scholarly journals Impact of Boundary Condition and Kinetic Parameter Uncertainties on NOx Predictions in Methane-Air Stagnation Flame Experiments

2021 ◽  
Author(s):  
Antoine Durocher ◽  
Jiayi Wang ◽  
Gilles Bourque ◽  
Jeffrey M. Bergthorson
Keyword(s):  
Boundary Conditions ◽  
High Pressures ◽  
Laminar Flame ◽  
Combustion Process ◽  
Industrial Applications ◽  
Parameter Uncertainties ◽  
Nox Formation ◽  
Important Species ◽  
Spectral Expansions ◽  
Combustion Properties

Abstract A comprehensive understanding of uncertainty sources in experimental measurements is required to develop robust thermochemical models for use in industrial applications. Due to the complexity of the combustion process in gas turbine engines, simpler flames are generally used to study fundamental combustion properties and measure concentrations of important species to validate and improve modelling. Stable, laminar flames have increasingly been used to study nitrogen oxide (NOx) formation in lean-to-rich compositions in low-to-high pressures to assess model predictions and improve accuracy to help develop future low-emissions systems. They allow for non-intrusive diagnostics to measure sub-ppm concentrations of pollutant molecules, as well as important precursors, and provide well-defined boundary conditions to directly compare experiments with simulations. The uncertainties of experimentally-measured boundary conditions and the inherent kinetic uncertainties in the nitrogen chemistry are propagated through one-dimensional stagnation flame simulations to quantify the relative importance of the two sources and estimate their impact on predictions. Measurements in lean, stoichiometric, and rich methane-air flames are used to investigate the production pathways active in those conditions. Various spectral expansions are used to develop surrogate models with different levels of accuracy to perform the uncertainty analysis for 15 important reactions in the nitrogen chemistry and the 6 boundary conditions (ϕ, Tin, uin, du/dzin, Tsurf, P) simultaneously. After estimating the individual parametric contributions, the uncertainty of the boundary conditions are shown to have a relatively small impact on the prediction of NOx compared to kinetic uncertainties in these laboratory experiments. These results show that properly calibrated laminar flame experiments can, not only provide validation targets for modelling, but also accurate indirect measurements that can later be used to infer individual kinetic rates to improve thermochemical models.

Skeletal Kinetic Modeling for the Combustion of Endothermic Hydrocarbon Fuel in Hypersonic Vehicle

2021 ◽  
pp. 1-24
Author(s):  
Hui-Sheng Peng ◽  
Bei-Jing Zhong
Keyword(s):  
Surrogate Model ◽  
Laminar Flame ◽  
Combustion Process ◽  
Hydrocarbon Fuel ◽  
Kinetic Mechanism ◽  
Chemical Kinetic ◽  
Vital Role ◽  
Reacting Flow ◽  
Combustion Properties ◽  
Endothermic Hydrocarbon Fuel

Abstract Chemical kinetic mechanism plays a vital role in the deep learning of reacting flow in practical combustors, which can help obtain many details of the combustion process. In this paper, a surrogate model and a skeletal mechanism for an endothermic hydrocarbon fuel were developed for further investigations of the combustion performance in hypersonic vehicles: (1) The surrogate model consists of 81.3 mol% decalin and 18.7 mol% n-dodecane, which were determined by both the composition distributions and key properties of the target endothermic hydrocarbon fuel. (2) A skeletal kinetic mechanism only containing 56 species and 283 reactions was developed by the method of “core mechanism​ sub mechanism”. This mechanism can be conveniently applied to the simulation of practical combustors for its affordable scale. (3) Accuracies of the surrogate model and the mechanism were systematically validated by the various properties of the target fuel under pressures of 1-20atm, temperatures of 400-1250K, and equivalence ratios of 0.5-1.5. The overall errors for the ignition and combustion properties are no more than 0.4 and 0.1, respectively. (4) Laminar flame speeds of the target fuel and the surrogate model fuel were also measured for the validations. Results show that both the surrogate model and the mechanism can well predict the properties of the target fuel. The mechanism developed in this work is valuable to the further design and optimization of the propulsion systems.

Assessment of Different Actuator Concepts for Acoustic Boundary Control of a Premixed Combustor

2008 ◽  
Vol 131 (2) ◽  
Author(s):  
Mirko R. Bothien ◽  
Jonas P. Moeck ◽  
Christian Oliver Paschereit
Keyword(s):  
Boundary Conditions ◽  
Combustion Process ◽  
Industrial Applications ◽  
Full Scale ◽  
Operating Conditions ◽  
Test Rig ◽  
Acoustic Boundary Conditions ◽  
Control Scheme ◽  
Finite Element Calculations ◽  
Control Authority

In the design process, new burners are generally tested in combustion test rigs. With these experiments, computational fluid dynamics, and finite element calculations, the burners’ performance in the full-scale engine is sought to be predicted. Especially, information about the thermoacoustic behavior and the emissions is very important. As the thermoacoustics strongly depend on the acoustic boundary conditions of the system, it is obvious that test rig conditions should match or be close to those of the full-scale engine. This is, however, generally not the case. Hence, if the combustion process in the test rig is stable at certain operating conditions, it may show unfavorable dynamics at the same conditions in the engine. In previous works, the authors introduced an active control scheme, which is able to mimic almost arbitrary acoustic boundary conditions. Thus, the test rig properties can be tuned to correspond to those of the full-scale engine. The acoustic boundary conditions were manipulated using woofers. In the present study, proportional valves are investigated regarding their capabilities of being used in the control scheme. It is found that the test rig impedance can be tuned equally well. In contrast to the woofers, however, the valves could be used in industrial applications, as they are more robust and exhibit more control authority. Additionally, the control scheme is further developed and used to tune the test rig at discrete frequencies. This exhibits certain advantages compared with the case of control over a broad frequency band.

Assessment of Different Actuator Concepts for Acoustic Boundary Control of a Premixed Combustor

2008 ◽  
Author(s):  
Mirko R. Bothien ◽  
Jonas P. Moeck ◽  
Christian Oliver Paschereit
Keyword(s):  
Boundary Conditions ◽  
Combustion Process ◽  
Industrial Applications ◽  
Full Scale ◽  
Operating Conditions ◽  
Test Rig ◽  
Acoustic Boundary Conditions ◽  
Control Scheme ◽  
Finite Element Calculations ◽  
Control Authority

In the design process, new burners are generally tested in combustion test rigs. With these experiments, computational fluid dynamics, and finite element calculations, the burners’ performance in the full-scale engine is sought to be predicted. Especially, information about the thermoacoustic behavior and the emissions is very important. As the thermoacoustics strongly depend on the acoustic boundary conditions of the system, it is obvious that test rig conditions should match or be close to those of the full-scale engine. This is, however, generally not the case. Hence, if the combustion process in the test rig is stable at certain operating conditions, it may show unfavorable dynamics at the same conditions in the engine. In a previous paper (GT2007-27796), the authors introduced an active control scheme which is able to mimic almost arbitrary acoustic boundary conditions. Thus, the test rig properties can be tuned to correspond to those of the full-scale engine. The acoustic boundary conditions were manipulated using woofers. In the present study, proportional valves are investigated regarding their capabilities of being used in the control scheme. It is found that the test rig impedance can be tuned equally well. In contrast to the woofers, however, the valves could be used in industrial applications, as they are more robust and exhibit more control authority. Additionally, the control scheme is further developed and used to tune the test rig at discrete frequencies. This exhibits certain advantages compared to the case of control over a broad frequency band.

scholarly journals Energy Treatment of Solid Municipal Waste in Combination with Biomass by Decentralized Method with the Respect to the Negative Effects on the Environment

2021 ◽  
Vol 13 (8) ◽  
pp. 4405
Author(s):  
Miroslav Rimar ◽  
Olha Kulikova ◽  
Andrii Kulikov ◽  
Marcel Fedak
Keyword(s):  
Heavy Metals ◽  
Municipal Solid Waste ◽  
Solid Waste ◽  
Process Analysis ◽  
Combustion Process ◽  
Municipal Waste ◽  
Negative Effects ◽  
Combustion Properties ◽  
Polycyclic Aromatic ◽  
Fuel Mixtures

Waste is a product of society and one of the biggest challenges for future generations is to understand how to sustainably dispose of large amounts of waste. The main objective of this study was to determine the possibility and conditions of the decentralized combustion of non-hazardous municipal waste. The analysis of the combustion properties of a mixture of wood chips and 20–30% of municipal solid waste showed an improvement in the operating parameters of the combustion process. Analysis also confirmed that the co-combustion of dirty fuels and biomass reduced the risk of releasing minerals and heavy metals from fuel into the natural environment. Approximately 55% of the heavy metals passed into the ash. The analysis of municipal solid waste and fuel mixtures containing municipal solid waste for polycyclic aromatic hydrocarbons showed the risk of increasing polycyclic aromatic hydrocarbon concentrations in flue gases.

Analysis of Water–Fuel Ratio Variation in a Gas Turbine With a Wet-Compressor System by Change in Fuel Composition

2017 ◽  
Vol 140 (5) ◽  
Author(s):  
Yonatan Cadavid ◽  
Andres Amell ◽  
Juan Alzate ◽  
Gerjan Bermejo ◽  
Gustavo A. Ebratt
Keyword(s):  
Gas Turbine ◽  
Burning Velocity ◽  
Thermal Power ◽  
Flame Temperature ◽  
Fuel Composition ◽  
Nox Formation ◽  
Gaseous Hydrocarbon ◽  
Power Generators ◽  
Fuel Ratio ◽  
Combustion Properties

The wet compressor (WC) has become a reliable way to reduce gas emissions and increase gas turbine efficiency. However, fuel source diversification in the short and medium terms presents a challenge for gas turbine operators to know how the WC will respond to changes in fuel composition. For this study, we assessed the operational data of two thermal power generators, with outputs of 610 MW and 300 MW, in Colombia. The purpose was to determine the maximum amount of water that can be added into a gas turbine with a WC system, as well as how the NOx/CO emissions vary due to changes in fuel composition. The combustion properties of different gaseous hydrocarbon mixtures at wet conditions did not vary significantly from each other—except for the laminar burning velocity. It was found that the fuel/air equivalence ratio in the turbine reduced with lower CH4 content in the fuel. Less water can be added to the turbine with leaner combustion; the water/fuel ratio was decreased over the range of 1.4–0.4 for the studied case. The limit is mainly due to a reduction in flame temperature and major risk of lean blowout (LBO) or dynamic instabilities. A hybrid reaction mechanism was created from GRI-MECH 3.0 and NGIII to model hydrocarbons up to C5 with NOx formation. The model was validated with experimental results published previously in literature. Finally, the effect of atmospheric water in the premixed combustion was analyzed and explained.

Influence of Imperfections in the Working Media on Diesel Engine Indicator Process: Part 2 — Results

1998 ◽  
Author(s):  
Stanislav N. Danov ◽  
Ashwani K. Gupta
Keyword(s):  
Mathematical Model ◽  
Diesel Engine ◽  
High Pressures ◽  
Combustion Process ◽  
Ideal Gas ◽  
Working Medium ◽  
High Pressures And Temperatures ◽  
Specific Heat Capacities ◽  
Working Media ◽  
The Mathematical Model

Abstract In the companion Part 1 of this two-part series paper several improvements to the mathematical model of the energy conversion processes, taking place in a diesel engine cylinder, have been proposed. Analytical mathematical dependencies between thermal parameters (pressure, temperature, volume) and caloric parameters (internal energy, enthalpy, specific heat capacities) have been obtained. These equations have been used to provide an improved mathematical model of diesel engine indicator process. The model is based on the first law of thermodynamics, by taking into account imperfections in the working media which appear when working under high pressures and temperatures. The numerical solution of the simultaneous differential equations is obtained by Runge-Kutta type method. The results show that there are significant differences between the values calculated by equations for ideal gas and real gas under conditions of high pressures and temperatures. These equations are then used to solve the desired practical problem in two different two-stroke turbo-charged engines (8DKRN 74/160 and Sulzer-RLB66). The numerical experiments show that if the pressure is above 8 to 9 MPa, the working medium imperfections must be taken into consideration. The mathematical model presented here can also be used to model combustion process of other thermal engines, such as advanced gas turbine engines and rockets.

CO and H2O Time-Histories in Shock-Heated Blends of Methane and Ethane for Assessment of a Chemical Kinetics Model

2017 ◽  
Vol 139 (12) ◽  
Author(s):  
O. Mathieu ◽  
C. R. Mulvihill ◽  
E. L. Petersen ◽  
Y. Zhang ◽  
H. J. Curran
Keyword(s):  
Chemical Kinetics ◽  
Laminar Flame ◽  
Combustion Process ◽  
Time History ◽  
Good Marker ◽  
Ignition Delay Times ◽  
Depletion Rate ◽  
Time Histories ◽  
Main Components ◽  
Detailed Kinetics

Methane and ethane are the two main components of natural gas and typically constitute more than 95% of it. In this study, a mixture of 90% CH4/10% C2H6 diluted in 99% Ar was studied at fuel lean (equiv. ratio = 0.5) conditions, for pressures around 1, 4, and 10 atm. Using laser absorption diagnostics, the time histories of CO and H2O were recorded between 1400 and 1800 K. Water is a final product from combustion, and its formation is a good marker of the completion of the combustion process. Carbon monoxide is an intermediate combustion species, a good marker of incomplete/inefficient combustion, as well as a regulated pollutant for the gas turbine industry. Measurements such as these species time histories are important for validating and assessing chemical kinetics models beyond just ignition delay times and laminar flame speeds. Time-history profiles for these two molecules were compared to a state-of-the-art detailed kinetics mechanism as well as to the well-established GRI 3.0 mechanism. Results show that the H2O profile is accurately reproduced by both models. However, discrepancies are observed for the CO profiles. Under the conditions of this study, the CO profiles typically increase rapidly after an induction time, reach a maximum, and then decrease. This maximum CO mole fraction is often largely over-predicted by the models, whereas the depletion rate of CO past this peak is often over-estimated for pressures above 1 atm.

CO and H2O Time-Histories in Shock-Heated Blends of Methane and Ethane for Assessment of a Chemical Kinetics Model

2017 ◽  
Author(s):  
O. Mathieu ◽  
C. Mulvihill ◽  
E. L. Petersen ◽  
Y. Zhang ◽  
H. J. Curran
Keyword(s):  
Gas Turbine ◽  
Chemical Kinetics ◽  
Laminar Flame ◽  
Combustion Process ◽  
Practical Interest ◽  
Time History ◽  
Good Marker ◽  
Ignition Delay Times ◽  
Time Histories ◽  
Detailed Kinetics

Methane and ethane are the two main components of natural gas and typically constitute more than 95% of it. In this study, a mixture of 90% CH4 /10% C2H6 diluted in 99% Ar was studied at fuel lean (ϕ = 0.5) conditions, for pressures around 1, 4, and 10 atm. Using laser absorption diagnostics, the time histories of CO and H2O were recorded between 1400 and 1800 K. Water is a final product from hydrocarbon combustion, and following its formation is a good marker of the completion of the combustion process. Carbon monoxide is an intermediate combustion species, a good marker of incomplete/inefficient combustion, as well as a regulated pollutant for the gas turbine industry. Measurements such as these species time histories are important for validating and assessing chemical kinetics models beyond just ignition delay times and laminar flame speeds. Time-history profiles for these two molecules measured herein were compared to a modern, state-of-the-art detailed kinetics mechanism as well as to the well-established GRI 3.0 mechanism. Results show that the H2O profile is accurately reproduced by both models. However, discrepancies are observed for the CO profiles. Under the conditions of this study, the measured CO profiles typically increase rapidly after an induction time, reach a maximum and then decrease. This maximum CO mole fraction is often largely over-predicted by the models, whereas the depletion rate of CO past this peak is often over-estimated by the models for pressures above 1 atm. This study demonstrates the need to improve on the accuracy of the HCCO reactions involved in CO formation for pressures of practical interest for the gas turbine industry.

Real-time capable simulation of diesel combustion processes for HiL applications

2017 ◽  
Vol 19 (2) ◽  
pp. 214-229 ◽  
Author(s):  
Daniel Neumann ◽  
Christian Jörg ◽  
Nils Peschke ◽  
Joschka Schaub ◽  
Thorsten Schnorbus
Keyword(s):  
Heat Release ◽  
Real Time ◽  
Fuel Injection ◽  
Combustion Process ◽  
Boost Pressure ◽  
Diesel Combustion ◽  
Main Challenge ◽  
Combustion Properties ◽  
Input Variables ◽  
Improved Model

The complexity of the development processes for advanced diesel engines has significantly increased during the last decades. A further increase is to be expected, due to more restrictive emission legislations and new certification cycles. This trend leads to a higher time exposure at engine test benches, thus resulting in higher costs. To counter this problem, virtual engine development strategies are being increasingly used. To calibrate the complete powertrain and various driving situations, model in the loop and hardware in the loop concepts have become more important. The main effort in this context is the development of very accurate but also real-time capable engine models. Besides the correct modeling of ambient condition and driver behavior, the simulation of the combustion process is a major objective. The main challenge of modeling a diesel combustion process is the description of mixture formation, self-ignition and combustion as precisely as possible. For this purpose, this article introduces a novel combustion simulation approach that is capable of predicting various combustion properties of a diesel process. This includes the calculation of crank angle resolved combustion traces, such as heat release and other thermodynamic in-cylinder states. Furthermore, various combustion characteristics, such as combustion phasing, maximum gradients and engine-out temperature, are available as simulation output. All calculations are based on a physical zero-dimensional heat release model. The resulting reduction of the calibration effort and the improved model robustness are the major benefits in comparison to conventional data-driven combustion models. The calibration parameters directly refer to geometric and thermodynamic properties of a given engine configuration. Main input variables to the model are the fuel injection profile and air path–related states such as exhaust gas recirculation rate and boost pressure. Thus, multiple injection event strategies or novel air path control structures for future engine control concepts can be analyzed.

scholarly journals Biological activity of carbon nanoparticles produced in combustion process

2019 ◽  
Vol 179 (4) ◽  
pp. 269-273
Author(s):  
Jarosław KAŁUŻNY ◽  
Natalia IDASZEWSKA ◽  
Tomasz RUNKA ◽  
Adam PIASECKI ◽  
Marek NOWICKI ◽  
...  
Keyword(s):  
Carbon Nanotubes ◽  
Experimental Study ◽  
Carbon Nanoparticles ◽  
Dominant Role ◽  
Combustion Process ◽  
Industrial Applications ◽  
Carbon Allotropes ◽  
Air Purifier ◽  
Residential Space

In the recent years industrial applications of carbon allotropes such as carbon nanotubes (CNTs) and graphene have been tested extensively, thus justifying research on the environmental impact these materials have. In the current paper we compare EDS spectroscopy results of a cabin filter used in a car to a filter used in an air purifier inside a residential space. The contaminants adsorbed on the carbon nanoparticles trapped in both types of filters allows for determining of their source of origin demonstrating clearly the dominant role of non-road emissions in Poland. Finally we present the experimental study on the growth of plants on substrates intentionally enriched with CNTs.

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