A Method for Improving the Quality of Bituminous Froth From Water Extraction of Oil Sands

1992 ◽  
Vol 114 (4) ◽  
pp. 261-266
Author(s):  
V. S. V. Rajan ◽  
R. Tipman

Bituminous froths produced from the water extraction of oil sands contain significant quantities of sand and water which must be removed prior to upgrading the bitumen to synthetic crude oil. This paper presents a summary of the study of a simple twostep process for removing most of the solid and water contaminants from the bituminous froth. Low-quality froths containing 10–30 percent bitumen at temperatures of 40–70°C were improved in quality to 50–60 percent bitumen by heating the raw froth to ~ 90°C and settling the product in a gravity settler. The gravity settling vessel incorporated unique features for the introduction of the hot froth into the vessel. Two types of froth heaters were tested: a column heater containing a structured grid packing which used live steam injection, and a shell and tube heat exchanger. Heat transfer data were obtained for both types of heaters in the range of froth flow conditions available in the pilot plant. There was no apparent difference between the two heating modes in terms of the froth quality improvement, but the direct contact heater had the benefit of deaerating the froth. Evaluation of the separation efficiency showed that the gravity separation vessel design performed very well, and hence was incorporated into a commercial froth cleaning plant design. The bitumen separation efficiency was the best for froths containing about 20 percent bitumen. There was no apparent improvement in the froth quality for froths containing over 65 percent bitumen.

Nanophotonics ◽  
2020 ◽  
Vol 9 (7) ◽  
pp. 2077-2088 ◽  
Author(s):  
Daixun Jiang ◽  
Xun Sun ◽  
Xilu Wu ◽  
Shuai Zhang ◽  
Xiaofei Qu ◽  
...  

AbstractThe strategy to improve the photocatalytic removal efficiencies towards organic pollutants is still a challenge for the novel Sillen–Aurivillius perovskite type Bi4NbO8Cl. Herein, we report carbon-supported TiO2/Bi4NbO8Cl (C-TiO2/Bi4NbO8Cl) heterostructures with enhanced charge separation efficiency, which were fabricated via molten-salt flux process. The carbon-supported TiO2 particles were derived from MXene Ti3C2 precursors, and attached on plate-like Bi4NbO8Cl, acting as electron-traps to achieve supressed recombination of photo-induced charges. The improved charge separation confers C-TiO2/Bi4NbO8Cl heterostructures superior photocatalytic performance with 53% higher than pristine Bi4NbO8Cl, towards rhodamine B removal with the help of photo-induced holes. Moreover, the C-TiO2/Bi4NbO8Cl heterostructures can be expanded to deal with other water contaminants, such as methyl orange, ciprofloxacin and 2,4-dichlorophenol with 44, 25 and 13% promotion, respectively, and thus the study offers a series of efficient photocatalysts for water purification.


SPE Journal ◽  
2012 ◽  
Vol 17 (03) ◽  
pp. 680-686 ◽  
Author(s):  
Dharmeshkumar R. Gotawala ◽  
Ian D. Gates

Summary Full steam conformance along the well pair of the steam-assisted gravity-drainage (SAGD) oil-sands-recovery process is essential for high thermal efficiency. Conformance can be improved by controlling injection and production strategies to ensure that steam is delivered to target regions in the reservoir. Smart wells use interval-control valves (ICVs) that, conceptually, can be dynamically controlled to yield uniform steam injectivity along the well pair. Dynamic control algorithms, such as proportional-integral-derivative (PID) control and their associated controller parameters, have not yet been developed for the SAGD processes that use ICVs. One control strategy would be to control the interwell subcool temperature difference—that is, the difference between the steam-injection temperature and the produced-fluids temperature. If this temperature difference is small, then the liquid pool above the production well is small and there is a likelihood of live steam production from the chamber. On the other hand, if the difference is large, the pool may rise above the injection well and gravity drainage is hindered because the chamber is largely filled with liquid. Here, the focus is on developing a simple, approximate theory for the behavior of the liquid pool at the base of the steam chamber to determine the ranges of values of control parameters to achieve a targeted interwell subcool temperature difference.


2010 ◽  
Author(s):  
Weiqiang Li ◽  
Daulat D. Mamora

Abstract Steam Assisted Gravity Drainage (SAGD) is one successful thermal recovery technique applied in the Athabasca oil sands in Canada to produce the very viscous bitumen. Water for SAGD is limited in supply and expensive to treat and to generate steam. Consequently, we conducted a study into injecting high-temperature solvent instead of steam to recover Athabasca oil. In this study, hexane (C6) coinjection at condensing condition is simulated using CMG STARS to analyze the drainage mechanism inside the vapor-solvent chamber. The production performance is compared with an equivalent steam injection case based on the same Athabasca reservoir condition. Simulation results show that C6 is vaporized and transported into the vapor-solvent chamber. At the condensing condition, high temperature C6 reduces the viscosity of the bitumen more efficiently than steam and can displace out all the original oil. The oil production rate with C6 injection is about 1.5 to 2 times that of steam injection with oil recovery factor of about 100% oil initially-in-place. Most of the injected C6 can be recycled from the reservoir and from the produced oil, thus significantly reduce the solvent cost. Results of our study indicate that high-temperature solvent injection appears feasible although further technical and economic evaluation of the process is required.


2021 ◽  
Author(s):  
Subha Ranjan Paul ◽  
Sumantra Bhattacharya

Abstract Separation efficiency of coal cleaning equipment is typically assessed by Probable Error in Separation (Ep) and Organic Efficiency (Eorg). The first one is determined on the basis of precise cut point density of separation and implies that for ideal separation the error is zero. The second one is calculated on the basis of yield of clean coal/ middling at the target ash and implies that for ideal separation the efficiency is 100%. Plant operators worldwide being accountable for the tonnage of the clean coal and middling produced regularly monitor Eorg with some application in plant design in India. Ep is universally used as an equipment selection criterion from among the vendors, in commercial contracts and sometimes for performance analysis of coal cleaning equipment carried out at the plants. Since both are performance measures there should possibly be a relationship between the two for specific cleaning equipment or for a particular type of density separators. Such relationships are however rarely observed. Moreover there are many instances where high to very high Eorg does not translate into low to very low Ep. Therefore, is there a dichotomy between the two performance measures?


2021 ◽  
Author(s):  
Jawaher Almorihil ◽  
Ahmed Alsmaeil ◽  
Ziyad Kaidar ◽  
Abdulkareem AlSofi

Abstract A second stage of gravity settling with the addition of demulsifiers or clarifiers is commonly used in processing plants to further treat the separated produced water. In previous work, we demonstrated gravity settling lower efficiency in removing oil carryover from produced water compared to other processing techniques. Both centrifugation and filtration were found to significantly improve the separated water quality. In this work, we focus on centrifugation and further evaluate its efficiency in improving the quality of separated water for both water and chemical floods, specifically surfactant/polymer (SP) flooding. Samples were firstly prepared to imitate the separation plant projected feed and operations. Synthetic representative brines were prepared and used with dead crude oil to prepare the oil/water emulsions. Emulsion separation was conducted at different temperatures, as well as different concentrations of SP, and the demulsifier. The kinetics and efficiency of separation were thoroughly studied over two stages of separation: primary gravity settling and secondary centrifugation. We performed gravitational separation using bottle tests in order to firstly obtain the separated produced water for use in secondary water treatment studies and to secondly further investigate gravity settling kinetics and efficiency. Water quality, in terms of oil content, was then assessed through solvent extraction and UV analyses. Samples of the produced water separated by the primary gravity settling were then exposed to secondary centrifugation. Centrifugation was performed at different rotational speeds using a dispersion analyzer. Light transmission evolution in space and time was used to study kinetics, efficiency and mechanisms of secondary centrifugation. The results reconfirmed that a single-stage gravity settling is not sufficient to reduce oil carryover to acceptable levels for disposal and re-injection into oilfields. Secondary centrifugation yielded clear and significant improvement in water quality even in the presence of EOR chemicals. With centrifugation, the separation efficiency was a function of the rotational speed. Higher rotational speeds resulted in higher creaming velocities and faster separation. In addition, creaming velocities indicated that higher temperatures yield favorable effects on oil droplets migration and separation rates. This is possibly due to the lower density and larger bouncy at higher temperatures. Based on these results, we conclude that secondary centrifugation is very efficient and effective in improving the quality of separated water. In terms of the effects of investigated EOR formulations, SP addition caused minor but manageable reduction in separated water quality at a level that would not harm conventional disposal practices.


1984 ◽  
Vol 24 (04) ◽  
pp. 417-430 ◽  
Author(s):  
Yoshiaki Ito

Ito, Yoshiaki, SPE, Gulf Canada Resources Inc. Abstract Historically, a vertical or horizontal fracture is believed to be a main recovery mechanism for a cyclic steam-injection process in unconsolidated oil sands. Most current computer process in unconsolidated oil sands. Most current computer models for the process are based on the fracture concept. With the postulated sand deformation concept, on the other hand, the injected fluid is able to penetrate the unconsolidated oil sand by creating micro channels. When the pore pressure is reduced during production, these secondary flow channels will collapse totally or partially. Condensed steam tends to sweep fluids where the bitumen had been heated and imparts mobility as a result of the injected hot fluid. Flow geometry of the new concept is described in this paper. The physical differences between the sand paper. The physical differences between the sand deformation zone and the no-deformation zone are also investigated. The three major differences between these two zones are porosity change, pressure level, and energy and flow characteristics resulting from the existence of micro channels. All these modifications were incorporated successfully into a conventional numerical thermal simulator. The new model provided an excellent match for all the field observations (steam-injection pressure, oil-and-water production rates, fluid production temperature, downhole production rates, fluid production temperature, downhole production pressure, and salinity changes) of a production pressure, and salinity changes) of a steam-stimulated well in an unconsolidated oil sand. The study indicates that the most important phenomenon for in-situ recovery of bitumen is the one-way-valve effect of the micro channels, which are opened during injection and closed during production. Introduction A physical interaction between the injected fluid and the reservoir formation is required to inject large volumes of steam into the oil sand formation. Until now, this physical interaction was believed to be a vertical or a physical interaction was believed to be a vertical or a horizontal fracture, depending on the strength of the directional stress. Many authors investigated and incorporated this concept into numerical thermal simulators and used it for history match and prediction studies. There are many difficulties in analyzing the actual performance of steam stimulated wells by means of the performance of steam stimulated wells by means of the fracture concept. Some of the evidence is extremely difficult or impossible to explain with the conventional fracture concept. A few of these problems are discussed later. I, therefore, have postulated a new flow geometry to achieve a realistic interpretation of well performances. The new flow geometry has been termed the "sand deformation concept." The well performance characteristics for the bitumen recovery process can be described more clearly with the new concept process can be described more clearly with the new concept than with the conventional fracture concept. Sand Deformation Concept Although unconsolidated oil sand might not behave like a consolidated rock under stress, fracturing is assumed to be an important mechanism in most mathematical models for in-situ recovery of bitumen by steam injection. Fig. 1 A shows this process when the horizontal fracture is assumed to be the main recovery mechanism. Injected steam and condensate are contained primarily in a thin fracture zone so the fluid accommodated in the fracture will leak off. The process is similar to a linear displacement of oil by hot fluid. With the sand deformation concept, on the other hand, the injected fluid is able to penetrate oil sand through the creation of micro channels. Fig. 1 B shows this process. Since the micro channeling is postulated in the new model, a significant amount of resident fluid, including oil and connate water, will remain around the well without contacting the injected fluid. The extra space required to create the channels may be obtained by overburden heaving. Therefore, overburden movement will control the directional orientation of the channel creation. The preferential directional orientation is likely to be created as a result of preferential overburden movement. preferential overburden movement. Fig. 2 shows the rough dimensions of the pressurized channeling envelope surrounding the well when approximately 10 000 m3 [353,147 cu ft] of cold water equivalent as steam was injected. The shape of the areal extension is determined from the strength of the overburden stresses. SPEJ p. 417


2012 ◽  
Vol 90 (10) ◽  
pp. 805-810 ◽  
Author(s):  
Amy Holland ◽  
Dominik Wechsler ◽  
Anjali Patel ◽  
Brian M. Molloy ◽  
Alaina R. Boyd ◽  
...  

Separation of bitumen from oil sands is far more efficient with an organic solvent than with the conventional hot water (Clark) process, but the removal of the organic solvent from the bitumen requires distillation. Distillation is problematic because of the energy cost and the need for a volatile solvent (which is therefore likely to be flammable and smog-forming). A switchable hydrophilicity solvent (SHS) is a solvent that is water-miscible in the presence of an atmosphere of CO2 but separates from water when CO2 is absent. Extraction of bitumen from low-grade high-fines oil sands using a SHS (CyNMe2) is efficient, removing 94%–97% of the bitumen. The resulting solids (sand and clay) are dry, free-flowing, and contaminated with only 0.4 wt % of bitumen and as little as 102 ppm of the solvent. No distillation step was required to recover the solvent from the bitumen. Instead, carbonated water extraction removed the solvent from the oil. Losses of the CyNMe2 solvent were, for the best method, 0.06 grams of solvent per gram of bitumen recovered. The method recovers more oil than the Clark process, produces cleaner solids, works with low-grade high-fines oil sands, and requires neither distillation nor a volatile solvent.


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