Co-Firing of Hydrogen and Natural Gases in Lean Premixed Conventional and Reheat Burners (Alstom GT26)

2014 ◽  
Author(s):  
Torsten Wind ◽  
Felix Güthe ◽  
Khawar Syed
Keyword(s):  
Natural Gas ◽  
Ignition Delay ◽  
Flame Temperature ◽  
Nox Emissions ◽  
Natural Gases ◽  
Fuel Blends ◽  
Auto Ignition ◽  
Fuel Flexibility ◽  
Higher Hydrocarbons ◽  
The Impact

Addition of hydrogen (H2), produced from excess renewable electricity, to natural gas has become a new fuel type of interest for gas turbines. The addition of hydrogen extends the existing requirements to widen the fuel flexibility of gas turbine combustion systems to accommodate natural gases of varying content of higher hydrocarbons (C2+). The present paper examines the performance of the EV and SEV burners used in the sequential combustion system of Alstom’s reheat engines, which are fired with natural gas containing varying amounts of hydrogen and higher hydrocarbons. The performance is evaluated by means of single burner high pressure testing at full scale and at engine-relevant conditions. The fuel blends studied introduce variations in Wobbe index and reactivity. The latter influences, for example, laminar and turbulent burning velocities, which are significant parameters for conventional lean premixed burners such as the EV, and auto-ignition delay times, which is a significant parameter for reheat burners, such as the SEV. An increase in fuel reactivity can lead to increased NOx emissions, flashback sensitivity and flame dynamics. The impact of the fuel blends and operating parameters, such as flame temperature, on the combustion performance is studied. Results indicate that variation of flame temperature of the first burner is an effective parameter to maintain low NOx emissions as well as offsetting the impact of fuel reactivity on the auto-ignition delay time of the downstream reheat burner. The relative impact of hydrogen and higher hydrocarbons is in agreement with results from simple reactor and 1D flame analyses. The changes in combustion behaviour can be compensated by a slightly extended operation concept of the engine following the guidelines of the existing C2+ operation concept and will lead to a widened, safe operational range of Alstom reheat engines with respect to fuel flexibility without hardware modifications.

Fuel Flexibility Influences on Premixed Combustor Blowout, Flashback, Autoignition and Instability

2006 ◽  
Author(s):  
Tim Lieuwen ◽  
Vince McDonell ◽  
Eric Petersen ◽  
Domenic Santavicca
Keyword(s):  
Natural Gas ◽  
Gas Turbine ◽  
Dynamic Stability ◽  
Current Understanding ◽  
Fuel Composition ◽  
Fuel Flexibility ◽  
Lean Premixed ◽  
Gas Fuel ◽  
The Impact ◽  
Underlying Processes

This paper addresses the impact of fuel composition on the operability of lean premixed gas turbine combustors. This is an issue of current importance due to variability in the composition of natural gas fuel supplies and interest in the use of syngas fuels. Of particular concern is the effect of fuel composition on combustor blowout, flashback, dynamic stability, and autoignition. This paper reviews available results and current understanding of the effects of fuel composition on the operability of lean premixed combustors. It summarizes the underlying processes that must be considered when evaluating how a given combustor’s operability will be affected as fuel composition is varied.

Ultra-Low Emission Hydrogen/Syngas Combustion With a 1.3 MW Injector Using a Micro-Mixing Lean-Premix System

2011 ◽  
Author(s):  
Brian Hollon ◽  
Erlendur Steinthorsson ◽  
Adel Mansour ◽  
Vincent McDonell ◽  
Howard Lee
Keyword(s):  
Carbon Dioxide ◽  
Natural Gas ◽  
Flame Temperature ◽  
Fuel Mixture ◽  
Full Scale ◽  
Operating Conditions ◽  
Nox Emissions ◽  
Fuel Injector ◽  
Nitrogen Dilution ◽  
Fuel Mixtures

This paper discusses the development and testing of a full-scale micro-mixing lean-premix injector for hydrogen and syngas fuels that demonstrated ultra-low emissions and stable operation without flashback for high-hydrogen fuels at representative full-scale operating conditions. The injector was fabricated using Macrolamination technology, which is a process by which injectors are manufactured from bonded layers. The injector utilizes sixteen micro-mixing cups for effective and rapid mixing of fuel and air in a compact package. The full scale injector is rated at 1.3 MWth when operating on natural gas at 12.4 bar (180 psi) combustor pressure. The injector operated without flash back on fuel mixtures ranging from 100% natural gas to 100% hydrogen and emissions were shown to be insensitive to operating pressure. Ultra-low NOx emissions of 3 ppm were achieved at a flame temperature of 1750 K (2690 °F) using a fuel mixture containing 50% hydrogen and 50% natural gas by volume with 40% nitrogen dilution added to the fuel stream. NOx emissions of 1.5 ppm were demonstrated at a flame temperature over 1680 K (2564 °F) using the same fuel mixture with only 10% nitrogen dilution, and NOx emissions of 3.5 ppm were demonstrated at a flame temperature of 1730 K (2650 °F) with only 10% carbon dioxide dilution. Finally, using 100% hydrogen with 30% carbon dioxide dilution, 3.6 ppm NOx emissions were demonstrated at a flame temperature over 1600 K (2420 °F). Superior operability was achieved with the injector operating at temperatures below 1470 K (2186 °F) on a fuel mixture containing 87% hydrogen and 13% natural gas. The tests validated the micro-mixing fuel injector technology and the injectors show great promise for use in future gas turbine engines operating on hydrogen, syngas or other fuel mixtures of various compositions.

Impact of Ethane, Propane, and Diluent Content in Natural Gas on the Performance of a Commercial Microturbine Generator

2008 ◽  
Vol 130 (1) ◽  
Author(s):  
Richard L. Hack ◽  
Vincent G. McDonell
Keyword(s):  
Power Generation ◽  
Natural Gas ◽  
Gas Turbine ◽  
Fuel Composition ◽  
Nox Emissions ◽  
Heating Value ◽  
Designed Experiment ◽  
Methane Number ◽  
The Impact ◽  
Lean Conditions

The impact of fuel composition on the performance of power generation devices is gaining interest as the desire to diversify fuel supplies increases. In the present study, measurements of combustion performance were conducted on a commercial natural gas-fired 60kW gas turbine as a function of fuel composition. A statistically designed experiment was carried out and exhaust emissions were obtained for significant amounts of ethane and propane. In addition, a limited study of the effect of inerts was conducted. The results show that emissions of NOx, CO, and NOx∕NO are not well correlated with common descriptions of the fuel, such as higher heating value or methane number. The results and trends indicate that the presence of higher hydrocarbons in the fuel leads to appreciably higher NOx emissions for both test devices operating under similar lean conditions, while having less impact on CO emissions.

Ignition Studies of C1–C7 Natural Gas Blends at Gas-Turbine Relevant Conditions

2020 ◽  
Author(s):  
Amrit Bikram Sahu ◽  
A. Abd El-Sabor Mohamed ◽  
Snehasish Panigrahy ◽  
Gilles Bourque ◽  
Henry Curran
Keyword(s):  
Natural Gas ◽  
Gas Turbine ◽  
Ignition Delay ◽  
Delay Time ◽  
Ignition Delay Time ◽  
Gas Mixtures ◽  
Auto Ignition ◽  
Wide Range ◽  
Detailed Kinetic Model ◽  
Sensitization Effect

Abstract New ignition delay time measurements of natural gas mixtures enriched with small amounts of n-hexane and n-heptane were performed in a rapid compression machine to interpret the sensitization effect of heavier hydrocarbons on auto-ignition at gas-turbine relevant conditions. The experimental data of natural gas mixtures containing alkanes from methane to n-heptane were carried out over a wide range of temperatures (840–1050 K), pressures (20–30 bar), and equivalence ratios (φ = 0.5 and 1.5). The experiments were complimented with numerical simulations using a detailed kinetic model developed to investigate the effect of n-hexane and n-heptane additions. Model predictions show that the addition of even small amounts (1–2%) of n-hexane and n-heptane can lead to increase in reactivity by ∼40–60 ms at compressed temperature (TC) = 700 K. The ignition delay time (IDT) of these mixtures decrease rapidly with an increase in concentration of up to 7.5% but becomes almost independent of the C6/C7 concentration beyond 10%. This sensitization effect of C6 and C7 is also found to be more pronounced in the temperature range 700–900 K compared to that at higher temperatures (> 900 K). The reason is attributed to the dependence of IDT primarily on H2O2(+M) ↔ 2ȮH(+M) at higher temperatures while the fuel dependent reactions such as H-atom abstraction, RȮ2 dissociation or Q.OOH + O2 reactions are less important compared to 700–900 K, where they are very important.

Fuel Interchangeability for Lean Premixed Combustion in Gas Turbine Engines

2008 ◽  
Author(s):  
Don Ferguson ◽  
Geo. A. Richard ◽  
Doug Straub
Keyword(s):  
Natural Gas ◽  
Dynamic Response ◽  
Gas Turbine ◽  
Turbine Engines ◽  
Nox Emissions ◽  
Gas Turbine Engines ◽  
Lean Premixed Combustion ◽  
Combustion Dynamics ◽  
Rijke Tube ◽  
Fuel Blends

In response to environmental concerns of NOx emissions, gas turbine manufacturers have developed engines that operate under lean, pre-mixed fuel and air conditions. While this has proven to reduce NOx emissions by lowering peak flame temperatures, it is not without its limitations as engines utilizing this technology are more susceptible to combustion dynamics. Although dependent on a number of mechanisms, changes in fuel composition can alter the dynamic response of a given combustion system. This is of particular interest as increases in demand of domestic natural gas have fueled efforts to utilize alternatives such as coal derived syngas, imported liquefied natural gas and hydrogen or hydrogen augmented fuels. However, prior to changing the fuel supply end-users need to understand how their system will respond. A variety of historical parameters have been utilized to determine fuel interchangeability such as Wobbe and Weaver Indices, however these parameters were never optimized for today’s engines operating under lean pre-mixed combustion. This paper provides a discussion of currently available parameters to describe fuel interchangeability. Through the analysis of the dynamic response of a lab-scale Rijke tube combustor operating on various fuel blends, it is shown that commonly used indices are inadequate for describing combustion specific phenomena.

An Experimental Ignition Delay Study of Alkane Mixtures in Turbulent Flows at Elevated Pressure and Intermediate Temperatures

2010 ◽  
Author(s):  
David Beerer ◽  
Vincent McDonell ◽  
Scott Samuelsen ◽  
Leonard Angello
Keyword(s):  
Natural Gas ◽  
Turbulent Flows ◽  
Ignition Delay ◽  
Flow Reactor ◽  
Elevated Pressure ◽  
Ternary Mixtures ◽  
Turbine Engine ◽  
Binary And Ternary Mixtures ◽  
Delay Times ◽  
Higher Hydrocarbons

Autoignition delay times of mixtures of alkanes and natural gas were studied experimentally in a high pressure and intermediate temperature turbulent flow reactor. Measurements were made at pressures between 7 and 15 atm and temperatures from 785 to 935K. The blends include binary and ternary mixtures of methane, ethane and propane; along with various natural gas blends. Based on these data, the effect of higher hydrocarbons on the ignition delay time of natural gas type fuels at actual gas turbine engine conditions has been quantified. While the addition of higher hydrocarbons in quantities of up to 30% were found to reduce the ignition delay by up to a factor of four, the delay times were still found to be greater than 60 milliseconds in all cases which is well above the residence times of most engine premixers. The data were used to develop simple Arrhenius type correlations as a function of temperature, pressure and fuel composition for design use.

Design Improvement Survey for NOx Emissions Reduction of a Heavy-Duty Gas Turbine Partially Premixed Fuel Nozzle Operating With Natural Gas: Experimental Campaign

2015 ◽  
Author(s):  
Matteo Cerutti ◽  
Roberto Modi ◽  
Danielle Kalitan ◽  
Kapil K. Singh
Keyword(s):  
Pressure Drop ◽  
Natural Gas ◽  
Gas Turbine ◽  
Pollutant Emissions ◽  
Nox Emissions ◽  
Heavy Duty ◽  
Fuel Nozzle ◽  
Partially Premixed ◽  
Heavy Duty Gas Turbine ◽  
The Impact

As government regulations become increasingly strict with regards to combustion pollutant emissions, new gas turbine combustor designs must produce lower NOx while also maintaining acceptable combustor operability. The design and implementation of an efficient fuel/air premixer is paramount to achieving low emissions. Options for improving the design of a natural gas fired heavy-duty gas turbine partially premixed fuel nozzle have been considered in the current study. In particular, the study focused on fuel injection and pilot/main interaction at high pressure and high inlet temperature. NOx emissions results have been reported and analyzed for a baseline nozzle first. Available experience is shared in this paper in the form of a NOx correlative model, giving evidence of the consistency of current results with past campaigns. Subsequently, new fuel nozzle premixer designs have been investigated and compared, mainly in terms of NOx emissions performance. The operating range of investigation has been preliminarily checked by means of a flame stability assessment. Adequate margin to lean blow out and thermo-acoustic instabilities onset has been found while also maintaining acceptable CO emissions. NOx emission data were collected over a variety of fuel/air ratios and pilot/main splits for all the fuel nozzle configurations. Results clearly indicated the most effective design option in reducing NOx. In addition, the impact of each design modification has been quantified and the baseline correlative NOx emissions model calibrated to describe the new fuel nozzles behavior. Effect of inlet air pressure has been evaluated and included in the models, allowing the extensive use of less costly reduced pressure test campaigns hereafter. Although the observed effect of combustor pressure drop on NOx is not dominant for this particular fuel nozzle, sensitivity has been performed to consolidate gathered experience and to make the model able to evaluate even small design changes affecting pressure drop.

Study of a Rich/Lean Staged Combustion Concept for Hydrogen at Gas Turbine Relevant Conditions

2013 ◽  
Author(s):  
Felipe Bolaños ◽  
Dieter Winkler ◽  
Felipe Piringer ◽  
Timothy Griffin ◽  
Rolf Bombach ◽  
...  
Keyword(s):  
Heat Transfer ◽  
Gas Turbine ◽  
Gas Turbines ◽  
Carbon Capture ◽  
Flame Temperature ◽  
Nox Emissions ◽  
Hydrogen Fuel ◽  
Auto Ignition ◽  
Wide Range ◽  
The Rich

The combustion of hydrogen-rich fuels (> 80 % vol. H2), relevant for gas turbine cycles with “pre-combustion” carbon capture, creates great challenges in the application of standard lean premix combustion technology. The significant higher flame speed and drastically reduced auto-ignition delay time of hydrogen compared to those of natural gas, which is normally burned in gas turbines, increase the risk of higher NOX emissions and material damage due to flashback. Combustion concepts for gas turbines operating on hydrogen fuel need to be adapted to assure safe and low-emission combustion. A rich/lean (R/L) combustion concept with integrated heat transfer that addresses the challenges of hydrogen combustion has been investigated. A sub-scale, staged burner with full optical access has been designed and tested at gas turbine relevant conditions (flame temperature of 1750 K, preheat temperature of 400 °C and a pressure of 8 bar). Results of the burner tests have confirmed the capability of the rich/lean staged concept to reduce the NOx emissions for undiluted hydrogen fuel. The NOx emissions were reduced from 165 ppm measured without staging (fuel pre-conversion) to 23 ppm for an R/L design having a fuel-rich hydrogen pre-conversion of 50 % at a constant power of 8.7 kW. In the realized R/L concept the products of the first rich stage, which is ignited by a Pt/Pd catalyst (under a laminar flow, Re ≈ 1900) are combusted in a diffusion-flame-like lean stage (turbulent flow Re ≈ 18500) without any flashback risk. The optical accessibility of the reactor has allowed insight into the combustion processes of both stages. Applying OH-LIF and OH*-chemiluminescence optical techniques, it was shown that mainly homogeneous reactions at rich conditions take place in the first stage, questioning the importance of a catalyst in the system, and opening a wide range of optimization possibilities. The promising results obtained in this study suggest that such a rich/lean staged burner with integrated heat transfer could help to develop a new generation of gas turbine burners for safe and clean combustion of H2-rich fuels.

DME as a Potential Alternative Fuel for Gas Turbines: A Numerical Approach to Combustion and Oxidation Kinetics

2011 ◽  
Author(s):  
Pierre A. Glaude ◽  
Rene´ Fournet ◽  
Roda Bounaceur ◽  
Michel Molie`re
Keyword(s):  
Natural Gas ◽  
Gas Turbine ◽  
Heat Input ◽  
Ignition Delay ◽  
Gas Turbines ◽  
Ignition Temperature ◽  
Alternative Fuels ◽  
Ignition Delay Times ◽  
Auto Ignition ◽  
Delay Times

Many investigations are currently carried out in order to reduce CO2 emissions in power generation. Among alternative fuels to natural gas and gasoil in gas turbine applications, dimethyl ether (DME; formula: CH3-O-CH3) represents a possible candidate in the next years. This chemical compound can be produced from natural gas or coal/biomass gasification. DME is a good substitute for gasoil in diesel engine. Its Lower Heating Value is close to that of ethanol but it offers some advantages compared to alcohols in terms of stability and miscibility with hydrocarbons. While numerous studies have been devoted to the combustion of DME in diesel engines, results are scarce as far as boilers and gas turbines are concerned. Some safety aspects must be addressed before feeding a combustion device with DME because of its low flash point (as low as −83°C), its low auto-ignition temperature and large domain of explosivity in air. As far as emissions are concerned, the existing literature shows that in non premixed flames, DME produces less NOx than ethane taken as parent molecular structure, based on an equivalent heat input to the burner. During a field test performed in a gas turbine, a change-over from methane to DME led to a higher fuel nozzle temperature but to a lower exhaust gas temperature. NOx emissions decreased over the whole range of heat input studied but a dramatic increase of CO emissions was observed. This work aims to study the combustion behavior of DME in gas turbine conditions with the help of a detailed kinetic modeling. Several important combustion parameters, such as the auto-ignition temperature (AIT), ignition delay times, laminar burning velocities of premixed flames, adiabatic flame temperatures, and the formation of pollutants like CO and NOx have been investigated. These data have been compared with those calculated in the case of methane combustion. The model was built starting from a well validated mechanism taken from the literature and already used to predict the behavior of other alternative fuels. In flame conditions, DME forms formaldehyde as the major intermediate, the consumption of which leads in few steps to CO then CO2. The lower amount of CH2 radicals in comparison with methane flames seems to decrease the possibility of prompt-NO formation. This paper covers the low temperature oxidation chemistry of DME which is necessary to properly predict ignition temperatures and auto-ignition delay times that are important parameters for safety.

Fuel Flexibility Test Campaign on a GE10 Gas Turbine: Experimental and Numerical Results

2006 ◽  
Author(s):  
Antonio Andreini ◽  
Bruno Facchini ◽  
Luca Mangani ◽  
Stefano Cocchi ◽  
Roberto Modi
Keyword(s):  
Natural Gas ◽  
Gas Turbine ◽  
Load Condition ◽  
Co2 Concentration ◽  
Flame Stabilization ◽  
Pollutant Emissions ◽  
Nox Emissions ◽  
Predictive Tool ◽  
Fuel Flexibility ◽  
Base Load

Medium- and low-LHV fuels are receiving a continuously growing interest in stationary power applications. Besides that, since in many applications the fuels available at a site can be time by time of significantly different composition, fuel flexibility has become one of the most important requirements to be taken into account in developing power systems. A test campaign, aimed to provide a preliminary assessment of a small power gas turbine’s fuel flexibility, was carried over a full-scale GE10 prototypical unit, located at the Nuovo-Pignone manufacturing site, in Florence. The engine is a single shaft, simple cycle gas turbine designed for power generation applications, rated at 11 MW electrical power and equipped with a silos-type combustor. A variable composition gas fuel was obtained by mixing natural gas with CO2 to about 40% by vol. at engine base-load condition. Tests involved two different diffusive combustion systems: the standard version, designed for operation with natural gas, and a specific system designed for low-LHV fuels. Tests performed aimed to investigate both ignition limits and combustors’ performances, focusing on hot parts’ temperatures and pollutant emissions. Regarding NOx emissions, data collected during standard combustor’s tests were matched a simple scaling law (as a function of cycle parameters and CO2 concentration in the fuel mixture), which can be used in similar applications as a NOx predictive tool. In a following step, a CFD study was performed in order to verify in detail the effects of LHV reduction on flame structure and to compare measured and calculated NOx. STAR-CD™ code was employed as main CFD solver while turbulent combustion and NOx models were specifically developed and implemented using STAR’s user-subroutine features. Both models are based on classical laminar-flamelet approach. Three different operating points were considered at base-load conditions, varying CO2 concentration (0%, 20% and 30% vol. simulated). Numerical simulations point out the flexibility of the GE10 standard combustor to assure flame stabilization even against large variation of fuel characteristics. Calculated NOx emissions are in fairly good agreement with measured data confirming the validity of the adopted models.

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