An experimental study of the volatilization and diffusion characteristics of benzene leakage in inland water transportation

Author(s):  
Shuifen Zhan ◽  
Wenxin Jiang ◽  
Xuemin Chen ◽  
Mingchao Wang
2010 ◽  
Vol 1263 ◽  
Author(s):  
Rebecca Ann Cantrell ◽  
Paulette Clancy

AbstractUsing atomic-scale Molecular Dynamics (MD) and energy minimization techniques in conjunction with semi-empirical MM3 potential energy functions, we consider the adsorption of a C60 molecule on a series of hypothetical pentacene structures that vary only in the tilt of the angle that the short axis of the pentacene molecules makes with the underlying surface (the long axis lying essentially flat, as on a metal substrate). Important relationships were discovered between the angle adopted by the short axis of pentacene on the surface, φ1, and the adsorption and diffusion characteristics of C60. Static energy calculations show that there is a transition of the deepest energy minima from between the pentacene rows at low values of φ1 to within the rows at high values of φ1, where φ1 is the angle the pentacene short axis makes with the surface. MD confirms this trend by the predominant residence locations at the extreme φ1 values. Furthermore, MD results suggest that the C60 traverses the pentacene surface in the east-west direction for lower φ1 values (φ1 ≤ 40°) and in the north-south direction for higher φ1 values (φ1 ≥ 70°). Taking both static and dynamic results together, the most favorable tilt angles for mono-directional nanowire growth should occur between 70° and 80° off-normal.


2016 ◽  
Vol 3 (5) ◽  
pp. 16-00269-16-00269 ◽  
Author(s):  
Qiusheng LIU ◽  
Hirohiko ENDO ◽  
Katsuya FUKUDA ◽  
Makoto SHIBAHARA ◽  
Peng ZHANG

2019 ◽  
Vol 48 (4) ◽  
pp. 404002
Author(s):  
王 平 Wang Ping ◽  
杜永成 Du Yongcheng ◽  
杨 立 Yang Li ◽  
金方圆 Jin Fangyuan

Energies ◽  
2019 ◽  
Vol 12 (18) ◽  
pp. 3445 ◽  
Author(s):  
Donghyeon Kim ◽  
Youngjin Seo ◽  
Juhyun Kim ◽  
Jeongmin Han ◽  
Youngsoo Lee

Coalbed methane (CBM) content is generally estimated using the isotherm theory between pressure and adsorbed amounts of methane. It usually determines the maximum content of adsorbed methane or storage capacity. However, CBM content obtained via laboratory experiment is not consistent with that in the in-situ state because samples are usually ground, which changes the specific surface area. In this study, the effect of the specific surface area relative to CBM content was investigated, and diffusion coefficients were estimated using equilibrium time analysis. The differences in adsorbed content with sample particle size allowed the determination of a specific surface area where gases can adsorb. Also, there was an equilibrium time difference between fine and lump coal, because more time is needed for the gas to diffuse through the coal matrix and adsorb onto the surface in lump coal. Based on this, we constructed a laboratory-scale simulation model, which matched with experimental results. Consequently, the diffusion coefficient, which is usually calculated through canister testing, can be easily obtained. These results stress that lump coal experiments and associated simulations are necessary for more reliable CBM production analysis.


RSC Advances ◽  
2019 ◽  
Vol 9 (56) ◽  
pp. 32873-32888 ◽  
Author(s):  
Xiao-fang Lv ◽  
Jiang-wei Zuo ◽  
Yang Liu ◽  
Shi-Dong Zhou ◽  
Da-yong Lu ◽  
...  

The formation and accumulation of hydrates in high pressure oil and gas pipelines bring great risks to field development and deep-water transportation.


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