Morphology Development of Polymer Blend With Different Viscosity Ratios Along an Extruder

Author(s):  
Han-Xiong Huang ◽  
Xiao-Jing Li ◽  
You-Fa Huang

The properties of polymer blends are largely determined by their morphology. So it is significant to investigate the morphology development of polymer blends during processing. In this work the morphology development of polymer blend was studied during flow along a single screw extruder. The polymer blend used incorporated polypropylene (PP) as its matrix phase and a high-viscosity or low-viscosity polyamide-6 (PA6) as the disperse phase. The samples of blends were taken from different positions using specially designed sampling device along the extruder online during the processing and were then examined using scanning electron microscopy (SEM). The morphology of the dispersed phase was quantitatively analyzed using image analysis software. The morphology evolution of blends along the melt conveying zone of screw was simulated. Theoretically predicted morphology evolution is in reasonable agreement with the experimental results. The aim of this work is to provide a better insight in the morphology development of blend during processing.

2008 ◽  
Vol 587-588 ◽  
pp. 505-509 ◽  
Author(s):  
S.M. Cunha ◽  
António Gaspar-Cunha ◽  
José A. Covas

A prototype modular single screw extruder fitted with a screw extracting device is used to monitor melting of an immiscible polymer blend (PP/PA6, with different weight ratios) in this widely used processing equipment. As anticipated, the phenomena observed are much more complex than those involved in extruding PP or PA6, when the well known Maddock/Tadmor mechanism is valid. Consequently a hybrid melting mechanism, involving Maddock/Tadmor and Dispersive melting sequences, is proposed.


Author(s):  
Maria Andreevna PONOMAREVA ◽  
◽  
Maria Petrovna FILINA ◽  
Vladimir Albertovich YAKUTENOK ◽  
◽  
...  

2017 ◽  
Vol 885 ◽  
pp. 36-41 ◽  
Author(s):  
Károly Dobrovszky ◽  
Ferenc Ronkay

Blending polymers is an effective method to develop novel materials, tailoring the properties of the components. However, different morphology structures can be formed during the preparation, which could result in a wide diversity of mechanical and physical properties. The properties of polymer blends are most significantly influenced by the emerging range of phase inversion, which depends on the composition ratio and the viscosity ratio. In this paper various blends were prepared, utilizing polyethylene terephthalate (PET), polystyrene (PS) and two high density polyethylenes (HDPE), which differ in flowability. After preliminary homogenization by twin screw extruder, standard injection moulded specimen were prepared in order to present the effects of phase inversion on tensile properties, shrinkage and burning characteristics in binary polymer blends.


Materials ◽  
2019 ◽  
Vol 12 (12) ◽  
pp. 1971 ◽  
Author(s):  
Suwei Wang ◽  
Ping Xue ◽  
Mingyin Jia ◽  
Jing Tian ◽  
Run Zhang

The polypropylene (PP)/wood flour (WF) composites were prepared using a co-rotating twin-screw extruder followed by a single-screw extruder foaming system in this paper. Polymers, such as polyolefin elastomer (POE), high-density polyethylene (HDPE) or microcrystalline wax, were blended with PP in the preparation of composites to improve the melt strength. And a cavity transfer mixer was introduced to increase the distribution uniformity of components in composites. Meanwhile, the effect of the polymer blends on the microstructure and mechanical properties of samples was investigated. The experimental results show that the addition of POE and HDPE resulted in the second melting peak in the differential scanning calorimeter (DSC) curves and a great decrease in the cell size was caused by the added POE. However, due to the velocity difference of composites in the die, the shape of bubbles gradually became irregular. Moreover, the impact strength of samples significantly increased by 85% for the added POE and the apparent density decreased by 6.7%. And the minimum Vicat softening temperature of 133.7 °C was obtained when the mass ratio of HDPE to PP was 4/6.


2016 ◽  
Vol 56 (12) ◽  
pp. 1349-1356 ◽  
Author(s):  
Krzysztof J. Wilczyński ◽  
Adrian Lewandowski ◽  
Krzysztof Wilczyński

1999 ◽  
Vol 39 (5) ◽  
pp. 881-886 ◽  
Author(s):  
Xuedong Li ◽  
Mingcai Chen ◽  
Yuhui Huang ◽  
Guangmin Cong

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