Microcapsules were prepared using the complex coacervation method with nano anatase TiO2 as the core material, gelatin/Arabia gum as the wall material, while dispersing TiO2 into the reaction solution using the ultrasonic. The prepared microcapsules can be finished into textiles such as the polypropylene nonwovens, and the microcapsules in the textiles gradually fracture and the anatase TiO2 was released, which would facilitate photo-degradation of the polypropylene nonwovens when exposed in sunlight. The microcapsules size was used as the process optimization evaluation index, and the quadratic general revolving combination design was used to conduct the experiments for obtaining the optimum ultrasonic conditions, and the other progress parameters were the same that used in our early microcapsule preparation. The obtained optimal process for ultrasound is: ultrasonic time is 17min; ultrasonic power is 74W and ultrasound temperature 60 °C.