scholarly journals Mixed Modes Fracture and Fatigue Evaluation for Lithium-Ion Batteries

Author(s):  
Michael A. Stamps ◽  
Hsiao-Ying Shadow Huang

Lithium ion batteries have become a widely known commodity for satisfying the world’s mobile energy storage needs. But these needs are becoming increasingly important, especially in the transportation industry, as concern for rising oil prices and environmental impact from fossil fuels are pushing for deployment of more electric vehicles (EV) or plug in hybrid-electric vehicles (PHEV) and renewable energy sources. The objective of this research is to obtain a fundamental understanding of degradation mechanisms and rate-capacity loss in lithium-ion batteries through fracture mechanics and fatigue analysis approaches. In this study we follow empirical observations that mechanical stresses accumulate on electrode materials during the cycling process. Crack induced fracturing will then follow in the material which electrical contact surface area is degraded and over capacitance of the battery reduces. A fatigue analysis simulation is applied using ANSYS finite element software coupled with analytical models to alleviate these parameters that play the most pivotal roles in affecting the rate-capacity and cycle life of the lithium-ion battery. Our results have potential to provide new models and simulation tools for clarifying the interplay of structure mechanics and electrochemistry while offering an increased understanding of fatigue degradation mechanisms in rechargeable battery materials. These models can aid manufacturers in the optimization of battery materials to ensure longer electrochemical cycling life with high-rate capacity for improved consumer electronics, electric vehicles, and many other military or space applications.

Author(s):  
Jie Li ◽  
Zhimin Li ◽  
Maolin Zhang ◽  
Yangxi Yan ◽  
Dongyan Zhang ◽  
...  

Improving the rate capacity of lithium-ion batteries is a continuous challenge to meet the demand in electric vehicles. Herein, NCM622 with biphasic features via Ga doping is obtained and is...


Author(s):  
Bhanu Sood ◽  
Lucas Severn ◽  
Michael Osterman ◽  
Michael Pecht ◽  
Anton Bougaev ◽  
...  

Abstract A review of the prevalent degradation mechanisms in Lithium ion batteries is presented. Degradation and eventual failure in lithium-ion batteries can occur for a variety of dfferent reasons. Degradation in storage occurs primarily due to the self-discharge mechanisms, and is accelerated during storage at elevated temperatures. The degradation and failure during use conditions is generally accelerated due to the transient power requirements, the high frequency of charge/discharge cycles and differences between the state-of-charge and the depth of discharge influence the degradation and failure process. A step-by-step methodology for conducting a failure analysis of Lithion batteries is presented. The failure analysis methodology is illustrated using a decision-tree approach, which enables the user to evaluate and select the most appropriate techniques based on the observed battery characteristics. The techniques start with non-destructive and non-intrusive steps and shift to those that are more destructive and analytical in nature as information about the battery state is gained through a set of measurements and experimental techniques.


2021 ◽  
Vol 13 (10) ◽  
pp. 5726
Author(s):  
Aleksandra Wewer ◽  
Pinar Bilge ◽  
Franz Dietrich

Electromobility is a new approach to the reduction of CO2 emissions and the deceleration of global warming. Its environmental impacts are often compared to traditional mobility solutions based on gasoline or diesel engines. The comparison pertains mostly to the single life cycle of a battery. The impact of multiple life cycles remains an important, and yet unanswered, question. The aim of this paper is to demonstrate advances of 2nd life applications for lithium ion batteries from electric vehicles based on their energy demand. Therefore, it highlights the limitations of a conventional life cycle analysis (LCA) and presents a supplementary method of analysis by providing the design and results of a meta study on the environmental impact of lithium ion batteries. The study focuses on energy demand, and investigates its total impact for different cases considering 2nd life applications such as (C1) material recycling, (C2) repurposing and (C3) reuse. Required reprocessing methods such as remanufacturing of batteries lie at the basis of these 2nd life applications. Batteries are used in their 2nd lives for stationary energy storage (C2, repurpose) and electric vehicles (C3, reuse). The study results confirm that both of these 2nd life applications require less energy than the recycling of batteries at the end of their first life and the production of new batteries. The paper concludes by identifying future research areas in order to generate precise forecasts for 2nd life applications and their industrial dissemination.


IEEE Access ◽  
2021 ◽  
Vol 9 ◽  
pp. 19175-19186
Author(s):  
Jiuchun Jiang ◽  
Xinwei Cong ◽  
Shuowei Li ◽  
Caiping Zhang ◽  
Weige Zhang ◽  
...  

Metals ◽  
2021 ◽  
Vol 11 (7) ◽  
pp. 1091
Author(s):  
Eva Gerold ◽  
Stefan Luidold ◽  
Helmut Antrekowitsch

The consumption of lithium has increased dramatically in recent years. This can be primarily attributed to its use in lithium-ion batteries for the operation of hybrid and electric vehicles. Due to its specific properties, lithium will also continue to be an indispensable key component for rechargeable batteries in the next decades. An average lithium-ion battery contains 5–7% of lithium. These values indicate that used rechargeable batteries are a high-quality raw material for lithium recovery. Currently, the feasibility and reasonability of the hydrometallurgical recycling of lithium from spent lithium-ion batteries is still a field of research. This work is intended to compare the classic method of the precipitation of lithium from synthetic and real pregnant leaching liquors gained from spent lithium-ion batteries with sodium carbonate (state of the art) with alternative precipitation agents such as sodium phosphate and potassium phosphate. Furthermore, the correlation of the obtained product to the used type of phosphate is comprised. In addition, the influence of the process temperature (room temperature to boiling point), as well as the stoichiometric factor of the precipitant, is investigated in order to finally enable a statement about an efficient process, its parameter and the main dependencies.


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