scholarly journals The Fate of Accessory Minerals and Key Trace Elements During Anatexis and Magma Extraction

2020 ◽  
Vol 61 (2) ◽  
Author(s):  
Martin Schwindinger ◽  
Roberto F Weinberg ◽  
Richard W White

Abstract Granite genesis and crustal evolution are closely associated with partial melting in the lower or middle crust and extraction of granite magmas to upper crustal levels. This is generally thought to be the leading mechanism by which the upper continental crust became enriched in incompatible components such as the heat-producing elements U and Th through time. However, field evidence from anatectic terrains, the source rocks of granite magmas, raises doubt about the efficiency of this process. Leucosomes and associated leucogranites, representative of melts in such terrains, are often depleted in U, Th and REE compared to their source and therefore unable to enrich the upper crust in these elements. This paper demonstrates using anatectic turbidites exposed on Kangaroo Island that accessory minerals, the main hosts of U, Th and REE, become preferentially concentrated in the melanosomes, effectively removing these elements from the melt. Whole rock geochemistry and detailed petrography suggests that (1) peraluminous melts dissolve only small fractions of monazite and xenotime, because efficient apatite dissolution saturates melt early in phosphorous; and (2) local melt–host reaction emerging from melt migration may cause melt to crystallize in the magma extraction channelways in or close to the magma source region. Crystallization causes oversaturation of the magma triggering crystallization and capture of accessory minerals in the growing biotite-rich selvedge rather than in the melt channel itself. Crystallization of accessory minerals away from the leucosome explains the apparent under-saturation of elements hosted by these accessory minerals in the leucosome and leucogranites. While intense reworking of thick piles of turbidites, common in accretionary orogens, reflect important processes of crustal formation, the fate of accessory phases and the key elements they control, such as the heat producing elements U and Th, are strongly dependent on the interaction between melt and surrounding solids during segregation and extraction.

2006 ◽  
Vol 144 (2) ◽  
pp. 361-378 ◽  
Author(s):  
PARAMPREET KAUR ◽  
NAVEEN CHAUDHRI ◽  
INGRID RACZEK ◽  
ALFRED KRÖNER ◽  
ALBRECHT W. HOFMANN

Determination of zircon ages as well as geochemical and Sm–Nd isotope systematics of granitoids in the Khetri Copper Belt of the Aravalli mountains, NW India, constrain the late Palaeoproterozoic crustal evolution of the Aravalli craton. The plutons are typical A-type within-plate granites, derived from melts generated in an extensional tectonic environment. They display REE and multi-element patterns characterized by steep LREE-enriched and almost flat HREE profiles and distinct negative anomalies for Sr, P and Ti. Initial εNd values range from −1.3 to −6.2 and correspond to crustal sources with mean crustal residence ages of 2.5 to 2.1 Ga. A lower mafic crustal anatectic origin is envisaged for these granitoids, and the heterogeneous εNd(t) values are inferred to have been acquired from the magma source region. Zircon Pb–Pb evaporation and U–Pb ages indicate widespread rift-related A-type magmatism at 1711–1660 Ma in the northern Delhi belt and also suggest a discrete older magmatic event at around 1800 Ma. The emplacement ages of the compositionally distinct A-type granitoid plutons, and virtually coeval granulite metamorphism and exhumation in another segment of the Aravalli mountains, further signify that part of the Aravalli crust evolved during a widespread extensional event in late Palaeoproterozoic time.


Chemical and O-, Sr-, Nd-, and Pb-isotope relations for the British Caledonian granitoids exhibit systematic variations that are attributed to derivation from both mantle and crustal sources. The ‘older’ (more than ca . 470 Ma) pre- and syn-tectonic granites were the product of local anatectic melting of Late Proterozoic metasedimentary upper crust (8 18 O æ 8 to 14% 0 , 87 S r/ 86 Sr > 0.710, 206 Pb / 204 Pb « 18.1-19.2) during the peak thermal conditions of the Grampian Orogeny. The ‘younger’ (less than ca . 440 Ma) post-tectonic granitoids have a complex origin which, in individual cases, involved at least four different source regions: (i) the upper mantle or subducted oceanic crust (8 18 O « 5.7 to 7.0%o, 87 Sr/ 86 Sr « 0.7035-0.7040, 206 Pb/ 204 Pb = 17.9 to 18.1) and (ii) Lower Palaeozoic geosynclinal sedimentary upper crust (8 18 O « 11 to 14% 0 , 87 Sr/ 86 Sr « 705-0.711, 206 Pb/ 204 Pb « 18.4) within the paratectonic Caledonides in the Scottish Midland Valley and Southern Uplands and in Northern England or (iii) Middle Proterozoic (?) mafic to intermediate granulitic lower crust (8 18 O « 8 to 10% 0 , 87 Sr/ 86 Sr « 0.705-0.707, 206 Pb / 204 Pb « 16.5-17.0) and (iv) Middle to Late Proterozoic metasedimentary upper crust (8 18 0 « 8 to 14% 0 , 87 Sr/ 86 Sr > 0.710, 206 Pb/ 207 Pb » 18.1-19.2) in the Scottish Highlands. Mantle-derived magmas or their direct derivatives were likely involved in the development of all of the ‘younger’ granitoids, either as end-member components or as the source for a substantial part of the heat required for crustal melting and assimilation. Although the Lower Palaeozoic was a time during which a large amount of igneous material was introduced into the upper crust in Britain, it was not a major crust-forming period because the Caledonian granitoids are dominated by recycled continental crust.


1989 ◽  
Vol 53 (369) ◽  
pp. 55-61 ◽  
Author(s):  
B. A. Paterson ◽  
W. E. Stephens ◽  
D. A. Herd

AbstractAccessory minerals are often difficult to investigate with light optics as the mineral grains tend to be small and the refractive indices high. Textural features due to variations in composition are well displayed in such minerals by backscattered electron imagery under circumstances designed to select only the composition contribution to electron backscattering and displayed as atomic number (Z)-contrast imagery (ZCI). It is shown by this technique that compositional zonation patterns are very common and sector zoning in titanite is described for the first time. The compositional basis for zonation of titanites in this study is shown to be controlled by coupled substitutions involving the REE. The technique is particularly good at revealing rounded cores to zircon grains which are normally taken to be refractory grains from the magma source region, and ZCI studies may improve targeting of grains for U-Pb geochronological investigations. Several examples are presented of applications of the technique to accessory minerals encountered in polished thin sections of granitoids in the Caledonian of Scotland. The consequences of ZCI studies for trace element modelling of REE in granitoid petrogenesis are discussed.


2019 ◽  
Vol 56 (10) ◽  
pp. 1003-1016
Author(s):  
Guosheng Sun ◽  
Tianxue Zhao ◽  
Ruixiang Jin ◽  
Qinghai Wang

We studied newly found high Nb–Ta alkaline rhyolites in the northern volcanic belt of the Great Xing’an Range, China. The LA–ICP–MS U–Pb weighted mean age is 114.07 ± 0.55 Ma, indicating that the rocks formed during the late Early Cretaceous and were the product of the late eruption of a Mesozoic volcano. The major element contents are characterized by high Si, rich K, low Fe, and poor Ca and Mg. In the total alkaline–silicon diagram, the sample points are in the alkaline rhyolite region. Meanwhile, rare earth elements show obvious Ce/Ce* positive anomalies and Eu/Eu* negative anomalies. In addition, trace elements are characterized by high Nb, Ta, and Yb, and low Sr. The two-stage Nd isotopic model age T2DM of the depleted mantle is between 799–813 Ma, indicating that the diagenetic material originated from the depleted mantle or partial melting of newly formed young crustal materials. The source rocks melted at a relative shallow depth (<30 km), under lower pressure (<0.5 Gpa) and high oxygen fugacity; moreover, the residues in the source region were Ca-rich mafic plagioclase + amphibole + orthopyroxene. In the Nb–Y–3Ga and Nb–Y–Ce diagrams, the sample points are in the A1 type region. It can be concluded that the mantle-derived basaltic magma underplated and supplied the heat sources for partial melting of the metamorphic crustal rocks in an intraplate extensional tectonic environment related to a rift, mantle plume, and hot spot.


2018 ◽  
Author(s):  
Hangyu Liu ◽  
◽  
N. Ryan McKenzie ◽  
Andrew J. Smye ◽  
Daniel F. Stockli

2015 ◽  
Vol 45 (1) ◽  
pp. 127-141 ◽  
Author(s):  
Hermínio Arias Nalini Júnior ◽  
Rômulo Machado ◽  
Essaid Bilal

The Urucum suite (582 ± 2 Ma, zircon U-Pb age), situated in the Mid-Rio Doce Valley, eastern part of Minas Gerais State, is characterized by elongated, NW-SE and N-S trending granitic massifs associated with the Conselho Peña-Resplendor high-angle shear zone. It corresponds to a syn to late collisional magmatism that presents dominant solid-state foliation. Four facies are distinguished within the Urucum suite: (i) a porphyritic (Urucum); (ii) a medium- to coarse nequigranular (Palmital); (iii) a tourmaline-bearing; and (iv) a pegmatitic facies. These facies are peraluminous, with alumina saturation index varying from 0.98 to 1.38. SiO2 contents vary from 70.7 to 73.7 wt%, with K2O values ranging from 3.5 to 5.7 wt%, Na2O from 1.9 to 4.4 wt%, MgO from 0.6 to 1.2 wt%, and CaO from 0.3 to 0.9%. Harker-type diagrams show rather continuous trends from the less-evolved Urucum facies to the more evolved tourmaline-bearing and pegmatitic facies. The behavior of several major oxides and trace elements (Fe2O3, MgO, MnO, CaO, TiO2, Al2O3, K2O, Rb and Ba) reflects the role played by fractionation of ferromagnesian minerals, feldspars and accessory minerals. Initial Sr87/Sr86 ratios vary from 0.711 to 0.716, with εNd (580 Ma) values between -7.4 to -8.2, and Sm-Nd TDM model ages ranging from 2290 to 1840 Ma.


Author(s):  
Peter I. Nabelek ◽  
Mian Liu

ABSTRACTLeucogranites are typical products of collisional orogenies. They are found in orogenic terranes of different ages, including the Proterozoic Trans-Hudson orogen, as exemplified in the Black Hills, South Dakota, and the Appalachian orogen in Maine, both in the USA, and the ongoing Himalayan orogen. Characteristics of these collisional leucogranites show that they were derived from predominantly pelitic sources at the veining stages of deformation and metamorphism in upper plates of thickened crusts. Once generated, the leucogranite magmas ascended as dykes and were emplaced within shallower parts of their source sequences. In these orogenic belts, there was a strong connection between deformation, metamorphism and granite generation. However, the heat sources needed for partial melting of the source rocks remain controversial. Lack of evidence for significant intrusion of mafic magmas necessary to cause melting of upper plate source rocks suggests that leucogranite generation in collisional orogens is mainly a crustal process.The present authors evaluate five types of thermal models which have previously been proposed for generating leucogranites in collisional orogens. The first, a thickened crust with exponentially decaying distribution of heat-producing radioactive isotopes with depth, has been shown to be insufficient for heating the upper crust to melting conditions. Four other models capable of raising the crustal temperatures sufficiently to initiate partial melting of metapelites in thickened crust include: (1) thick sequences of sedimentary rocks with high amounts of internal radioactive heat production; (2) decompression melting; (3) thinning of mantle lithosphere; and (4) shear-heating. The authors show that, for reasonable boundary conditions, shear-heating along crustal-scale shear zones is the most viable process to induce melting in upper plates of collisional orogens where pelitic source lithologies are usually located. The shear-heating model directly links partial melting to the deformation and metamorphism that typically precede leucogranite genera


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