Amorphous/crystalline silicon heterojunction solar cells via Remote plasma chemical vapor deposition: Influence of hydrogen dilution, RF power, and sample Z-height position

Author(s):  
E. U. Onyegam ◽  
W. James ◽  
R. Rao ◽  
L. Mathew ◽  
M. Hilali ◽  
...  
2001 ◽  
Vol 685 ◽  
Author(s):  
Byeong Y. Moon ◽  
Jae H. Youn ◽  
Sung H. Won ◽  
Jin Jang ◽  
Stanislaw M. Pietruszko

AbstractPolycrystalline silicon thin films have been deposited by an inductively coupled plasma chemical vapor deposition using SiH4/H2 mixtures. The quality of poly-Si can be improved by increasing RF power and hydrogen dilution ratio. The poly-Si deposited at a RF power of 1000 W with an addition of H2, showed a Raman polycrystalline volume fraction of 85.7 %, FWHM of 6.4 cm−1, deposition rate of 9.64 Å/s and SEM grain size of ∼3000 Å.


2007 ◽  
Vol 7 (11) ◽  
pp. 4169-4173 ◽  
Author(s):  
Chaehwan Jeong ◽  
Seongjae Boo ◽  
Minsung Jeon ◽  
Koichi Kamisako

The hydrogenated amorphous silicon (a-Si:H) films, which can be used as the passivation or absorption layer of solar cells, were prepared by inductively coupled plasma chemical vapor deposition (ICP-CVD) and their characteristics were studied. Deposition process of a-Si:H films was performed by varying the parameters, gas ratio (H2/SiH4), radio frequency (RF) power and substrate temperature, while a working pressure was fixed at 70 m Torr. Their characteristics were studied by measuring thickness, optical bandgap (eV), photosensitivity, bond structure and surface roughness. When the RF power and substrate temperature were 300 watt and 200 °C, respectively, optical bandgap and photosensitivity, similar to the intrinsic a-Si:H film, were obtained. The Si-H stretching mode at 2000 cm−1, which means a good quality of films, was found at all conditions. Although the RF power increased up to 400 watt, average of surface roughness got better, compared to a-Si:H films deposited by the conventional PECVD method. These results show the potential for developing the solar cells using ICP-CVD, which have the relatively less damage of plasma.


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