test a longer-term knowledge of students. From our research it would appear that exergy and the second-law efficiency are useful concepts which make it possible for students to get a better grasp of the material and to not only obtain a clearer understanding and knowledge of standard topics like heat engines, but also a broader view and insight into the meaning of energy and both the first and the second law, and their interrelation.


Author(s):  
A. M. Savchenko ◽  
Yu. V. Konovalov ◽  
A. V. Laushkin

The relationship of the first and second laws of thermodynamics based on their energy nature is considered. It is noted that the processes described by the second law of thermodynamics often take place hidden within the system, which makes it difficult to detect them. Nevertheless, even with ideal mixing, an increase in the internal energy of the system occurs, numerically equal to an increase in free energy. The largest contribution to the change in the value of free energy is made by the entropy of mixing, which has energy significance. The entropy of mixing can do the job, which is confirmed in particular by osmotic processes.


Author(s):  
Olivier Darrigol

This chapter recounts how Boltzmann reacted to Hermann Helmholtz’s analogy between thermodynamic systems and a special kind of mechanical system (the “monocyclic systems”) by grouping all attempts to relate thermodynamics to mechanics, including the kinetic-molecular analogy, into a family of partial analogies all derivable from what we would now call a microcanonical ensemble. At that time, Boltzmann regarded ensemble-based statistical mechanics as the royal road to the laws of thermal equilibrium (as we now do). In the same period, he returned to the Boltzmann equation and the H theorem in reply to Peter Guthrie Tait’s attack on the equipartition theorem. He also made a non-technical survey of the second law of thermodynamics seen as a law of probability increase.


2018 ◽  
Author(s):  
M. T. Nitsas ◽  
I. P. Koronaki ◽  
L. Prentza

The utilization of solar energy in thermal energy systems was and always be one of the most effective alternative to conventional energy resources. Energy efficiency is widely used as one of the most important parameters in order to evaluate and compare thermal systems including solar collectors. Nevertheless, the first law of thermodynamics is not solely capable of describing the quantitative and qualitative performance of such systems and thus exergy efficiency is used so as to introduce the systems’ quality. In this work, the performance of a flat plate solar collector using water based nanofluids of different nanoparticle types as a working fluid is analyzed theoretically under the climatic conditions in Greece based on the First and Second Law of Thermodynamics. A mathematical model is built and the model equations are solved iteratively in a MATLAB code. The energy and exergy efficiencies as well as the collector losses coefficient for various parameters such as the inlet temperature, the particles concentration and type are determined. Moreover, a dynamic model is built so as to determine the performance of a flat plate collector working with nanofluids and the useful energy that can be stored in a water tank. The exergy destruction and exergy leakage are determined for a typical day in summer during which high temperatures and solar intensity values are common for the Greek climate.


2021 ◽  
Vol 0 (0) ◽  
Author(s):  
Tasawar Hayat ◽  
Ikram Ullah ◽  
Ahmad Alsaedi ◽  
Shaher Momani

Abstract Our intention in this article is to investigate entropy optimization in nonlinear mixed convective unsteady magnetohydrodynamic flow of nanomaterials in porous space. An exponentially stretched sheet creates the liquid flow. Nanomaterial is considered electrically conducting. The concentration and energy expressions comprise viscous dissipation, Joule heating, thermophoresis and Brownian motion aspects. Arrhenius activation energy is considered. Computation of entropy generation based upon the second law of thermodynamics is made. Nonlinear partial expressions are obtained via suitable dimensionless variables. Resultant expressions are tackled by the OHAM technique. Features of numerous variables on entropy, temperature, velocity and concentration are graphically visualized. Skin friction and the temperature gradient at the surface are also elaborated. Comparative analysis is deliberated in tabulated form to validate the previously published outcomes. Velocity is reduced significantly via the suction parameter. The entropy rate increases for higher values of Brinkman, Biot and Hartmann numbers.


2020 ◽  
Vol 45 (2) ◽  
pp. 121-132
Author(s):  
Daniel P. Sheehan

AbstractCanonical statistical mechanics hinges on two quantities, i. e., state degeneracy and the Boltzmann factor, the latter of which usually dominates thermodynamic behaviors. A recently identified phenomenon (supradegeneracy) reverses this order of dominance and predicts effects for equilibrium that are normally associated with non-equilibrium, including population inversion and steady-state particle and energy currents. This study examines two thermodynamic paradoxes that arise from supradegeneracy and proposes laboratory experiments by which they might be resolved.


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