Synergistic Antiwear Effects of Zinc Dialkyl Dithiophosphate and Different Detergents

Author(s):  
G. Pennecot ◽  
K. Komvopoulos ◽  
E. S. Yamaguchi

The effectiveness of blends consisting of base oil, some secondary zinc dialkyl dithiophosphate (ZDDP), and different detergents to form antiwear tribofilms on steel surfaces sliding in the boundary lubrication regime was investigated in the temperature range of 105–125°C. The efficacy of the tribofilms formed from these blends was evaluated in terms of contact voltage and wear rate measurements. The best antiwear performance was demonstrated by the tribofilm formed from the blend containing sulphonate detergent. The results of this study provide insight into competing effects between ZDDP and different detergents that affect significantly the antiwear performance of the formed tribofilms.

Author(s):  
S L Smith ◽  
D Dowson ◽  
A A J Goldsmith

It has been found that a remarkable reduction in the wear of metal-on-metal hip joints can be achieved by simply increasing the diameter of the joint. A tribological evaluation of metal-on-metal joints of 16, 22,225, 28 and 36 mm diameter was conducted in 25 per cent bovine serum using a hip joint simulator. The joints were subject to dynamic motion and loading cycles simulating walking for both lubrication and wear studies. For each size of joint in the lubrication study, an electrical resistivity technique was used to detect the extent of surface separation through a complete walking cycle. Wear of each size of joint was measured gravimetrically in wear tests of at least 2 × 106 cycles duration. Joints of 16 and 22.225mm diameter showed no surface separation in the lubrication study. This suggested that wear would be proportional to the sliding distance and hence joint size in this boundary lubrication regime. A 28 mm diameter joint showed only limited evidence of surface separation suggesting that these joints were operating in a mixed lubrication regime. A 36 mm diameter joint showed surface separation for considerable parts of each walking cycle and hence evidence of the formation of a protective lubricating film. Wear testing of 16 and 22.225mm diameter metal-on-metal joints gave mean wear rates of 4.85 and 6.30mm3/106 cycles respectively. The ratio of these wear rates, 0.77, is approximately the same as the joint diameters ratio, 16/22.225 or 0.72, as expected from simple wear theory for dry or boundary lubrication conditions. No bedding-in was observed with these smaller diameter joints. For the 28 mm diameter joint, from 0 to 2 × 106 cycles, the mean wear rate was 1.62 mm3/106 cycles as the joints bedded-in. Following bedding-in, from 2.0 × 106 to 4.7 × 106 cycles, the wear rate was 0.54mm3/106 cycles. As reported previously by Goldsmith in 2000 [1], the mean steady state wear rate of the 36 mm diameter joints was lower than those of all the other diameters at 0.07 mm3/106 cycles. For a range of joints of various diameters, subjected to identical test conditions, mean wear rates differed by almost two orders of magnitude. This study has demonstrated that the application of sound tribological principles to prosthetic design can reduce the wear of metal-on-metal joints, using currently available materials, to a negligible level.


Wear ◽  
1984 ◽  
Vol 93 (2) ◽  
pp. 117-126 ◽  
Author(s):  
J.M. Martin ◽  
J.L. Mansot ◽  
I. Berbezier ◽  
H. Dexpert

2019 ◽  
Vol 9 (1) ◽  
Author(s):  
Masaki Tsuchiko ◽  
Saiko Aoki

Abstract This study aims to investigate the influence of surface morphology on boundary-lubricated friction in a stearic acid solution. The surface morphology was controlled by fabricating submicrometer line-and-space patterns on Si(100) surface via photolithography. The boundary-lubricated friction on the patterns was measured by in-liquid lateral force microscopy for both transverse and longitudinal ridges, with respect to the sliding direction; the highest friction was observed on longitudinal ridges and grooves, which is in agreement with the tendency observed in our previous friction studies on steel surfaces. To further investigate this phenomenon, some additional patterns having different submicrometer morphologies were prepared and their friction characteristics were investigated. On the patterns not allowing the fluid to flow along the grooves, the frictional forces were equivalent for transverse and longitudinal grooves and ridges. Therefore, the high friction observed on the longitudinal ridges was caused by flowing out of fluid along the grooves, and it was possible to conclude that the fluidity around the submicrometer ridges and grooves influences the friction-reducing effect of stearic acid in boundary lubrication regime.


2017 ◽  
Vol 403 ◽  
pp. 472-486 ◽  
Author(s):  
Pourya Parsaeian ◽  
Ali Ghanbarzadeh ◽  
Marcel C.P. Van Eijk ◽  
Ileana Nedelcu ◽  
Anne Neville ◽  
...  

Author(s):  
Josef Fryza ◽  
Petr Sperka ◽  
Ivan Krupka ◽  
Martin Hartl

The interfaces of plastic components are often operated as self-lubricating or lubricated with greases close to the piezoviscous-elastic lubrication regime. However, current basic tribological knowledge about grease-lubricated compliant contacts is still very limited. This experimental study provides insight into relations between film thicknesses of grease and its base oil in compliant polymethylmethacrylate–steel and stiff glass–steel point contacts at different speeds and loads. The results are compared with predictions. The ratio between grease and its base oil film thickness was found to be significantly influenced by the interplay of load and the non-Newtonian response of grease, especially for the compliant contact, while the effect of speed and the slide-to-roll ratio was considerably lower. The role of viscoelasticity and grease thickener concentration is discussed.


Langmuir ◽  
2021 ◽  
Vol 37 (5) ◽  
pp. 1743-1759 ◽  
Author(s):  
Kimaya Vyavhare ◽  
Richard B. Timmons ◽  
Ali Erdemir ◽  
Brian L. Edwards ◽  
Pranesh B. Aswath

2012 ◽  
Vol 47 (3) ◽  
pp. 341-347 ◽  
Author(s):  
Caitlin Moore Strobel ◽  
Pradeep L. Menezes ◽  
Michael R. Lovell ◽  
Kurt E. Beschorner

Author(s):  
Fathima Banu Raza ◽  
Anand Kumar

The o-rings in ball retained overdentures deteriorate with time and need replacement to restore the retentive quality. We evaluated retrospectively the mechanical properties of o-rings after 3 years in function in one and two-piece implant-supported overdentures. The o-rings were retrieved from one-piece (Myriad snap, Equinox-Straumann, 3.3 x 13mm) and two-piece (Neo Biotech, 3.3 x 13mm) implant-supported overdenture patients. A total of 16 pairs of matrices were tested for wear, type of damage and elasticity using Pin on Disc method, USB Digital Camera in 30x zoom and Universal Tensile Machine respectively. The statistical analysis for independent groups were done with the Mann-Whitney U test. Assessment of used O-rings showed 84% more wear in the two-piece system with an abrasive type of damage while 46% wear in the one-piece system with a compressive type of damage. The o-rings in one-piece system showed increase in elongation and maximum displacement to 2% and 7% respectively, while two-piece system showed decrease in elongation and maximum displacement by 13% and 6% respectively. In one-piece system, the loss of retention was more with slow wear rate and in two-piece system, the wear resistance of O-rings decreased due to increased stiffness. Further studies to evaluate the changes in O-ring with increased sample size and at interval 1 year will pave way for insight into the progressive changes in the mechanical properties of an O-ring.


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