Influence of Cr doping on the phase composition of Cr,Ca:YAG ceramics by solid state reaction sintering

2018 ◽  
Vol 102 (4) ◽  
pp. 2104-2115 ◽  
Author(s):  
Mykhailo Chaika ◽  
Wojciech Paszkowicz ◽  
Wiesław Strek ◽  
Dariusz Hreniak ◽  
Robert Tomala ◽  
...  
2016 ◽  
Vol 61 (2) ◽  
pp. 965-969 ◽  
Author(s):  
M. Mikuśkiewicz ◽  
M. Stopyra ◽  
G. Moskal

Abstract The paper presents results of investigation on synthesis and characterization of cerium-dysprosium oxide. The input powders - dysprosium oxide Dy2O3 and cerium oxide CeO2 - were mixed so as to obtain equimolar ratio of cations, milled in alcohol and synthesized via solid state reaction process at 1350°C under 15MPa in vacuum for 2h. The microstructure, phase composition and thermal properties were analyzed. The obtained material was multiphase. Non-stoichiometric compounds were identified. Thermal diffusivity of investigated material decreased in the temperature range of 25-1000°C from 0,71 to 0,45 mm2/s.


Using the concept of phonon-lattice interaction, an expression is derived for the minimum temperature, T R , of a solid at which it may enter into solid-state reaction. This expression leads to a more precise idea of single-component reaction (sintering) temperatures than those given by Hüttig. Reaction between two different solids has been re-examined in the light of their physical and crystallographic properties. The rate law for such an additive reaction has been deduced from the quantum rate theory. It is concluded that crystallographic phase transformations and the formation of transitional superstructures constitute the phase-boundary processes and that the kinetics are governed by the dynamics of the diffusion process.


2006 ◽  
Vol 45 ◽  
pp. 276-280 ◽  
Author(s):  
Ewa Stobierska ◽  
Jerzy Lis ◽  
Mirosław M. Bućko ◽  
Agnieszka Gubernat

The results of preliminary investigation on preparation of perovskite pigments by solid state reaction are presented. The effects of different raw materials used as component carriers on formation of colored pigments were examined. Pigment composition, optimum chromophore addition, type of mineralizer and the conditions of synthesis were determined experimentally as well as the resulting color, phase composition and morphology of powders. The wet method of preparation of starting mixtures was also analyzed.


RSC Advances ◽  
2017 ◽  
Vol 7 (54) ◽  
pp. 33745-33750 ◽  
Author(s):  
X. X. Dong ◽  
C. Y. Huang ◽  
Q. Jin ◽  
J. Zhou ◽  
P. Feng ◽  
...  

Spherical LiFe1−xCrxBO3/C (x = 0, 0.005, 0.008) has been successfully synthesized by ball-milling and spray-drying assisted high-temperature solid-state reaction.


RSC Advances ◽  
2016 ◽  
Vol 6 (98) ◽  
pp. 96229-96236 ◽  
Author(s):  
Zhi Qi Yuan ◽  
Bing Liu ◽  
Xiao Qiang Liu ◽  
Xiang Ming Chen

Sr(La1−xSmx)2Al2O7 (0 ≤ x ≤ 1) ceramics were synthesized by a standard solid-state reaction method, and the microwave dielectric characteristics were investigated together with the densification behavior, microstructure and phase composition.


2012 ◽  
Vol 535-537 ◽  
pp. 797-800
Author(s):  
Liang Luo ◽  
Yan Jun Zhu ◽  
Ling Ling Song ◽  
Xiao Bo Zhang

A facile one-pot hydrothermal method has been developed for synthesis of porous and non-porous BaTiO3 ceramics using Ba(OH)2.8H2O, BaCO3 as barium source. In this paper, we research the effect of different barium source on the nanostructure of BaTiO3 ceramics in a solid state reaction, and the results indicated that the two different morphologies of BaTiO3 ceramics can be easily prepared by using these two different barium source. The phase composition and morphology of the as-obtained products were investigated by X-ray diffraction and field emission scanning electron microscopy (SEM).


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