scholarly journals Controllable synthesis of pomelo peel-based aerogel and its application in adsorption of oil/organic pollutants

2019 ◽  
Vol 6 (2) ◽  
pp. 181823 ◽  
Author(s):  
Guangyu Shi ◽  
Yizhu Qian ◽  
Fengzhi Tan ◽  
Weijie Cai ◽  
Yuan Li ◽  
...  
Keyword(s):  
High Speed ◽  
Chemical Properties ◽  
Absorption Capacity ◽  
High Porosity ◽  
X Ray Diffraction ◽  
Water Separation ◽  
Physico Chemical ◽  
Wide Range ◽  
Oil Water Separation ◽  
Oil Water

Oil/water separation is a field of high significance as it might efficiently resolve the contamination of industrial oily wastewater and other oil/water pollution. In this paper, an environmentally-friendly hydrophobic aerogel with high porosity and low density was successfully synthesized with renewable pomelo peels (PPs) as precursors. Typically, a series of sponge aerogels (HPSA-0, HPSA-1 and HPSA-2) were facilely prepared via high-speed dispersion, freeze-drying and silanization with methyltrimethoxysilane. Indeed, the physical properties of aerogel such as density and pore diameter could be tailored by different additives (filter paper fibre and polyvinyl alcohol). Hence, their physico-chemical properties including internal morphology and chemical structure were characterized in detail by Fourier transform infrared, Brunauer–Emmett–Teller, X-ray diffraction, scanning electron microscope, Thermal gravimetric analyzer (TG) etc. Moreover, the adsorption capacity was further determined and the results revealed that the PP-based aerogels presented excellent adsorption performance for a wide range of oil products and/or organic solvents (crude oil 49.8 g g −1 , soya bean oil 62.3 g g −1 , chloroform 71.3 g g −1 etc.). The corresponding cyclic tests showed the absorption capacity decreased slightly from 94.66% to 93.82% after 10 consecutive cycles, indicating a high recyclability.

scholarly journals Carbon Nanotubes and Polydopamine Modified Poly(dimethylsiloxane) Sponges for Efficient Oil–Water Separation

Materials ◽  
2021 ◽  
Vol 14 (9) ◽  
pp. 2431
Author(s):  
Wen Zhang ◽  
Juanjuan Wang ◽  
Xue Han ◽  
Lele Li ◽  
Enping Liu ◽  
...  
Keyword(s):  
Carbon Nanotubes ◽  
Large Scale ◽  
Absorption Capacity ◽  
Potential Candidate ◽  
Hard Template ◽  
Water Separation ◽  
Industrial Oil ◽  
The Matrix ◽  
Oil Water Separation ◽  
Oil Water

In this paper, effective separation of oil from both immiscible oil–water mixtures and oil-in-water (O/W) emulsions are achieved by using poly(dimethylsiloxane)-based (PDMS-based) composite sponges. A modified hard template method using citric acid monohydrate as the hard template and dissolving it in ethanol is proposed to prepare PDMS sponge composited with carbon nanotubes (CNTs) both in the matrix and the surface. The introduction of CNTs endows the composite sponge with enhanced comprehensive properties including hydrophobicity, absorption capacity, and mechanical strength than the pure PDMS. We demonstrate the successful application of CNT-PDMS composite in efficient removal of oil from immiscible oil–water mixtures within not only a bath absorption, but also continuous separation for both static and turbulent flow conditions. This notable characteristic of the CNT-PDMS sponge enables it as a potential candidate for large-scale industrial oil–water separation. Furthermore, a polydopamine (PDA) modified CNT-PDMS is developed here, which firstly realizes the separation of O/W emulsion without continuous squeezing of the sponge. The combined superhydrophilic and superoleophilic property of PDA/CNT-PDMS is assumed to be critical in the spontaneously demulsification process.

scholarly journals Complex Aerogels Generated from Nano-Polysaccharides and Its Derivatives for Oil–Water Separation

Polymers ◽  
2019 ◽  
Vol 11 (10) ◽  
pp. 1593 ◽  
Author(s):  
Hajo Yagoub ◽  
Liping Zhu ◽  
Mahmoud H. M. A. Shibraen ◽  
Ali A. Altam ◽  
Dafaalla M. D. Babiker ◽  
...  
Keyword(s):  
Guar Gum ◽  
Corn Oil ◽  
Cellulose Nanofibers ◽  
Aqueous Media ◽  
Three Dimensional ◽  
Absorption Capacity ◽  
Water Contact ◽  
Water Separation ◽  
Oil Water Separation ◽  
Oil Water

The complex aerogel generated from nano-polysaccharides, chitin nanocrystals (ChiNC) and TEMPO-oxidized cellulose nanofibers (TCNF), and its derivative cationic guar gum (CGG) is successfully prepared via a facile freeze-drying method with glutaraldehyde (GA) as cross-linkers. The complexation of ChiNC, TCNF, and CGG is shown to be helpful in creating a porous structure in the three-dimensional aerogel, which creates within the aerogel with large pore volume and excellent compressive properties. The ChiNC/TCNF/CGG aerogel is then modified with methyltrichlorosilane (MTCS) to obtain superhydrophobicity/superoleophilicity and used for oil–water separation. The successful modification is demonstrated through FTIR, XPS, and surface wettability studies. A water contact angle of 155° on the aerogel surface and 150° on the surface of the inside part of aerogel are obtained for the MTCS-modified ChiNC/TCNF/CGG aerogel, resulting in its effective absorption of corn oil and organic solvents (toluene, n-hexane, and trichloromethane) from both beneath and at the surface of water with excellent absorption capacity (i.e., 21.9 g/g for trichloromethane). More importantly, the modified aerogel can be used to continuously separate oil from water with the assistance of a vacuum setup and maintains a high absorption capacity after being used for 10 cycles. The as-prepared superhydrophobic/superoleophilic ChiNC/TCNF/CGG aerogel can be used as a promising absorbent material for the removal of oil from aqueous media.

scholarly journals Fabricated of Superhydrophobic Silanized Melamine Sponge with Photochromic Properties for Efficiency Oil/Water Separation

2019 ◽  
Vol 2019 ◽  
pp. 1-8 ◽  
Author(s):  
Peng Hong ◽  
Zhu Liu ◽  
Yang Gao ◽  
Yubin Chen ◽  
Mingxun Zhuang ◽  
...  
Keyword(s):  
Large Scale ◽  
Separation Efficiency ◽  
Low Cost ◽  
Water Repellency ◽  
Dip Coating ◽  
Absorption Capacity ◽  
Photochromic Properties ◽  
Water Separation ◽  
Oil Water Separation ◽  
Oil Water

Superhydrophobic sponge as potential absorbing material for oil/water separation is attracting great attention recently. However, there are still some challenges to feasibly fabricate superhydrophobic sponge with large scale and low cost. Herein, a novel photochromic superhydrophobic melamine sponge (PDMS-SP sponge) is fabricated by facilely dip-coating and thermocuring of hydroxyl-terminated polydimethylsiloxanes mixed with photochromic spiropyran. FT-IR, EDS, and XPS results confirm the successful coating of PDMS-SP upon melamine sponge. The resultant sponge not only possesses excellent water repellency with a contact angle of 154.5° and oil-water separation efficiency with an oil absorption capacity of 48–116 folds of itself weight, but also shows photochromic phenomenon between colorless and purple when it is successively exposed to UV irradiation and visible light.

Experimental Research on the Effect of Heating Temperature, Demulsifier Dose and Water Cut on the Oil-Water Separation in Three-Phase Separator

2018 ◽  
Author(s):  
Ang Li ◽  
Jianfeng Bai ◽  
Yun Shen ◽  
Hang Jin ◽  
Wei Wang ◽  
...  
Keyword(s):  
Heating Temperature ◽  
High Water ◽  
Water Mixture ◽  
Water Separation ◽  
Three Phase ◽  
Wide Range ◽  
Oil Water Separation ◽  
Oil Water ◽  
Water Cut ◽  
Phase Separator

The three-phase separator has a wide range of applications in oil production industry. For the purpose of studying the effect of heating temperature, demulsifiers and water content on the separation of oil-water mixture in the three-phase separator, eight kinds of oil samples were taken from different oil transfer stations in Changqing Oilfield and the mixtures were prepared by stirring method. To simulate the two-stage dehydration process, the first stage dehydration experiments without any heating were performed on mixtures at the dose of 100ppm demulsifer at 20°C, and the water cut of these mixtures is the same as that of the gathering pipeline in each oil transfer station. The water cut of the upper crude oil was measured after 40 minutes, and the values of them ranged from 0.5 vol% to 65.2 vol%. No visual stratification was observed for the sample most difficult to separate, so it was selected to conduct the second stage dewatering process. Three bottles of the same mixture were prepared and heated to 30°C, 40°C and 50°C, respectively. The results showed that all of them stratified in 10 minutes, and the water-cut values of the upper oil layer were 1.4 vol%, 0.5 vol% and 0.3 vol%, respectively, compared to 65.2 vol% at 20°C. When the concentration of demulsifier was changed to 200ppm and 300ppm, the results exhibited almost no differences. So it is deduced that the further improvement of heating temperature and demulsifier dose have limited enhancement on oil-water separation. At Last, 35 vol%, 50 vol%, 70 vol% and 85 vol% water cut mixtures of the special oil sample were made to experiment as previously. In consequence, the 35 vol% water-cut emulsions presented a relatively slow rate of oil-water stratification at low heating temperature, and the oil content of the lower separated water was improved by the addition of demulsifier dosage above 100ppm when the water cut was 90 vol%. It is indicated that high heating temperature is necessarry for low water-cut mixtures oil-water separation and can be appropriately reduced to save energy consumption as the water cut continues to rise. The demulsifier dosage is also neccessary be controlled in high water cut period. These experimental data provide the basis for the further optimization operation of the three-phase separator.

scholarly journals Preparation and Characterization of Tris(trimethylsiloxy)silyl Modified Polyurethane Acrylates and Their Application in Textile Treatment

Polymers ◽  
2020 ◽  
Vol 12 (8) ◽  
pp. 1629
Author(s):  
Xuecheng Yu ◽  
Ying Xiong ◽  
Zhen Li ◽  
Hongding Tang
Keyword(s):  
Microphase Separation ◽  
Triethylene Glycol ◽  
Absorption Capacity ◽  
Attenuated Total Reflection ◽  
Water Mixture ◽  
Water Contact ◽  
Water Separation ◽  
Cotton Textiles ◽  
Oil Water Separation ◽  
Oil Water

Three series of silicone modified polyurethane acrylate (SPUA) prepolymers were prepared from dicyclohexylmethane-4, 4′-diisocyanate (HMDI), PPG1000, triethylene glycol (TEG), 2-hydroxyethyl acrylate (HEA), and multi-hydroxyalkyl silicone (MI-III) with tris(trimethylsiloxy)silyl propyl side groups. Their structures were confirmed by 1H NMR, 13C NMR, and Fourier transformed infrared (FTIR) analysis, and SPUA films were obtained by UV curing. The properties of films were investigated by attenuated total reflection (ATR)-FTIR, scanning electron microscopy (SEM), energy dispersive X-ray spectroscopy (EDS), water contact angle (WCA), thermogravimetric analysis (TGA), differential scanning calorimeter (DSC), water and hexane resistance, and tensile testing. The results showed that the structures and dosages of MI-III could influence the polymerization properties, surface properties, water and n-hexane resistance, and thermal and tensile properties of SPUA. For instance, the surface aggregation of tris(trimethylsiloxy)silyl propyl groups (even ~2.5 wt%) could endow SPUA films with less microphase separation, good hydrophobicity, lipophilicity, thermal stability, and mechanical properties. Interestingly, obvious regular winkles appeared on the surfaces of SPUAIII films, which are characterized by relatively high WCA values. However, relatively smooth were observed on the surfaces of SPUAIII films, which also exhibit lower water absorption ratio values. Furthermore, the ordinary cotton textiles would be transformed into hydrophobic and oleophilic textiles after treating with SPUA simply, and they were used in the oil/water separation study. Among them, consistent with water and hexane resistance analysis of SPUA films, SPUAII treated cotton textiles are characterized by relatively small liquid absorption capacity (LAC) values. Thus, phenyl groups and side-chain tris(trimethylsiloxy)silyl propyl groups are helpful to improve the hydrophobicity and lipophilicity of SPUA films. SPUAII-5 (even with 5 wt% MII) treated cotton textiles could efficiently separate the oil/water mixture, such as n-hexane, cyclohexane, or methylbenzene with water. Thus, this material has great potential in the application of hydrophobic treatment, oil/water separation, and industrial sewage emissions, among others.

Graphene foam with hierarchical structures for the removal of organic pollutants from water

RSC Advances ◽  
2016 ◽  
Vol 6 (6) ◽  
pp. 4889-4898 ◽  
Author(s):  
Sudong Yang ◽  
Lin Chen ◽  
Lei Mu ◽  
Bin Hao ◽  
Junteng Chen ◽  
...  
Keyword(s):  
Thermal Stability ◽  
Organic Pollutants ◽  
Hierarchical Structure ◽  
Hierarchical Structures ◽  
High Porosity ◽  
Water Separation ◽  
Graphene Foam ◽  
Excellent Thermal Stability ◽  
Oil Water Separation ◽  
Oil Water

Graphene foam with hierarchical structure was prepared. The developed material exhibited high porosity, hydrophobicity, excellent thermal stability, and can be for oil–water separation.

scholarly journals A Robust Superhydrophobic Polyurethane Sponge Loaded with Multi-Walled Carbon Nanotubes for Efficient and Selective Oil-Water Separation

Nanomaterials ◽  
2021 ◽  
Vol 11 (12) ◽  
pp. 3344
Author(s):  
De Liu ◽  
Shiying Wang ◽  
Tao Wu ◽  
Yujiang Li
Keyword(s):  
Ionic Strength ◽  
Absorptive Capacity ◽  
Large Scale ◽  
Low Cost ◽  
Absorption Capacity ◽  
Effect Of Temperature ◽  
Water Contact ◽  
Water Separation ◽  
Oil Water Separation ◽  
Oil Water

The influence of different coupling agents and coupling times on the wettability of a polyurethane (PU) sponge surface were optimized. Octadecyltrichlorosilane (OTS) was selected as the optimal coupling agent to prepare the superhydrophobic sponge. The superhydrophobic sponge was prepared in one step, which has the advantages of simple operation and enhanced durability. The superhydrophobic sponge was characterized by scanning electron microscopy, Teclis Tracker tensiometry, and Fourier transform infrared (FT-IR) spectrophotometry. The water contact angle increased from 64.1° to 151.3°, exhibiting ideal superhydrophobicity. Oils and organic solvents with different viscosities and densities can be rapidly and selectively absorbed by superhydrophobic sponges, with an absorption capacity of 14.99 to 86.53 times the weight of the sponge itself, without absorbing any water. Since temperature affects the viscosity and ionic strength of oil, and influences the surface wettability of the sponges, the effect of temperature and ionic strength on the oil absorption capacity of the superhydrophobic sponges was measured, and its mechanism was elucidated. The results showed that the absorptive capacity retained more than 90% of the initial absorptive capacity after repeated use for 10 times. Low-cost, durable superhydrophobic sponges show great potential for large-scale oil-water separation.

scholarly journals Robust and continuous oil/water separation with superhydrophobic glass microfiber membrane by vertical polymerization under harsh conditions

2020 ◽  
Vol 10 (1) ◽  
Author(s):  
Seeun Woo ◽  
Hong Ryul Park ◽  
Jinyoung Park ◽  
Johan Yi ◽  
Woonbong Hwang
Keyword(s):  
Low Cost ◽  
Three Dimensional ◽  
High Water ◽  
Alkaline Solutions ◽  
Oxygen Plasma Treatment ◽  
Membrane Thickness ◽  
Water Separation ◽  
Wide Range ◽  
Oil Water Separation ◽  
Oil Water

AbstractWe report a robust and continuous oil/water separation with nanostructured glass microfiber (GMF) membranes modified by oxygen plasma treatment and self-assembled monolayer coating with vertical polymerization. The modified GMF membrane had a nanostructured surface and showed excellent superhydrophobicity. With an appropriate membrane thickness, a high water intrusion pressure (< 62.7 kPa) was achieved for continuous pressure-driven separation of oil/water mixtures with high flux (< 4418 L h−1 m−2) and high oil purity (> 99%). Under simulated industrial conditions, the modified GMF membrane exhibited robust chemical stability against strong acidic/alkaline solutions and corrosive environments. The proposed superhydrophobic composite coating technique is simple, low cost, environmentally friendly, and suitable for the mass production of scalable three-dimensional surfaces. Moreover, its stability and customizable functionality offers considerable potential for a wide range of novel applications.

High Porosity Supermacroporous Polystyrene Materials with Excellent Oil–Water Separation and Gas Permeability Properties

2015 ◽  
Vol 7 (12) ◽  
pp. 6745-6753 ◽  
Author(s):  
Shuzhen Yu ◽  
Hongyi Tan ◽  
Jin Wang ◽  
Xin Liu ◽  
Kebin Zhou
Keyword(s):  
Gas Permeability ◽  
High Porosity ◽  
Water Separation ◽  
Oil Water Separation ◽  
Oil Water

scholarly journals Facile Fabrication of Superhydrophobic Cross-Linked Nanocellulose Aerogels for Oil–Water Separation

Polymers ◽  
2021 ◽  
Vol 13 (4) ◽  
pp. 625
Author(s):  
Qianqian Shang ◽  
Jianqiang Chen ◽  
Yun Hu ◽  
Xiaohui Yang ◽  
Lihong Hu ◽  
...  
Keyword(s):  
Adsorption Capacity ◽  
Three Dimensional ◽  
Chemical Vapor ◽  
High Porosity ◽  
Water Contact ◽  
Water Separation ◽  
Cellular Microstructure ◽  
Oil Water Separation ◽  
Facile Fabrication ◽  
Oil Water

A facile and environmental-friendly approach was developed for the preparation of the cross-linked nanocellulose aerogel through the freeze-drying process and subsequent esterification. The as-prepared aerogel had a three-dimensional cellular microstructure with ultra-low density of 6.05 mg·cm−3 and high porosity (99.61%). After modifying by chemical vapor deposition (CVD) with hexadecyltrimethoxysilane (HTMS), the nanocellulose aerogel displayed stable super-hydrophobicity and super-oleophilicity with water contact angle of 151°, and had excellent adsorption performance for various oil and organic solvents with the adsorption capacity of 77~226 g/g. Even after 30 cycles, the adsorption capacity of the nanocellulose aerogel for chloroform was as high as 170 g/g, indicating its outstanding reusability. Therefore, the superhydrophobic cross-linked nanocellulose aerogel is a promising oil adsorbent for wastewater treatment.

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