Self-Aligned Carbon Nanotube Yarns for Multifunctional Optoelectronic Applications
In this work, the morphology and electrocatalytic features of carbon nanotube yarns at the structural level allow for enhanced photoconversion efficiency. The energy conversion of electron-hole pairs within the carbon nanotube yarn (CNY) due to the functionalization with nanostructured photoactive TiO2 phases is remarkable. A well oriented anatase TiO2 thin layer (approximately 100 nm) forms at the interfaces of CNY and TiO2 mesoporous film when the sample is precoated and annealed at 350°C. Field Emission Scanning Electron Microscopy (FESEM) images show the integrity and homogeneity of the TiO2 surface, which is indicative of the overall durability of the CNY-based dye sensitized solar cell (DSSC); Coating TiO2 on self-aligned carbon nanotube yarns provides several benefits from their high chemical stability, excellent functionality, nontoxicity and relatively low cost. The maximum photon to current conversion efficiency (ηAM1.5) achieved was 3.1%.