Natural Gas Decarbonization to Reduce CO2 Emission From Combined Cycles—Part II: Steam-Methane Reforming

2000 ◽  
Vol 124 (1) ◽  
pp. 89-95 ◽  
Author(s):  
G. Lozza ◽  
P. Chiesa
Keyword(s):  
Natural Gas ◽  
Gas Turbine ◽  
Partial Oxidation ◽  
Power Plants ◽  
Combined Cycle ◽  
Performance Estimation ◽  
Thermodynamic Efficiency ◽  
Methane Reforming ◽  
Operating Pressure ◽  
Carbon Conversion

This paper discusses novel schemes of combined cycle, where natural gas is chemically treated to remove carbon, rather than being directly used as fuel. Carbon conversion to CO2 is achieved before gas turbine combustion. The first part of the paper discussed plant configurations based on natural gas partial oxidation to produce carbon monoxide, converted to carbon dioxide by shift reaction and therefore separated from the fuel gas. The second part will address methane reforming as a starting reaction to achieve the same goal. Plant configuration and performance differs from the previous case because reforming is endothermic and requires high temperature heat and low operating pressure to obtain an elevated carbon conversion. The performance estimation shows that the reformer configuration has a lower efficiency and power output than the systems addressed in Part I. To improve the results, a reheat gas turbine can be used, with different characteristics from commercial machines. The thermodynamic efficiency of the systems of the two papers is compared by an exergetic analysis. The economic performance of natural gas fired power plants including CO2 sequestration is therefore addressed, finding a superiority of the partial oxidation system with chemical absorption. The additional cost of the kWh, due to the ability of CO2 capturing, can be estimated at about 13–14 mill$/kWh.

Natural Gas Decarbonization to Reduce CO2 Emission From Combined Cycles: Part B — Steam-Methane Reforming

2000 ◽  
Author(s):  
Giovanni Lozza ◽  
Paolo Chiesa
Keyword(s):  
Natural Gas ◽  
Gas Turbine ◽  
Partial Oxidation ◽  
Power Plants ◽  
Combined Cycle ◽  
Performance Estimation ◽  
Thermodynamic Efficiency ◽  
Methane Reforming ◽  
Operating Pressure ◽  
Carbon Conversion

This paper discusses novel schemes of combined cycle, where natural gas is chemically treated to remove carbon, rather than being directly used as fuel. Carbon conversion to CO2 is achieved before gas turbine combustion. The first part of the paper discussed plant configurations based on natural gas partial oxidation to produce carbon monoxide, converted to carbon dioxide by shift reaction and therefore separated from the fuel gas. The second part will address methane reforming as a starting reaction to achieve the same goal. Plant configuration and performance differs from previous case because reforming is endothermic and requires high temperature heat and low operating pressure to obtain an elevated carbon conversion. The performance estimation shows that the reformer configuration has a lower efficiency and power output than the systems addressed in Part A. To improve the results, a reheat gas turbine can be used, with different characteristics from commercial machines. The thermodynamic efficiency of the systems of the two papers is compared by an exergetic analysis. The economic performance of natural gas fired power plants including CO2 sequestration are therefore addressed, finding a superiority of the partial oxidation system with chemical absorption. The additional cost of the kWh, due to the ability of CO2 capturing, can be estimated at about 13–14 mill$/kWh.

Natural Gas Decarbonisation Technologies for Advanced Power Plants

2006 ◽  
Author(s):  
Marco Gambini ◽  
Michela Vellini
Keyword(s):  
Power Plant ◽  
Natural Gas ◽  
Partial Oxidation ◽  
Power Plants ◽  
H2 Production ◽  
Combined Cycle ◽  
Methane Reforming ◽  
Steam Methane Reforming ◽  
Steam Methane ◽  
Percentage Points

In this paper two options for H2 production, by means of natural gas, are presented and their performances are evaluated when they are integrated with advanced H2/air cycles. In this investigation two different schemes have been analysed: an advanced combined cycle power plant (CC) and a new advanced mixed cycle power plant (AMC). The two methods for producing H2 are as follows: • steam methane reforming: it is the simplest and potentially the most economic method for producing hydrogen in the foreseeable future; • partial oxidation of methane: it could offer an energy advantage because this method reduces energy requirement of the reforming process. These hydrogen production plants require material and energetic integrations with power section and the best interconnections must be investigated in order to obtain good overall performance. With reference to thermodynamic and economic performance, significant comparisons have been made between the above introduced reference plants. An efficiency decrease and an increase in the cost of electricity has been obtained when power plants are equipped with a natural gas decarbonisation section. The main results of the performed investigation are quite variable among the different H2 production technologies here considered: the efficiency decreases in a range of 5.5 percentage points to nearly 10 for the partial oxidation of the natural gas and in a range of 8.8 percentage points to over 12 for the steam methane reforming. The electricity production cost increases in a range of about 41–42% for the first option and in a range of about 34–38% for the second one. The AMC, coupled with partial oxidation, stands out among the other power plant solutions here analysed because it exhibits the highest net efficiency and the lowest final specific CO2 emission. In addition to this, economic impact is favourable when AMC is equipped with systems for H2 production based on partial oxidation of natural gas.

Natural Gas Decarbonization to Reduce CO2 Emission From Combined Cycles—Part I: Partial Oxidation

2000 ◽  
Vol 124 (1) ◽  
pp. 82-88 ◽  
Author(s):  
G. Lozza ◽  
P. Chiesa
Keyword(s):  
Natural Gas ◽  
Gas Turbine ◽  
Partial Oxidation ◽  
Removal Rate ◽  
H2 Production ◽  
Combined Cycle ◽  
Thermodynamic Efficiency ◽  
Co2 Removal ◽  
Reaction Products ◽  
Combined Cycles

This paper discusses novel schemes of combined cycle, where natural gas is chemically treated to remove carbon, rather than being directly used as fuel. Carbon conversion to CO2 is achieved before gas turbine combustion. Therefore CO2 can be removed from fuel (rather than from exhausts, thus utilizing less demanding equipment) and made available for long-term storage, to avoid dispersion toward the atmosphere and the consequent contribution to the greenhouse effect. The strategy here proposed to achieve this goal is natural gas partial oxidation. The second part of the paper will address steam/methane reforming. Partial oxidation is an exothermic oxygen-poor combustion devoted to CO and H2 production. The reaction products are introduced in a multiple stage shift reactor converting CO to CO2. Carbon dioxide is removed by means of physical or chemical absorption processes and made available for storage, after compression and liquefaction. The resulting fuel mainly consists of hydrogen and nitrogen, thus gas turbine exhausts are virtually devoid of CO2. The paper discusses the selection of some important parameters necessary to obtain a sufficient level of conversion in the various reactors (temperature and pressure levels, methane-to-air or methane-to-steam ratios) and their impact on the plant integration and on the thermodynamic efficiency. Overall performance (efficiency, power output, and carbon removal rate) is predicted by means of a computational tool developed by the authors. The results show that a net efficiency of 48.5 percent, with a 90 percent CO2 removal, can be obtained by combined cycles based on large heavy duty machines of the present technological status, either by using chemical or physical absorption.

Natural Gas Decarbonization to Reduce CO2 Emission From Combined Cycles: Part A — Partial Oxidation

2000 ◽  
Author(s):  
Giovanni Lozza ◽  
Paolo Chiesa
Keyword(s):  
Natural Gas ◽  
Gas Turbine ◽  
Partial Oxidation ◽  
Removal Rate ◽  
H2 Production ◽  
Combined Cycle ◽  
Thermodynamic Efficiency ◽  
Co2 Removal ◽  
Reaction Products ◽  
Combined Cycles

This paper discusses novel schemes of combined cycle, where natural gas is chemically treated to remove carbon, rather than being directly used as fuel. Carbon conversion to CO2 is achieved before gas turbine combustion. Therefore CO2 can be removed from fuel (rather than from exhausts, thus utilizing less demanding equipment) and made available for long-term storage, to avoid dispersion toward the atmosphere and the consequent contribution to the greenhouse effect. The strategy here proposed to achieve this goal is natural gas partial oxidation. The second part of the paper will address steam / methane reforming. Partial oxidation is an exothermic oxygen-poor combustion devoted to CO and H2 production. The reaction products are introduced in a multiple stage shift reactor converting CO to CO2. Carbon dioxide is removed by means of physical or chemical absorption processes and made available for storage, after compression and liquefaction. The resulting fuel mainly consists of hydrogen and nitrogen, thus gas turbine exhausts are virtually devoid of CO2. The paper discusses the selection of some important parameters necessary to obtain a sufficient level of conversion in the various reactors (temperature and pressure levels, methane-to-air or methane-to-steam ratios) and their impact on the plant integration and on the thermodynamic efficiency. Overall performance (efficiency, power output and carbon removal rate) is predicted by means of a computational tool developed by the authors. The results show that a net efficiency of 48.5%, with a 90% CO2 removal, can be obtained by combined cycles based on large heavy duty machines of the present technological status, either by using chemical or physical absorption.

Natural Gas Decarbonization Technologies for Advanced Power Plants

2007 ◽  
Vol 129 (4) ◽  
pp. 1114-1124 ◽  
Author(s):  
Marco Gambini ◽  
Michela Vellini
Keyword(s):  
Power Plant ◽  
Natural Gas ◽  
Partial Oxidation ◽  
Power Plants ◽  
H2 Production ◽  
Combined Cycle ◽  
Methane Reforming ◽  
Steam Methane Reforming ◽  
Steam Methane ◽  
Percentage Points

In this paper two options for H2 production, by means of natural gas, are presented and their performances are evaluated when they are integrated with advanced H2/air cycles. In this investigation two different schemes have been analyzed: an advanced combined cycle power plant (CC) and a new advanced mixed cycle power plant (AMC). The two methods for producing H2 are as follows: (1) steam methane reforming: it is the simplest and potentially the most economic method for producing hydrogen in the foreseeable future; and (2) partial oxidation of methane: it could offer an energy advantage because this method reduces the energy requirement of the reforming process. These hydrogen production plants require material and energetic integrations with power section and the best interconnections must be investigated in order to obtain good overall performance. With reference to thermodynamic and economic performance, significant comparisons have been made between the above introduced reference plants. An efficiency decrease and an increase in the cost of electricity has been obtained when power plants are equipped with a natural gas decarbonization section. The main results of the performed investigation are quite variable among the different H2 production technologies here considered: the efficiency decreases in a range of 5.5 percentage points to nearly 10 for the partial oxidation of the natural gas and in a range of about 9 percentage points to over 12 for the steam methane reforming. The electricity production cost increases in a range of about 41–42% for the first option and in a range of about 34–38% for the second one. The AMC, coupled with partial oxidation, stands out among the other power plant solutions here analyzed because it exhibits the highest net efficiency and the lowest final specific CO2 emission. In addition to this, economic impact is favorable when AMC is equipped with systems for H2 production based on partial oxidation of natural gas.

Enhancing Gas Turbine Operation With Heavy Fuel Oil

2013 ◽  
Author(s):  
Vikram Muralidharan ◽  
Matthieu Vierling
Keyword(s):  
Power Generation ◽  
Natural Gas ◽  
Gas Turbine ◽  
Power Plants ◽  
High Efficiency ◽  
Combined Cycle ◽  
Fuel Oil ◽  
Residual Oil ◽  
Heavy Fuel Oil ◽  
Hydro Power

Power generation in south Asia has witnessed a steep fall due to the shortage of natural gas supplies for power plants and poor water storage in reservoirs for low hydro power generation. Due to the current economic scenario, there is worldwide pressure to secure and make more gas and oil available to support global power needs. With constrained fuel sources and increasing environmental focus, the quest for higher efficiency would be imminent. Natural gas combined cycle plants operate at a very high efficiency, increasing the demand for gas. At the same time, countries may continue to look for alternate fuels such as coal and liquid fuels, including crude and residual oil, to increase energy stability and security. In over the past few decades, the technology for refining crude oil has gone through a significant transformation. With the advanced refining process, there are additional lighter distillates produced from crude that could significantly change the quality of residual oil used for producing heavy fuel. Using poor quality residual fuel in a gas turbine to generate power could have many challenges with regards to availability and efficiency of a gas turbine. The fuel needs to be treated prior to combustion and needs a frequent turbine cleaning to recover the lost performance due to fouling. This paper will discuss GE’s recently developed gas turbine features, including automatic water wash, smart cooldown and model based control (MBC) firing temperature control. These features could significantly increase availability and improve the average performance of heavy fuel oil (HFO). The duration of the gas turbine offline water wash sequence and the rate of output degradation due to fouling can be considerably reduced.

Effect of Deaerator Parameters on Simple and Reheat Gas/Steam Combined Cycle With Different Cooling Medium

2019 ◽  
Author(s):  
Mayank Maheshwari ◽  
Onkar Singh
Keyword(s):  
Gas Turbine ◽  
Mass Fraction ◽  
Power Plants ◽  
Performance Enhancement ◽  
Pressure Ratio ◽  
Combined Cycle ◽  
Cycle Performance ◽  
Inlet Temperature ◽  
Operating Pressure ◽  
Cooling Medium

Abstract Performance of gas/steam combined cycle power plants relies upon the performance exhibited by both gas based topping cycle and steam based bottoming cycle. Therefore, the measures for improving the performance of the gas turbine cycle and steam bottoming cycle eventually result in overall combined cycle performance enhancement. Gas turbine cooling medium affects the cooling efficacy. Amongst different parameters in the steam bottoming cycle, the deaerator parameter also plays its role in cycle performance. The present study analyzes the effect of deaerator’s operating pressure being varied from 1.6 bar to 2.2 bar in different configurations of simple and reheat gas/steam combined cycle with different cooling medium for fixed cycle pressure ratio of 40, turbine inlet temperature of 2000 K and ambient temperature of 303 K with varying ammonia mass fraction from 0.6 to 0.9. Analysis of the results obtained for different combined cycle configuration shows that for the simple gas turbine and reheat gas turbine-based configurations, the maximum work output of 643.78 kJ/kg of air and 730.87 kJ/kg of air respectively for ammonia mass fraction of 0.6, cycle efficiency of 54.55% and 53.14% respectively at ammonia mass fraction of 0.7 and second law efficiency of 59.71% and 57.95% respectively at ammonia mass fraction of 0.7 is obtained for the configuration having triple pressure HRVG with ammonia-water turbine at high pressure and intermediate pressure and steam turbine operating at deaerator pressure of 1.6 bar.

scholarly journals Simulation of Producer Gas Fired Power Plants with Inlet Fog Cooling and Steam Injection

2006 ◽  
Vol 129 (3) ◽  
pp. 637-647 ◽  
Author(s):  
Mun Roy Yap ◽  
Ting Wang
Keyword(s):  
Natural Gas ◽  
Steam Turbine ◽  
Gas Turbine ◽  
Power Output ◽  
Power Plants ◽  
Steam Injection ◽  
Combined Cycle ◽  
Producer Gas ◽  
Turbine Inlet ◽  
Cycle Systems

Biomass can be converted to energy via direct combustion or thermochemical conversion to liquid or gas fuels. This study focuses on burning producer gases derived from gasifying biomass wastes to produce power. Since the producer gases are usually of low calorific values (LCV), power plant performance under various operating conditions has not yet been proven. In this study, system performance calculations are conducted for 5MWe power plants. The power plants considered include simple gas turbine systems, steam turbine systems, combined cycle systems, and steam injection gas turbine systems using the producer gas with low calorific values at approximately 30% and 15% of the natural gas heating value (on a mass basis). The LCV fuels are shown to impose high compressor back pressure and produce increased power output due to increased fuel flow. Turbine nozzle throat area is adjusted to accommodate additional fuel flows to allow the compressor to operate within safety margin. The best performance occurs when the designed pressure ratio is maintained by widening nozzle openings, even though the turbine inlet pressure is reduced under this adjustment. Power augmentations under four different ambient conditions are calculated by employing gas turbine inlet fog cooling. Comparison between inlet fog cooling and steam injection using the same amount of water mass flow indicates that steam injection is less effective than inlet fog cooling in augmenting power output. Maximizing steam injection, at the expense of supplying the steam to the steam turbine, significantly reduces both the efficiency and the output power of the combined cycle. This study indicates that the performance of gas turbine and combined cycle systems fueled by the LCV fuels could be very different from the familiar behavior of natural gas fired systems. Care must be taken if on-shelf gas turbines are modified to burn LCV fuels.

scholarly journals Development of Multimode Gas Fired Combined Cycle Chemical-Looping Combustion Based Power Plant Lay-Outs

2021 ◽  
Author(s):  
Basavaraja Revappa Jayadevappa
Keyword(s):  
Carbon Dioxide ◽  
Power Plant ◽  
Natural Gas ◽  
Flue Gas ◽  
Power Plants ◽  
Carbon Dioxide Capture ◽  
Combined Cycle ◽  
Chemical Looping Combustion ◽  
Chemical Looping ◽  
Operating Pressure

Abstract Operation of power plants in carbon dioxide capture and non-capture modes and energy penalty or energy utilization in such operations are of great significance. This work reports on two gas fired pressurized chemical-looping combustion power plant lay-outs with two inbuilt modes of flue gas exit namely, with carbon dioxide capture mode and second mode is letting flue gas (consists carbon dioxide and water) without capturing carbon dioxide. In the non-CCS mode, higher thermal efficiencies of 54.06% and 52.63% efficiencies are obtained with natural gas and syngas. In carbon capture mode, a net thermal efficiency of 52.13% is obtained with natural gas and 48.78% with syngas. The operating pressure of air reactor is taken to be 13 bar for realistic operational considerations and that of fuel reactor is 11.5 bar. Two power plant lay-outs developed based combined cycle CLC mode for natural gas and syngas fuels. A single lay-out is developed for two fuels with possible retrofit for dual fuel operation. The CLC Power plants can be operated with two modes of flue gas exit options and these operational options makes them higher thermal efficient power plants.

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