Characteristic Time Model Correlation of NOx Emissions From Lean Premixed Combustors

Author(s):  
Donald M. Newburry ◽  
Arthur M. Mellor

The semi–empirical characteristic time model (CTM) has been used previously to correlate and predict emissions data from conventional diffusion flame, gas turbine combustors. The form of the model equation was derived for NOx emissions from laboratory flameholders and then extended to conventional gas turbine combustors. The model relates emissions to the characteristic times of distinct combustion subprocesses, with empirically determined model constants. In this paper, a new model is developed for lean premixed (LP) NOx emissions from a perforated plate flameholder combustor burning propane fuel. Several modifications to the diffusion flame CTM were required, including a new activation energy and a more complicated dependence on combustor pressure. Appropriate model constants were determined from the data, and the correlation results are reasonable. An attempt was made to validate the new model with LP NOx data for a different but geometrically similar flameholder operating at lower pressures. The predictions are good for the low equivalence ratio data. However, a systematic error in the reported equivalence ratios may be adversely affecting the predictions of the higher equivalence ratio data through the calculated adiabatic flame temperature.

Author(s):  
J. C. Barnes ◽  
A. M. Mellor

The characteristic time model (CTM) represents the dominant physical subprocesses related to combustor performance in terms of characteristic times. Properly formulated, these characteristic times account for variations in combustor geometry, fuel characteristics, and operating conditions. Here, a CTM for piloted–lean premixed combustor NOx emissions is used to investigate the sensitivity of NO formation in such combustors to fuel/air unmixedness and suggests an experimental method of evaluating premixed performance under fired conditions that is discussed in the companion paper.


Author(s):  
J. C. Barnes ◽  
A. M. Mellor

Lean premixed combustor manufacturers require premixer concepts that provide homogeneity (mixedness) of the fuel which burns in the main flame. Ideally premixer evaluation would be conducted under realistic combustor operating conditions. However, current techniques typically are limited to cold—flow, low pressure (<14 atm) conditions or comparison of measured NOx emissions with others obtained in premixed systems. Thus, a simple, consistent method for quantifying unmixedness in lean premixed combustors operating at high pressure, fired operating conditions is proposed here, using the characteristic time model developed in the companion paper.


Author(s):  
Ernst Schneider ◽  
Stephan Staudacher ◽  
Bruno Schuermans ◽  
Haiwen Ye

Strict environmental regulations demand gas turbine operation at very low equivalence ratios. Premixed gas turbine combustors, operated at very lean conditions, are prone to thermoacoustic instabilities. Thermoacoustic instabilities cause significant performance and reliability problems in gas turbine combustors, so their prevention is a general task. Splitting the fuel mass flow between different burner groups, i.e. using a burner group fuel staging technique, is a possibility to control the thermoacoustic instabilities. The resulting combustion perturbations have also effects on the gas turbine NOx emissions making it necessary to find an optimum balance between pulsations and emissions. This paper presents a model based active combustion control concept for the reduction of pulsations and emissions in lean premixed gas turbine combustors. The model is integrated in an observer structure derived from a Luenberger observer. The control logic is based on a PID algorithm allowing either the direct command of the pulsation level with a continuous monitoring and a potential limit setting of the NOx emission level or vice versa. The gas turbine pulsations and emissions are modelled using Gaussian Processes. - Gaussian Processes are stochastic processes related to Neural Networks that can approximate arbitrary functions. Based on measured gas turbine data they can be implemented in an easy and straightforward manner. The model provides the control system with real time data of the outputs resulting from settings of the staging ratio that is the actuating variable of the system. A model based control concept can significantly alleviate the effects of time delays in the system. The model based control concept allows for fast adaptation of the burner group staging ratio during static and transient operations to achieve an optimum of the pulsation and emission levels. During tests the model based control concept gave good results and proved to be robust even at high disturbance levels.


Author(s):  
Bhupendra Khandelwal ◽  
Yingchun Li ◽  
Priyadarshini Murthy ◽  
Vishal Sethi ◽  
Riti Singh

A design of a hydrogen fuelled micromix concept based combustor is proposed in this paper. The proposed micromix concept based combustor yields improved mixing, which leads to wider flammability range of the hydrogen-air flames compared to conventional kerosene and micromix concept based combustors. This improved mixing allows the combustion zone to operate at a much lower equivalence ratio than the conventional kerosene based and micromix concept based combustors considered in this study. Furthermore, when burning hydrogen the thermal energy radiated to the surroundings is lower (as the result of using lower equivalence ratio) than that of kerosene, consequently resulting in an increased liner life and lower cooling requirement. The aim of this paper is to highlight the impact of using hydrogen as a fuel in gas turbine combustors. It is perceived that this new micromix concept based combustor would also help in achieving low emissions and better performance. Possibilities for lowering NOx emissions when using hydrogen as a fuel in new designs of micromix combustor are also discussed.


Author(s):  
D. A. Sullivan ◽  
P. A. Mas

The effect of inlet temperature, pressure, air flowrate and fuel-to-air ratio on NOx emissions from gas turbine combustors has received considerable attention in recent years. A number of semi-empirical and empirical correlations relating these variables to NOx emissions have appeared in the literature. They differ both in fundamental assumptions and in their predictions. In the present work, these simple NOx correlations are compared to each other and to experimental data. A review of existing experimental data shows that an adequate data base does not exist to evaluate properly the various NOx correlations. Recommendations are proposed to resolve this problem in the future.


1980 ◽  
Author(s):  
T. M. Liu ◽  
R. M. Washam

During the development of a rich-lean staged dry low NOx combustor, the conventional trend of increasing smoke with increasing operating equivalence ratio was found when tests were run with distillate fuel (%H = 13.0). However, when tests were run with residual fuel (%H = 11.4), the trend was reversed. In addition, when the same combustor was run with blends of distillate fuel and residual fuel, a drastic improvement of smoke was observed when only 6 percent of residual fuel was mixed with distillate fuel, and for any blending of more than 10 percent of residual fuel the combustor was practically smoke free. A chemical analysis of fuel samples revealed an appreciable amount of trace metals in the residual fuel, giving rise to the suspicion that the smoke reduction may have been due in part to these trace metals. Of these elements found, vanadium is believed to be the most likely to cause smoke reduction because of its relatively high concentration.


Author(s):  
K. O. Smith ◽  
A. C. Holsapple ◽  
H. K. Mak ◽  
L. Watkins

The experimental results from the rig testing of an ultra-low NOx, natural gas-fired combustor for an 800 to 1000 kw gas turbine are presented. The combustor employed lean-premixed combustion to reduce NOx emissions and variable geometry to extend the range over which low emissions were obtained. Testing was conducted using natural gas and methanol. Testing at combustor pressures up to 6 atmospheres showed that ultra-low NOx emissions could be achieved from full load down to approximately 70% load through the combination of lean-premixed combustion and variable primary zone airflow.


Author(s):  
Iarno Brunetti ◽  
Giovanni Riccio ◽  
Nicola Rossi ◽  
Alessandro Cappelletti ◽  
Lucia Bonelli ◽  
...  

The use of hydrogen as derived fuel for low emission gas turbine is a crucial issue of clean coal technology power plant based on IGCC (Integrated Gasification Combined Cycle) technology. Control of NOx emissions in gas turbines supplied by natural gas is effectively achieved by lean premixed combustion technology; conversely, its application to NOx emission reduction in high hydrogen content fuels is not a reliable practice yet. Since the hydrogen premixed flame is featured by considerably higher flame speed than natural gas, very high air velocity values are required to prevent flash-back phenomena, with obvious negative repercussions on combustor pressure drop. In this context, the characterization of hydrogen lean premixed combustion via experimental and modeling analysis has a special interest for the development of hydrogen low NOx combustors. This paper describes the experimental and numerical investigations carried-out on a lean premixed burner prototype supplied by methane-hydrogen mixture with an hydrogen content up to 100%. The experimental activities were performed with the aim to collect practical data about the effect of the hydrogen content in the fuel on combustion parameters as: air velocity flash-back limit, heat release distribution, NOx emissions. This preliminary data set represents the starting point for a more ambitious project which foresees the upgrading of the hydrogen gas turbine combustor installed by ENEL in Fusina (Italy). The same data will be used also for building a computational fluid dynamic (CFD) model usable for assisting the design of the upgraded combustor. Starting from an existing heavy-duty gas turbine burner, a burner prototype was designed by means of CFD modeling and hot-wire measurements. The geometry of the new premixer was defined in order to control turbulent phenomena that could promote the flame moving-back into the duct, to increase the premixer outlet velocity and to produce a stable central recirculation zone in front of the burner. The burner prototype was then investigated during a test campaign performed at the ENEL’s TAO test facility in Livorno (Italy) which allows combustion test at atmospheric pressure with application of optical diagnostic techniques. In-flame temperature profiles, pollutant emissions and OH* chemiluminescence were measured over a wide range of the main operating parameters for three fuels with different hydrogen content (0, 75% and 100% by vol.). Flame control on burner prototype fired by pure hydrogen was achieved by managing both the premixing degree and the air discharge velocity, affecting the NOx emissions and combustor pressure losses respectively. A CFD model of the above-mentioned combustion test rig was developed with the aim to validate the model prediction capabilities and to help the experimental data analysis. Detailed simulations, performed by a CFD 3-D RANS commercial code, were focused on air/fuel mixing process, temperature field, flame position and NOx emission estimation.


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