Thermal Radiation Properties of Acetylene

1985 ◽  
Vol 107 (4) ◽  
pp. 943-948 ◽  
Author(s):  
M. A. Brosmer ◽  
C. L. Tien

The spectral absorptivities of the ν3 and ν5 fundamental and the ν4 + ν5 combination bands of acetylene have been measured at low resolution for temperatures between 290 and 600 K. These measurements allow the determination of spectral-mean (narrow-band) parameters for the three bands based on the Elsasser and Goody models and the correlation of the band absorptance data using the Edwards exponential wide-band model. Charts for the total emissivity and Planck mean absorption coefficient have been developed for acetylene based on the wide-band parameters.

1971 ◽  
Vol 93 (2) ◽  
pp. 172-177 ◽  
Author(s):  
S. H. Chan ◽  
C. L. Tien

The low resolution measurements of infrared absorption are presented for ν1, ν3, 2ν1, and ν1 + ν3 bands of sulfur dioxide. These measurements were performed at room temperature and at the optical pathlengths such that the data cover the transition and strong absorption regions. The spectral data were correlated in terms of the line-strength and the line-shape parameters by use of the Elsasser model while the Edwards exponential wide-band model was employed to correlate the total band absorptance data. The total emissivity was then calculated from these total band absorptance correlations to compare with Hottel’s result. It is found that Hottel’s result is much higher than the present calculations. Possible causes for such a large discrepancy in Hottel’s result are discussed.


1991 ◽  
Vol 113 (4) ◽  
pp. 946-952 ◽  
Author(s):  
T. K. Kim ◽  
J. A. Menart ◽  
H. S. Lee

The S-N discrete ordinates method is applied to analyze radiative heat transfer in nongray gases. Spectral correlation between the terms in the equation of transfer is considered for black or nearly nonreflecting walls. Formulations to apply the S-N method using a narrow-band or the exponential wide-band model are presented. The net radiative wall heat fluxes and the radiative source distributions are obtained for uniform, parabolic, and boundary layer type temperature profiles, as well as for a parabolic concentration profile. The narrow- and wide-band nongray solutions are compared with gray-band approximations using the same band models. The computational speed of the gray-band approximation is obtained at the expense of accuracy in the internal fluxes and radiative source distributions. The wall radiative flux predictions by the gray-band approximation are satisfactory.


1982 ◽  
Vol 104 (4) ◽  
pp. 602-608 ◽  
Author(s):  
T. F. Smith ◽  
Z. F. Shen ◽  
J. N. Friedman

The weighted sum of gray gases model postulates that total emissivity and absorptivity may be represented by the sum of a gray gas emissivity weighted with a temperature dependent factor. The gray gas emissivity is expressed in terms of a temperature-independent absorption coefficient, absorbing gas partial pressure, and path length. The weighting factors are given by polynomials in gas temperature with associated polynomial coefficients. For absorptivity, a second polynomial for the irradiation temperature is introduced. A regression scheme is employed to fit the model to total emissivity and absorptivity values obtained from the exponential wide-band model. Absorption and polynomial coefficients are reported for carbon dioxide, water vapor, and mixtures of these gases. The model with these coefficients more accurately represents the total properties over a wider range of temperatures and partial pressure-path length products than previously available coefficients.


2001 ◽  
Vol 124 (1) ◽  
pp. 26-29 ◽  
Author(s):  
S. P. Fuss ◽  
A. Hamins

The Planck mean absorption coefficient, ap, has been calculated for HBr, HCl, and HF over a temperature range from 300 K–2300 K using data from the 1996 edition of the HITRAN molecular database. Plots of ap versus temperature showed monotonically decreasing behavior over this temperature range, with peak values at 300 K of 45.9 (atm-m)−1, 5.3 (atm-m)−1, and 1.95 (atm-m)−1 for HF, HCl, and HBr, respectively. The magnitude of these values suggests that HBr, HCl, and HF can significantly impact calculations of radiative transfer in flames containing these species. Two sets of additional calculations were performed for CO to validate the methodology used for calculation of ap for HBr, HF, and HCl. In the first approach, which employed the narrow band model RADCAL, the calculation procedure was similar to that of the present calculations. The second approach utilized tabulated values of the integrated intensity for each CO band and an average value of the Planck function within each band. Results from the three methods showed general agreement. Polynomial expressions are provided as fits to ap as a function of temperature for HBr, HCl, HF, and CO.


2020 ◽  
Vol 6 (6) ◽  
pp. 42-47
Author(s):  
A. Abdullin

The influence of the spectral model of radiation on heat fluxes and the temperature of combustion products in the radiant chambers of tube furnaces of the petrochemical industry is analyzed. A wide-band model and a Hottel gray model are considered. It is shown that the spectral model of the combustion medium radiation weakly affects the calculated characteristics of the total heat transfer.


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