Iron-Rich Sintered Glass-Ceramics from Industrial Wastes

2004 ◽  
Vol 82 (11) ◽  
pp. 3012-3016 ◽  
Author(s):  
Alexander Karamanov ◽  
Giuliana Taglieri ◽  
Mario Pelino
2014 ◽  
Vol 92 ◽  
pp. 174-183 ◽  
Author(s):  
Alexander Karamanov

Results about the vitrification of several hazardous iron-rich industrial wastes (from productions of Zn and Cu metals, as well as EAFD and MSWA) and the usage of obtained glasses for synthesise of sintered glass-ceramics are summarises. It is shown that the appropriated method of sinter-crystallization mainly depends on the crystallization trend of used glasses. When the parent composition is characterised by formation of a moderate amount of crystal phase low temperature sintering with short crystallization step in the interval 800-900 °C can be used. In addition, attractive granite-like building glass-ceramic can be obtained by mixing fine and coarse glass frits and “free” sintering in refractory moulds at 1000-1050 °C. Contrary, when intensive phase formation carries out the crystallization inhibits the sintering resulting in specimens with scarce degree of densification. However, in some cases a secondary densification process occurs at temperatures near to the eutectic ones, leading to well sintered samples with higher crystallinity and improved mechanical properties. It is also highlighted that the preventing of Fe2+oxidation by using inert atmosphere during the heat-treatments leads to a decreasing of sintering temperature, finer crystalline structure and additional enhancement of the mechanical properties.


2009 ◽  
Vol 35 (7) ◽  
pp. 2609-2617 ◽  
Author(s):  
M. Erol ◽  
S. Küçükbayrak ◽  
A. Ersoy-Meriçboyu

2021 ◽  
Vol 372 ◽  
pp. 115769
Author(s):  
K. Waetzig ◽  
J. Schilm ◽  
C. Heubner ◽  
K. Nikolowski ◽  
M. Partsch

2019 ◽  
Vol 51 (3) ◽  
pp. 285-294
Author(s):  
Dang Wei ◽  
H.-Y. He

High strength lightweight glass-ceramics were fabricated with coal gangue and clay as main raw materials. The utilization ratio of coal gangue, the ratio of the coal gangue with clay, mineralization agents, forming process and sintering process on the properties of the fabricated glass-ceramics were optimized. The utilization ratio of coal gangue reached 75, and the ratio of coal gangue to clay was 3/1, as an optimal property was observed. The optimal sintering temperature was found to be 1370?C. At this optimal temperature, the sintered glass-ceramics showed the main phase of mullite and spindle and so showed high strength, low density, and low water absorbance. The appropriate amounts of codoping of the TiO2, ZnO, and MnO2/dolomite as mineralization agents obviously enhanced the properties of the glass-ceramics. Process optimizations further determined reasonable and optimal process parameters. The high strength lightweight glass-ceramics fabricated in this work may be very suitable for various applications including building materials, cooking ceramics, and proppant materials, et al.


2016 ◽  
Vol 7 (4) ◽  
pp. 885-898 ◽  
Author(s):  
Anna Kritikaki ◽  
Dimitra Zaharaki ◽  
Kostas Komnitsas

2015 ◽  
Vol 114 (sup1) ◽  
pp. S11-S16 ◽  
Author(s):  
R. K. Chinnam ◽  
E. Bernardo ◽  
J. Will ◽  
A. R. Boccaccini

2019 ◽  
Vol 56 (1) ◽  
pp. 11-20
Author(s):  
Marcin Kozłowski ◽  
Gamal Khater ◽  
Piotr Olesik ◽  
Mokhtar Mahmoud

Materials ◽  
2019 ◽  
Vol 12 (12) ◽  
pp. 2032 ◽  
Author(s):  
Diana M. Ayala Valderrama ◽  
Jairo A. Gómez Cuaspud ◽  
Judith A. Roether ◽  
Aldo R. Boccaccini

Developments in the field of materials science are contributing to providing solutions for the recycling of industrial residues to develop new materials. Such approaches generate new products and provide optimal alternatives to the final disposal of different types of industrial wastes. This research focused on identifying and characterizing slag, fly ash, and glass cullet from the Boyacá region in Colombia as raw materials for producing glass-ceramics, with the innovative aspect of the use of these three residues without the addition of nucleating agents to produce the glass-ceramics. To characterize the starting materials, X-ray diffraction (XRD), X-ray fluorescence (XRF), and Scanning Electron Microscopy (SEM) techniques were used. The results were used to evaluate the best conditions to produce mixtures of the three waste components and to determine the specific compositions of glass-ceramics to achieve products with attractive technical properties for potential industrial applications. The proposed mixtures were based on three compositions: Mixture 1, 2, and 3. The materials were obtained through thermal treatment at 1200 °C in a tubular furnace in accordance with the results of a comprehensive characterization using thermal analysis. The microstructure, thermal stability, and structural characteristics of the samples were examined through SEM, differential thermal analysis (DTA), and XRD analyses, which showed that the main crystalline phases were diopside and anorthite, with a small amount of enstatite and gehlenite. The obtained glass-ceramics showed properties of technical significance for structural applications.


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