Modeling Diesel Spray Flame Lift-Off, Sooting Tendency and NOx Emissions Using Detailed Chemistry With Phenomenological Soot Model

2005 ◽  
Author(s):  
Song-Charng Kong ◽  
Yong Sun ◽  
Rolf D. Reitz
Keyword(s):  
Nox Reduction ◽  
Diesel Spray ◽  
Nox Emissions ◽  
Soot Emission ◽  
Detailed Chemistry ◽  
Emission Process ◽  
Start Of Injection ◽  
Soot Emissions ◽  
Lift Off ◽  
Soot Model

A detailed chemistry-based CFD model was developed to simulate the diesel spray combustion and emission process. A reaction mechanism of n-heptane is coupled with a reduced NOx mechanism to simulate diesel fuel oxidation and NOx formation. The soot emission process is simulated by a phenomenological soot model that uses a competing formation and oxidation rate formulation. The model is applied to predict the diesel spray lift-off length and its sooting tendency under high temperature and pressure conditions with good agreement with experiments of Sandia. Various nozzle diameters and chamber conditions were investigated. The model successfully predicts that the sooting tendency is reduced as the nozzle diameter is reduced and/or the initial chamber gas temperature is decreased, as observed by the experiments. The model is also applied to simulate diesel engine combustion under PCCI-like conditions. Trends of heat release rate, NOx and soot emissions with respect to EGR levels and start-of-injection timings are also well predicted. Both experiments and models reveal that soot emissions peak when the start of injection occurs close to TDC. The model indicates that low soot emission at early SOI is due to better oxidation while low soot emission at late SOI is due to less formation. Since NOx emissions decrease monotonically with injection retardation, a late injection scheme can be utilized for simultaneous soot and NOx reduction for the engine conditions investigated in this study.

Modeling Diesel Spray Flame Liftoff, Sooting Tendency, and NOx Emissions Using Detailed Chemistry With Phenomenological Soot Model

2005 ◽  
Vol 129 (1) ◽  
pp. 245-251 ◽  
Author(s):  
Song-Charng Kong ◽  
Yong Sun ◽  
Rolf D. Rietz
Keyword(s):  
Nox Reduction ◽  
Diesel Spray ◽  
Nox Emissions ◽  
Soot Emission ◽  
Gas Temperature ◽  
Detailed Chemistry ◽  
Emission Process ◽  
Start Of Injection ◽  
Soot Emissions ◽  
Soot Model

A detailed chemistry-based CFD model was developed to simulate the diesel spray combustion and emission process. A reaction mechanism of n-heptane is coupled with a reduced NOx mechanism to simulate diesel fuel oxidation and NOx formation. The soot emission process is simulated by a phenomenological soot model that uses a competing formation and oxidation rate formulation. The model is applied to predict the diesel spray lift-off length and its sooting tendency under high temperature and pressure conditions with good agreement with experiments of Sandia. Various nozzle diameters and chamber conditions were investigated. The model successfully predicts that the sooting tendency is reduced as the nozzle diameter is reduced and/or the initial chamber gas temperature is decreased, as observed by the experiments. The model is also applied to simulate diesel engine combustion under premixed charge compression ignition (PCCI) conditions. Trends of heat release rate, NOx, and soot emissions with respect to EGR levels and start-of-injection timings are also well predicted. Both experiments and models reveal that soot emissions peak when the start of injection (SOI) occurs close to TDC. The model indicates that low soot emission at early SOI is due to better oxidation while low soot emission at late SOI is due to less formation. Since NOx emissions decrease monotonically with injection retardation, a late injection scheme can be utilized for simultaneous soot and NOx reduction for the engine conditions investigated in this study.

A Study on Biodiesel NOx Emission Control With the Reduced Chemical Kinetics Model

2014 ◽  
Vol 136 (10) ◽  
Author(s):  
Juncheng Li ◽  
Zhiyu Han ◽  
Cai Shen ◽  
Chia-fon Lee
Keyword(s):  
Chemical Kinetics ◽  
Combustion Process ◽  
Operating Conditions ◽  
Nox Emission ◽  
Kinetics Model ◽  
Combustion Model ◽  
Nox Emissions ◽  
Soot Emission ◽  
Start Of Injection ◽  
Combustion Processes

In this paper, the effects of the start of injection (SOI) timing and exhaust gas recirculation (EGR) rate on the nitrogen oxides (NOx) emissions of a biodiesel-powered diesel engine are studied with computational fluid dynamics (CFD) coupling with a chemical kinetics model. The KIVA code coupling with a CHEMKIN-II chemistry solver is applied to the simulation of the in-cylinder combustion process. A surrogate biodiesel mechanism consisting of two fuel components is employed as the combustion model of soybean biodiesel. The in-cylinder combustion processes of the cases with four injection timings and three EGR rates are simulated. The simulation results show that the calculated NOx emissions of the cases with default EGR rate are reduced by 20.3% and 32.9% when the injection timings are delayed by 2- and 4-deg crank angle, respectively. The calculated NOx emissions of the cases with 24.0% and 28.0% EGR are reduced by 38.4% and 62.8%, respectively, compared to that of the case with default SOI and 19.2% EGR. But higher EGR rate deteriorates the soot emission. When EGR rate is 28.0% and SOI is advanced by 2 deg, the NOx emission is reduced by 55.1% and soot emission is controlled as that of the case with 24% EGR and default SOI. The NOx emissions of biodiesel combustion can be effectively improved by SOI retardation or increasing EGR rate. Under the studied engine operating conditions, introducing more 4.8% EGR into the intake air with unchanged SOI is more effective for NOx emission controlling than that of 4-deg SOI retardation with default EGR rate.

A Study on Biodiesel NOx Emission Control With the Reduced Chemical Kinetics Model

2013 ◽  
Author(s):  
Juncheng Li ◽  
Chia-fon F. Lee ◽  
Zhiyu Han ◽  
Cai Shen ◽  
Mianzhi Wang
Keyword(s):  
Chemical Kinetics ◽  
Nox Emission ◽  
Kinetics Model ◽  
Combustion Model ◽  
Nox Emissions ◽  
Soot Emission ◽  
Start Of Injection ◽  
Soybean Biodiesel ◽  
Combustion Processes ◽  
Gas Recirculation

In this paper, the effects of the start of injection (SOI) timing and EGR rate on the nitrogen oxide (NOx) emissions of biodiesel-powered diesel engine are studied with computational fluid dynamics (CFD) coupling with a chemical kinetics model. A surrogate biodiesel mechanism consisting of two fuel components is employed as the combustion model of soybean biodiesel. The in-cylinder combustion processes of the cases with four injection timings and three exhaust gas recirculation (EGR) rates are simulated. The simulation results show that the NOx emissions of biodiesel combustion can be effectively improved by SOI retardation or increasing EGR rate. The calculated NOx emissions of the cases with default EGR rate are reduced by 20.3% and 32.9% when the injection timings are delayed by 2-degree and 4-degree crank angle, respectively. The calculated NOx emissions of the cases with 24.0% and 28.0% EGR are reduced by 38.4% and 62.8%, respectively, compared to that of the case with default SOI and 19.2% EGR. But higher EGR rate deteriorates the soot emission. When EGR rate is 28.0% and SOI is advanced by 2-degree, the NOx emission is reduced by 55.1% and soot emission is controlled as that of the case with 24% EGR and default SOI.

Numerical Investigation of Fuel Effects on Soot Emissions at Heavy-Duty Diesel Engine Conditions

2018 ◽  
Author(s):  
Meng Tang ◽  
Yuanjiang Pei ◽  
Yu Zhang ◽  
Michael Traver ◽  
David Cleary ◽  
...  
Keyword(s):  
Diesel Engine ◽  
Turbulence Model ◽  
Soot Formation ◽  
Heavy Duty ◽  
Cfd Simulations ◽  
Heavy Duty Diesel Engine ◽  
Soot Emissions ◽  
Heavy Duty Diesel ◽  
Lift Off ◽  
Soot Model

Gasoline compression ignition (GCI) engine technology has shown the potential to achieve high fuel efficiency with low criteria pollutant emissions. In order to guide the design and optimization of GCI combustion, it is essential to develop high-fidelity simulation tools. Building on the previous work in computational fluid dynamic (CFD) simulations of spray combustion, this work focuses on predicting the soot emissions in a constant-volume vessel representative of heavy-duty diesel engine applications for an ultra-low sulfur diesel (ULSD) and a high reactivity (Research Octane Number 60) gasoline, and comparing the soot evolution characteristics of the two fuels. Simulations were conducted using both Reynolds Averaged Navier-Stokes (RANS) and Large Eddy Simulation (LES) turbulence models. Extensive model validations were performed against the experimental soot emissions data for both fuels. It was found that the simulation results using the LES turbulence model agreed better with the measured ignition delays and liftoff lengths than the RANS turbulence model. In addition, two soot models were evaluated in the current study, including an empirical two-step soot formation and oxidation model, and a detailed soot model that involves poly-aromatic hydrocarbon (PAH) chemistry. Validations showed that the separation of the flame lift-off location and the soot lift-off location and the relative natural luminosity signals were better predicted by the detailed soot model combined with the LES turbulence model. Qualitative comparisons of simulated local soot concentration distributions against experimental measurements in the literature confirmed the model’s performance. CFD simulations showed that the transition of domination from soot formation to soot oxidation was fuel-dependent, and the two fuels exhibited different temporal and spatial characteristics of soot emissions. CFD simulations also confirmed the lower sooting propensity of gasoline compared to ULSD under all investigated conditions.

Two-Stroke Marine Diesel Engine Variable Injection Timing System Performance Evaluation and Optimum Setting for Minimum Fuel Consumption at Acceptable NOx Levels

2014 ◽  
Author(s):  
Dimitrios T. Hountalas ◽  
Spiridon Raptotasios ◽  
Antonis Antonopoulos ◽  
Stavros Daniolos ◽  
Iosif Dolaptzis ◽  
...  
Keyword(s):  
Diesel Engine ◽  
Fuel Consumption ◽  
Engine Performance ◽  
Operating Conditions ◽  
Specific Fuel Consumption ◽  
Injection Timing ◽  
Nox Emissions ◽  
Pressure Measurements ◽  
Cylinder Pressure ◽  
Start Of Injection

Currently the most promising solution for marine propulsion is the two-stroke low-speed diesel engine. Start of Injection (SOI) is of significant importance for these engines due to its effect on firing pressure and specific fuel consumption. Therefore these engines are usually equipped with Variable Injection Timing (VIT) systems for variation of SOI with load. Proper operation of these systems is essential for both safe engine operation and performance since they are also used to control peak firing pressure. However, it is rather difficult to evaluate the operation of VIT system and determine the required rack settings for a specific SOI angle without using experimental techniques, which are extremely expensive and time consuming. For this reason in the present work it is examined the use of on-board monitoring and diagnosis techniques to overcome this difficulty. The application is conducted on a commercial vessel equipped with a two-stroke engine from which cylinder pressure measurements were acquired. From the processing of measurements acquired at various operating conditions it is determined the relation between VIT rack position and start of injection angle. This is used to evaluate the VIT system condition and determine the required settings to achieve the desired SOI angle. After VIT system tuning, new measurements were acquired from the processing of which results were derived for various operating parameters, i.e. brake power, specific fuel consumption, heat release rate, start of combustion etc. From the comparative evaluation of results before and after VIT adjustment it is revealed an improvement of specific fuel consumption while firing pressure remains within limits. It is thus revealed that the proposed method has the potential to overcome the disadvantages of purely experimental trial and error methods and that its use can result to fuel saving with minimum effort and time. To evaluate the corresponding effect on NOx emissions, as required by Marpol Annex-VI regulation a theoretical investigation is conducted using a multi-zone combustion model. Shop-test and NOx-file data are used to evaluate its ability to predict engine performance and NOx emissions before conducting the investigation. Moreover, the results derived from the on-board cylinder pressure measurements, after VIT system tuning, are used to evaluate the model’s ability to predict the effect of SOI variation on engine performance. Then the simulation model is applied to estimate the impact of SOI advance on NOx emissions. As revealed NOx emissions remain within limits despite the SOI variation (increase).

THE METHOD OF NITROGEN OXIDE EMISSION REDUCTION DURING THE COMBUSTION OF GASEOUS FUEL IN MUNICIPAL THERMAL POWER BOILERS

2020 ◽  
Vol 5 (3) ◽  
pp. 18-33
Author(s):  
Sylwia Janta-Lipińska ◽  
Keyword(s):  
European Union ◽  
Emission Reduction ◽  
Thermal Power ◽  
Nox Reduction ◽  
Gaseous Fuel ◽  
Nox Emissions ◽  
The European Union ◽  
Nitrogen Oxide Emission ◽  
Boiler Efficiency ◽  
Injection Technology

The nitrogen oxides in a flame of burning fuel can be created by many mechanisms. The amount of NOx concentration emitted to the ground atmosphere mainly depends on the type of fuel burned in the industrial and heating boilers. Changes in the country's thermal policy and requirements that are set for us by the European Union States are forcing us to reduce greenhouse gas emissions. Directed metered ballast method is one of the most attractive techniques for reducing NOx emissions. In recent years, moisture injection technology is still investigated on low and medium power thermal power boilers operating on gaseous fuel. The goal of this work was to perform the investigations of the process of a moisture injection into the zones of decisive influence (SDW-I and SDW-II) on steam and water boilers: DKVR 10-13, DKVR 20-13, DE 25-14 and PTVM-50. The obtained results clearly show how the proposed method affects NOx reduction and boiler efficiency.

NOx Emissions in a Steel Reheat Furnace Firing By-Product Fuels

2001 ◽  
Author(s):  
Bradley R. Adams ◽  
Dave H. Wang
Keyword(s):  
Low Cost ◽  
Nox Reduction ◽  
Coke Oven ◽  
Cfd Modeling ◽  
Stoichiometric Ratio ◽  
Nox Emissions ◽  
Confined Space ◽  
Nox Formation ◽  
Reheat Furnace ◽  
Bottom Zone

Abstract A DOE-funded program was used to understand the mechanisms that control the formation of NOx during the combustion of steelmaking by-product fuels and to investigate possible low-cost control options to minimize the NOx emissions. This paper discusses the CFD modeling results of NOx emissions in a reheat furnace. The reheat furnace has a total of 20 burners distributed over three firing zones. The furnace is fired at a rate of 250 × 106 Btu/hr and an overall stoichiometric ratio of 1.06 (fuel lean). Fuels with heating values of approximate 500 Btu/SCF were examined, including coke oven gas (COG), blast furnace gas (BFG) and a blend of COG, BFG, natural gas (NG) and nitrogen. A good range of process variables was modeled to examine effects of fuel type, air preheat, stoichiometric ratio, firing rate and burner stoichiometry distribution on NOx emissions. Modeling results indicated that NOx formation in the reheat furnace is dominated by thermal NO, with some variation depending on the fuel fired. Temperature profiles showed an effective separation of the furnace interior into top and bottom zones as a result of the steel slab barrier. Higher temperatures characterized the bottom zone and elevated NOx levels as a result of the confined space and enhanced fuel air mixing provided by the slab supports. Results also showed that reburning of NOx plays a significant role in final NOx emissions with 30–40% of NOx formed being reduced by reburning in most cases. Modeling identified that operating the side burners in each burner zone slightly substoichiometric (while maintaining the overall furnace stoichiometry at 1.06) provided significant NOx reduction via reburning. NOx reductions of 23% and 30% were predicted when firing with COG and COG-NG-Air fuels, respectively. Overall furnace exit temperatures and heat flux profiles were not significantly affected by the biased firing.

A NOx Reduction Project for a GT11 Type Gas Turbine

2005 ◽  
Author(s):  
Lars O. Nord ◽  
David R. Schoemaker ◽  
Helmer G. Andersen
Keyword(s):  
Power Plant ◽  
Distribution System ◽  
Gas Turbines ◽  
Nox Reduction ◽  
Measurement Data ◽  
Combustion Stability ◽  
Study Phase ◽  
Nox Emissions ◽  
Ambient Conditions ◽  
Exhaust Temperature

A study was initiated to investigate the possibility of significantly reducing the NOx emissions at a power plant utilizing, among other manufacturers, ALSTOM GT11 type gas turbines. This study is limited to one of the GT11 type gas turbines on the site. After the initial study phase, the project moved on to a mechanical implementation stage, followed by thorough testing and tuning. The NOx emissions were to be reduced at all ambient conditions, but particularly at cold conditions (below 0°C) where a NOx reduction of more than 70% was the goal. The geographical location of the power plant means cold ambient conditions for a large part of the year. The mechanical modifications included the addition of Helmholtz damper capacity with an approximately 30% increase in volume for passive thermo-acoustic instability control, significant piping changes to the fuel distribution system in order to change the burner configuration, and installation of manual valves for throttling of the fuel gas to individual burners. Subsequent to the mechanical modifications, significant time was spent on testing and tuning of the unit to achieve the wanted NOx emissions throughout a major part of the load range. The tuning was, in addition to the main focus of the NOx reduction, also focused on exhaust temperature spread, combustion stability, CO emissions, as well as other parameters. The measurement data was acquired through a combination of existing unit instrumentation and specific instrumentation added to aid in the tuning effort. The existing instrumentation readings were polled from the control system. The majority of the added instrumentation was acquired via the FieldPoint system from National Instruments. The ALSTOM AMODIS plant-monitoring system was used for acquisition and analysis of all the data from the various sources. The project was, in the end, a success with low NOx emissions at part load and full load. As a final stage of the project, the CO emissions were also optimized resulting in a nice compromise between the important parameters monitored, namely NOx emissions, CO emissions, combustion stability, and exhaust temperature distribution.

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