scholarly journals New Thermodynamic Models and Calculated Phase Equilibria in NCFMAS for Basic and Ultrabasic Compositions through the Transition Zone into the Uppermost Lower Mantle

2013 ◽  
Vol 54 (9) ◽  
pp. 1901-1920 ◽  
Author(s):  
T. J. B. Holland ◽  
N. F. C. Hudson ◽  
R. Powell ◽  
B. Harte
2020 ◽  
Vol 989 ◽  
pp. 204-209 ◽  
Author(s):  
Gennady G. Mikhailov ◽  
L.A. Makrovets ◽  
O.V. Samoilova

Thermodynamic modeling of phase equilibria and further construction of a full projection of the liquidus surface in the FeO–Al2O3–Cr2O3 and MgO–Al2O3–Cr2O3 systems were carried out. Theories of sub-regular ionic solutions, regular ionic solutions and ideal ionic solutions were used for calculation. Values of energy parameters of the used thermodynamic models were obtained in the course of the research. These values might be applicable for further modeling of more complex oxide slag systems which are formed in the process of manufacture of chromic steels. Calculated phase diagrams for the FeO–Al2O3–Cr2O3 and MgO–Al2O3–Cr2O3 systems were compared with available data from literature sources.


RSC Advances ◽  
2015 ◽  
Vol 5 (112) ◽  
pp. 92270-92291 ◽  
Author(s):  
M. Gürth ◽  
A. Grytsiv ◽  
J. Vrestal ◽  
V. V. Romaka ◽  
G. Giester ◽  
...  

Experimental and calculated phase equilibria for the system Ti–Ni–Sn.


2021 ◽  
Author(s):  
Oluwakemi Victoria Eniolorunda ◽  
Antonin Chapoy ◽  
Rod Burgass

Abstract In this study, new experimental data using a reliable approach are reported for solid-fluid phase equilibrium of ternary mixtures of Methane-Carbon-dioxide- n-Hexadecane for 30-73 mol% CO2 and pressures up to 24 MPa. The effect of varying CO2 composition on the overall phase transition of the systems were investigated. Three thermodynamic models were used to predict the liquid phase fugacity, this includes the Peng Robison equation of state (PR-EoS), Soave Redlich-Kwong equation of state (SRK-EoS) and the Cubic plus Association (CPA) equation of state with the classical mixing rule and a group contribution approach for calculating binary interaction parameters in all cases. To describe the wax (solid) phase, three activity coefficient models based on the solid solution theory were investigated: the predictive universal quasichemical activity coefficients (UNIQUAC), Universal quasi-chemical Functional Group activity coefficients (UNIFAC) and the predictive Wilson approach. The solid-fluid equilibria experimental data gathered in this experimental work including those from saturated and under-saturated conditions were used to check the reliability of the various phase equilibria thermodynamic models.


1998 ◽  
Vol 20 (4) ◽  
pp. 163-169 ◽  
Author(s):  
Eiji OHTANI ◽  
Yasuhiro KUDOH ◽  
Hiroshi NAITO ◽  
Haruo ARASHI

2007 ◽  
Vol 260 (1-2) ◽  
pp. 1-9 ◽  
Author(s):  
Frank E. Brenker ◽  
Christian Vollmer ◽  
Laszlo Vincze ◽  
Bart Vekemans ◽  
Anja Szymanski ◽  
...  
Keyword(s):  

1980 ◽  
Vol 70 (2) ◽  
pp. 487-508
Author(s):  
Sonja Faber ◽  
Gerhard MÜller

abstract Precursors to S and SKS were observed in long-period SRO and WWSSN seismograms of the Romanian earthquake of March 4, 1977, recorded in the United States at distances from 68° to 93°. According to the fault-plane solution, the stations were close to a nodal plane and SV radiation was optimum in their direction. Particle-motion diagrams, constructed from the digital data of the SRO station ANMO (distance 89.1°), show the P-wave character of the precursors. Several interpretations are discussed; the most plausible is that the precursors are Sp phases generated by conversion from S to P below the station. The travel-time differences between S or SKS and Sp are about 60 sec and indicate conversion in the transition zone between the upper and lower mantle. Sp conversions were also observed at long-period WWSSN stations in the western United States for 2 Tonga-Fiji deep-focus earthquakes (distances from 82° to 96°). Special emphasis is given in this paper to the calculation of theoretical seismograms, both for Sp precursors and the P-wave coda, including high-order multiples such as sP4 which may arrive simultaneously with Sp. The Sp calculations show: (1) the conversions produced by S, ScS, and SKS at interfaces or transition zones between the upper and lower mantle form a complicated interference pattern, and (2) conversion at transition zones is less effective than at first-order discontinuities only if their thickness is greater than about half a wavelength of S waves. As a consequence, details of the velocity structure between the upper and lower mantle can only be determined within these limits from long-period Sp observations. Our observations are compatible with velocity models having pronounced transition zones at depths of 400 and 670 km as have been proposed for the western United States, and they exclude much smoother structures. Our study suggests that long-period Sp precursors from pure thrust or normal-fault earthquakes, observed at distances from 70° to 95° close to a nodal plane and at azimuths roughly perpendicular to its strike, offer a simple means for qualitative mapping of the sharpness of the transition zones between the upper and lower mantle.


Elements ◽  
2020 ◽  
Vol 16 (6) ◽  
pp. 381-387 ◽  
Author(s):  
Katy A. Evans ◽  
Andrew G. Tomkins

Metamorphic reactions within the Earth’s crust produce fluids of variable composition that play a major role in the evolution of continents. Metamorphic fluids facilitate reactions that alter crustal rheology, reduce melting temperature, cycle elements between geological reservoirs and form ore deposits. These fluids are relatively inaccessible, other than by study of fluid inclusions, so most studies rely on a combination of indirect evidence and predictive thermodynamic models to determine the characteristics and roles of the fluids. In this article, the origins, compositions, controlling phase equilibria, and roles of metamorphic fluids are reviewed, followed by a discussion of selected areas of current and future research.


2019 ◽  
Vol 117 (1) ◽  
pp. 184-189 ◽  
Author(s):  
Yanhao Lin ◽  
Qingyang Hu ◽  
Yue Meng ◽  
Michael Walter ◽  
Ho-Kwang Mao

The distribution and transportation of water in Earth’s interior depends on the stability of water-bearing phases. The transition zone in Earth’s mantle is generally accepted as an important potential water reservoir because its main constituents, wadsleyite and ringwoodite, can incorporate weight percent levels of H2O in their structures at mantle temperatures. The extent to which water can be transported beyond the transition zone deeper into the mantle depends on the water carrying capacity of minerals stable in subducted lithosphere. Stishovite is one of the major mineral components in subducting oceanic crust, yet the capacity of stishovite to incorporate water beyond at lower mantle conditions remains speculative. In this study, we combine in situ laser heating with synchrotron X-ray diffraction to show that the unit cell volume of stishovite synthesized under hydrous conditions is ∼2.3 to 5.0% greater than that of anhydrous stishovite at pressures of ∼27 to 58 GPa and temperatures of 1,240 to 1,835 K. Our results indicate that stishovite, even at temperatures along a mantle geotherm, can potentially incorporate weight percent levels of H2O in its crystal structure and has the potential to be a key phase for transporting and storing water in the lower mantle.


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