scholarly journals The use of the coherer to investigate adsorption films

In spite of the former widespread use of the "coherer" or loose-contact detector of electric waves, and the numerous researches on its mode of action, no systematic investigation appears to have been undertaken to ascertain the effect on the detector of the gas surrounding the contact. Branly and others suggested that the cohering effect under electric stress across the contact might be due to the dispersion of a badly-conducting film originally lying between the metal surfaces at the point of contact. This hypothesis appears to be con­firmed by the results described below, which indicate not only a highly specific effect for each gas, but an effect in agreement with the known phenomena of adsorption of gases at solid surfaces. The possibility that additional information might be obtained about the stability and formation of these films was the incentive to the present work. The theory of Eccles, founded upon the thermo-electric properties of the metals in contact and depending upon temperature changes at the point of contact, seems to be untenable when it is found that cohering action can certainly occur with a frequency of 10 6 times a second. In the investigation described below, contacts between fine tungsten filaments taken from an old lamp, between platinum filaments, and between carbon-tungsten surfaces were studied. The first named material is admirably suited for these experiments, which are held to depend upon the formation of films of adsorbed gas, as by reason of its very refractory properties it can be raised to a high temperature in order to clean the surface. In addition there is the advantage that the filaments must have been exceptionally well glowed-out during the working of the lamp of which they formed a part. The same advantage applies to the carbon filament used.

2018 ◽  
Author(s):  
Cory Simon ◽  
carlo carraro

<div>In the two-balloon experiment, two rubber balloons are connected and allowed to exchange gas. Owing to the non-monotonic relationship between the radius of the balloon and the pressure of gas inside of it, the two-balloon system presents multi- and in-stabilities.</div><div><br></div><div>Herein, we consider a two-adsorbent system, where two different adsorbents are allowed to exchange gas. We show that, for rigid adsorbents, the thermodynamic equilibrium state is unique.</div><div><br></div><div>Then, we consider an adsorbent-balloon system, where an adsorbent exchanges gas with a rubber balloon. This system can exhibit multiple states at thermodynamic equilibrium-- two (meta)stable and one unstable. The size of the balloon, pressure of gas in the balloon, and partitioning of gas between the adsorbent and the balloon differ among the equilibrium states. Temperature changes and the addition/removal of gas into/from the adsorbent-balloon system can induce catastrophe bifurcations and show hysteresis. Furthermore, the adsorbent-balloon system exhibits a critical temperature where, when approached from below, the discrepancy of balloon size between the two (meta)stable states decreases and, beyond, bistability is impossible.</div><div><br></div><div>Practically, our findings preclude multiple partitions of adsorbed gas in rigid mixed-linker metal-organic frameworks and may inspire new soft actuator and sensor designs.</div>


2011 ◽  
Vol 39 (1) ◽  
pp. 220 ◽  
Author(s):  
Adesola L. NASSIR ◽  
Omolayo J. ARIYO

Twelve rice varieties were cultivated in inland hydromorphic lowland over a four year-season period in tropical rainforest ecology to study the genotype x environment (GxE) interaction and yield stability and to determine the agronomic and environmental factors responsible for the interaction. Data on yield and agronomic characters and environmental variables were analyzed using the Additive Main Effect and Multiplicative Interaction (AMMI), Genotype and Genotype x Environment Interaction, GGE and the yield stability using the modified rank-sum statistic (YSi). AMMI analysis revealed environmental differences as accounting for 47.6% of the total variation. The genotype and GxE interaction accounted for 28.5% and 24% respectively. The first and second interaction axes captured 57% and 30% of the total variation due to GXE interaction. The analysis identified ‘TOX 3107’ as having a combination of stable and average yield. The GGE captured 85.8%of the total GxE. ‘TOX 3226-53-2-2-2’ and ‘ITA 230’ were high yielding but adjudged unstable by AMMI. These two varieties along with ‘WITA 1’ and ‘TOX 3180-32-2-1-3-5’ were identified with good inland swamp environment, which is essentially moisture based. The two varieties (‘TOX 3226-53-2-2-2’ and ‘ITA 230’), which were equally considered unstable in yield by the stability variance, ?2i, were selected by YSi in addition to ‘TOX 3107’, ‘WITA 1’, ‘IR 8’ and ‘M 55’. The statistic may positively complement AMMI and GGE in selecting varieties suited to specific locations with peculiar fluctuations in environmental indices. Correlation of PC scores with environmental and agronomic variables identified total rainfall up to the reproductive stage, variation in tillering ability and plant height as the most important factors underlying the GxE interaction. Additional information from the models can be positively utilized in varietal development for different ecologies.


Author(s):  
Wei Ge ◽  
Ning Yang ◽  
Wei Wang ◽  
Jinghai Li

The drag interaction between gas and solids not only acts as a driving force for solids in gas-solids flows but also plays as a major role in the dissipation of the energy due to drag losses. This leads to enormous complexities as these drag terms are highly non-linear and multiscale in nature because of the variations in solids spatio-temporal distribution. This chapter provides an overview of this important aspect of the hydrodynamic interactions between the gas and solids and the role of spatio-temporal heterogeneities on the quantification of this drag force. In particular, a model is presented which introduces a mesoscale description into two-fluid models for gas-solids flows. This description is formulated in terms of the stability of gas-solids suspension. The stability condition is, in turn, posed as a minimization problem where the competing factors are the energy consumption required to suspend and transport the solids and their gravitational potential energy. However, the lack of scale-separation leads to many uncertainties in quantifying mesoscale structures. The authors have incorporated this model into computational fluid dynamics (CFD) simulations which have shown improvements over traditional drag models. Fully resolved simulations, such as those mentioned in this chapter and the subject of a later chapter on Immersed Boundary Methods, can be used to obtain additional information about these mesoscale structures. This can be used to formulate better constitutive equations for continuum models.


2018 ◽  
Vol 4 (12) ◽  
pp. 2146-2159 ◽  
Author(s):  
Ivona Capjak ◽  
Maja Zebić Avdičević ◽  
Maja Dutour Sikirić ◽  
Darija Domazet Jurašin ◽  
Amela Hozić ◽  
...  

pH, electrolytes and surfactants affected the stability of AgNPs in artificial test water system.


1993 ◽  
Vol 76 (3) ◽  
pp. 637-643 ◽  
Author(s):  
Joe W Dorner ◽  
Paul D Blankenship ◽  
Richard J Cole

Abstract A study was conducted to measure the precision of 2 rapid aflatoxin assay systems in use at 37 peanut buying points during the 1991 harvest season. Aflatoxin laboratories were established at the 37 buying points to analyze peanut samples from all incoming farmers’ stock loads as part of a joint project sponsored by various segments of the U.S. peanut industry and the U.S. Department of Agriculture. Eighteen laboratories were equipped with Neogen’s veratox FSP rapid assay system, whereas 19 laboratories used Vicam’s Aflatest rapid assay system. To monitor the performance of the field laboratories during the project, 3 portions of each of six 27 kg samples of ground peanuts were sent to each laboratory for analysis over a period of 6 weeks. Aflatoxin concentrations ranged from 0 to 300 ng/g when eight 200 g subsamples of each sample were analyzed by liquid chromatography (LC). For the 5 samples contaminated with aflatoxin, relative standard deviations for repeatability (RSDr) for laboratories using veratox FSP ranged from 18.66 to 53.29%, and the relative standard deviations for reproducibility (RSDR) ranged from 22.79 to 59.29%. For laboratories using the Aflatest system, RSDr values ranged from 18.70 to 41.48%, and RSDR values ranged from 23.84 to 47.56%. Horwitz ratios &lt; 2.0 were found for 4 of the 5 contaminated samples for both methods, indicating that the overall precision of the 2 methods used in the project was good. Mean aflatoxin concentrations, as determined with the rapid assay systems, were generally lower than those determined by LC, particularly for more highly contaminated samples. This could not be attributed to instability of aflatoxin in peanut paste, because additional information gathered in the study indicated that the stability of aflatoxin in peanut paste stored for 58 days was good.


Author(s):  
Cory M. Simon ◽  
Carlo Carraro

In the two-balloon experiment, two rubber balloons are connected and allowed to exchange gas. Owing to the non-monotonic relationship between the radius of the balloon and the pressure of gas inside it, the two-balloon system presents multi- and in-stabilities. Herein, we consider a two-adsorbent system, where two different adsorbents are allowed to exchange gas. We show that, for rigid adsorbents, the thermodynamic equilibrium state is unique. Then, we consider an adsorbent–balloon system, where an adsorbent exchanges gas with a rubber balloon. This system can exhibit multiple states at thermodynamic equilibrium– two (meta)stable and one unstable. The size of the balloon, pressure of gas in the balloon, and partitioning of gas between the adsorbent and the balloon differ among the equilibrium states. Temperature changes and the addition/removal of gas into/from the adsorbent–balloon system can induce catastrophe bifurcations and show hysteresis. Furthermore, the adsorbent–balloon system exhibits a critical temperature where, when approached from below, the discrepancy of balloon size between the two (meta)stable states decreases and, beyond, bistability is impossible. Practically, our findings preclude multiple partitions of adsorbed gas in rigid, mixed-linker or stratified metal-organic frameworks and may inspire new soft actuator and sensor designs.


Soil Research ◽  
1963 ◽  
Vol 1 (2) ◽  
pp. 129 ◽  
Author(s):  
WW Emerson

Orientated flakes of dry Na-montmorillonite were brought into equilibrium successively with relative vapour pressures of 0.92 and 0.985 and the moisture contents, (001) spacings, and swelling measured, the latter with a travelling microscope. Over saturated water vapour the clay continued to swell with time, in contrast to Ca-montmorillonite. Hysteresis in swelling was only observed at values of p/po > 0.985. The further expansion of flakes when immersed in solutions, N in Na+, of sodium chloride with dilute buffer added (from pH 4.4 to 10) or sodium hydroxide or chloride plus neutral sodium pyrophosphate was determined. The Na+ concentration was then reduced and the corresponding swelling measured, until the flake dispersed. Similar experiments were made on orientated flakes prepared from Na-montmorillonite to which 1.5% cetyltrimethylarnmonium bromide (CTAB) had been added, as well as from Na-montmorillonite which had been washed with lithium chloride and heated before reconversion to the Na form. The expansion of Li-vermiculite crystals in lithium chloride solutions was also determined. In solutions N in Na+ the swelling of Na-montmorillonite flakes was independent of pH, but for Na+ < N/2 the swelling increased sharply above pH 8.0. The swelling of Na-clay + CTAB was much less than untreated clay and was independent of pH. Na-montmorillonite which had been lithium-treated at 95�C gave a swelling pattern at pH 4.4 similar to that of Na-clay + CTAB, whereas in sodium hydroxide the pattern was similar to that of untreated clay. The specific effect of the pyrophosphate anion on the swelling of the CTAB-treated clay was slight. There was marked hysteresis in the swelling of Na-montmorillonite with respect to salt concentration, whereas the swelling of Li-vermiculite was almost reversible. Adding CTAB inhibited the intercrystalline swelling of Na-montmorillonite, the CTA+ ions forming Stern layers on the external surfaces of the crystals. A similar effect was apparently produced in the acetate buffer by aluminium ions released during the lithium treatment. The increase in the swelling of the untreated clay with pH is consistent with the removal of aluminium ions from the external surfaces of the crystals. There must be residual attractive forces between the crystal at high pH to account for the stability of the clay in dilute salt solutions. The edge to face forces linking the silicate sheets together appear to be constant above pH 4.0. Neutral sodium pyrophosphate disperses the clay at Na+ concentrations of < N Na+ by removing aluminium ions and neutralizing positive edge charges. The montmorillonite crystals are considered to be linked mainly edge to edge in a tactoid. The bands observed in thin sections of expanded gels, using polarized light, may be due to a periodicity in the stacking of the silicate sheets forming the crystals.


2019 ◽  
Vol 18 (3) ◽  
pp. 477-494 ◽  
Author(s):  
Pekka Ruponen ◽  
Petri Pennanen ◽  
Teemu Manderbacka

Abstract A decision support system with damage stability analysis has been recognized as an important tool for passenger ships. Various software applications have been developed and taken into use over the years, without a direct link to any compelling requirement, set forth in the international regulatory framework. After the Costa Concordia accident, new regulations have been established, setting minimum requirements for a decision support system, as an extension to a loading computer. Yet, more advanced systems have been developed recently, aiming at providing valuable additional information on the predicted development of the stability of the damaged ship. This paper presents these alternative decision support systems with damage stability analysis methods for flooding emergencies on passenger ships. The technical background, usability, and usefulness of the various approaches are compared and discussed, taking into account the important statutory approval point of view. In addition, practical examples, including past accidents, are presented and discussed.


2019 ◽  
Vol 11 (13) ◽  
pp. 1531 ◽  
Author(s):  
Maxim Okhrimenko ◽  
Chris Hopkinson

Multi-spectral (ms) airborne light detection and ranging (lidar) data are increasingly used for mapping purposes. Geometric data are enriched by intensity digital numbers (DNs) and, by utilizing this additional information either directly, or in the form of active spectral vegetation indices (SVIs), enhancements in land cover classification and change monitoring are possible. In the case of SVIs, the indices should be calculated from reflectance values derived from intensity DNs after rigorous calibration. In practice, such calibration is often not possible, and SVIs calculated from intensity DNs are used. However, the consistency of such active ms lidar products is poorly understood. In this study, the authors reported on an ms lidar mission at three different altitudes above ground to investigate SVI consistency. The stability of two families of indices—spectral ratios and normalized differences—was compared. The need for atmospheric correction in case of considerable range difference was established. It was demonstrated that by selecting single returns (provided sufficient point density), it was possible to derive stable SVI products. Finally, a criterion was proposed for comparing different lidar acquisitions over vegetated areas.


RSC Advances ◽  
2015 ◽  
Vol 5 (125) ◽  
pp. 103451-103457 ◽  
Author(s):  
Zhen-Yu Xiao ◽  
Yong-Feng Li ◽  
Bin Yao ◽  
Zhan-Hui Ding ◽  
Rui Deng ◽  
...  

In this work, we report a systematic investigation on the stability of a metal/thiourea aqueous/ethanol-based precursor solution used for fabricating Cu2ZnSnS4 (CZTS) thin films.


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