Effect of Mechanical Cycling at Elevated Temperatures on The Constitutive Properties and Microstructure of Lead Free Solder Alloys

2021 ◽  
Author(s):  
Mohd Aminul Hoque ◽  
Mohammad Ashraful Haq ◽  
Jeffrey C. Suhling ◽  
Pradeep Lall

Abstract Solder joints in electronic packages often experience fatigue failures due to cyclic mechanical stresses and strains in fluctuating temperature environments. These stresses and strains are induced by mismatches in coefficients of thermal expansion, and lead to damage accumulation that contributes to crack initiation, crack propagation, and eventually to failure. In this study, we have tried to compare the effects of elevated mechanical cycling on SAC305 and SAC+Bi (SAC_Q). Initially, small uniaxial cylindrical samples of both alloys were prepared and reflowed in a reflow oven. These samples were then mechanically cycled for various durations at testing temperatures of 100 °C. The measured cyclic stress-strain curves were used to characterize the evolution of the hysteresis loop properties (peak stress, hysteresis loop area, and plastic strain range) with high temperature mechanical cycling. In addition, uniaxial tensile tests and creep tests were also conducted on specimens that had been previously mechanically cycled for various durations (e.g 0, 50, 100, 200, and 300 cycles) at an elevated temperature. This allowed us to study the evolution of the constitutive behavior of the solder alloys that occurred during the high temperature mechanical cycling due to the fatigue damage that builds up in the specimens. The reductions in the properties that occur during high temperature mechanical cycling were also correlated with the corresponding changes in the microstructure of the specimens. Rectangular cross-sectioned samples of the two lead free solder alloys were polished and selected regions indented to track the changes in the microstructure of a fixed region with mechanical cycling at T = 100 °C. Using the results of this study, we are working to develop better fatigue criteria for lead free solders which are subjected to variable temperature applications.

Author(s):  
Pradeep Lall ◽  
Vikas Yadav ◽  
Jeff Suhling ◽  
David Locker

Abstract Electronic components in downhole oil drilling and gas industry applications, automotive and avionics may exposed to high temperatures (> 150°C) and high strain rates (1–100 per sec) during storage, operation and handling which can contribute to the failures of electronics devices. Temperatures in these applications can exceed 200°C, which is closed to melting point for SAC alloys. The microstructure for lead free solder alloys constantly evolves when subjected to thermal aging for sustained periods with accompanying degradation in mechanical properties of solder alloys. In this paper, evolution of microstructure and Anand parameters for unaged and aged SAC (SAC105 and SAC-Q) lead free solder alloys at high strain rates has been investigated induced due to thermal aging. The microstructure of the SAC solder is studied using scanning electron microscopy (SEM) for different strain rate and elevating temperature. The thermal aged leadfree SAC solder alloys specimen has been tested at high strain rates (10–75 per sec) at elevated temperatures of (25°C–200°C). The SAC leadfree solder samples were subjected to isothermal aging at 50°C up to 1-year before testing. To describe the material constitutive behavior, Anand Viscoplastic model has been used. Effect of thermal aging on Anand parameters has been investigated. In order to verify the accuracy of the model, the computed Anand parameters have been used to simulate the uniaxial tensile test. FEA based method has been used to simulate the drop events using Anand constitutive model. Hysteresis loop and Plastic work density has been computed from FEA.


2012 ◽  
Vol 626 ◽  
pp. 200-204 ◽  
Author(s):  
Kazuhiro Nogita ◽  
Hideyuki Yasuda ◽  
Stuart D. McDonald ◽  
Kentaro Uesugi

This paper demonstrates how recent progress for real-time solidification observation at SPring-8 synchrotron has contributed to the development of Sn-7wt%Cu-0.05wt%Ni high temperature lead-free solder alloys. Lead-free solder alloys in the composition range Sn-0.7 to 7.6wt%Cu that consist of primary Cu6Sn5in a eutectic Sn-Cu6Sn5matrix have been proposed as solders for application at temperatures up to 400°C for the assembly high current semiconductors. It is shown that trace levels of Al have a marked effect on the solder microstructure and refine the size of the primary Cu6Sn5. The solidification pathway that leads to the refinement was observed in real-time using X-ray synchrotron observations.


2012 ◽  
Vol 476-478 ◽  
pp. 1163-1168 ◽  
Author(s):  
M.Z. Shahrul Fadzli ◽  
M.A. Azmah Hanim ◽  
T. Sai Hong ◽  
A. Aidy ◽  
R. Rohaizuan

The development works on high temperature lead free solder are mostly discussed nowadays. To replace the current high temperature lead free solders, further research need to be done. A great deal of effort has been put into the development of lead free solder alloys. Bi (Bismuth) and Sb (Antimony) solder system proved as one of the promising candidates for electronic assembly. Melting temperature of three Bi-Sb solder alloys studied in this research enhanced their potential as the alternative solder candidates for high temperature lead free solder. At interface, Cu3Sb IMC layer was formed for 95Bi-5Sb solder alloy. Spallation of Cu3Sb IMC layer took placed with the results of Cu3Sb IMC also found in the solder bulk. Analysis of 97.5Bi-2.5Sb solder alloy classified as no metallurgical reaction at the interface and only the mechanical joining existed at the interface. The dissolution of Cu from subtrate affected the formation of Cu rich phase and the unstable Bi-Cu rich phase phenomena act as the isothermal product found in solder bulk. Mechanical grain boundary grooving observed in 98.5Bi-1.5Sb solder alloys at interface. Different compositions of Bi-Sb solder alloys resulted in different types of microstructures at interface and in solder bulk after reflow.


2011 ◽  
Vol 337 ◽  
pp. 402-405
Author(s):  
Kuai Le Zhao ◽  
Yan Fu Yan ◽  
Yang Yang Sheng ◽  
Ning Du ◽  
Zhan Lei Liu

Zn20Sn solder with the melting point of 383.9°C and a low cost is considered as an ideal high-temperature lead-free solder. In the paper a new solder alloys were made by adding trace Cu into Zn20Sn alloy through alloying principle. Interfacial reaction and solderability of Zn20SnxCu (x=0 wt.%, 2 wt.%, 4 wt.% and 6 wt.%) solder on the copper substrate were investigated. Results showed that β’-CuZn, γ-Cu5Zn8 and ε-CuZn5 IMC layers were formed at the interface of Zn20SnxCu/Cu. The spreading areas of the Zn20SnxCu solders were reduced linearly with the increasing of the content of copper. The spreading aera of Zn20Sn solder was 52.88 mm2 while that of Zn20Sn6Cu was 50.82mm2 which was approximately 3.9% smaller than that of matrix solder. It is mainly related to the formation of ε-CuZn5 phase and the metal intermetallic compound between the solder and the substrate.


Author(s):  
Qian Zhang ◽  
Abhijit Dasgupta ◽  
Peter Haswell

The isothermal mechanical durability properties of two lead-free solder alloys, Sn3.5Ag and Sn3.9Ag0.6Cu, are presented and compared to that of the baseline eutectic Sn37Pb solder. Cyclic mechanical tests are performed at room temperature at various strain-rates and load levels, using a thermo-mechanical-microstructural (TMM) test system developed by the authors. The data is analyzed using standard power-law durability models based on work and inelastic strain range. The Sn3.9Ag0.6Cu lead-free alloy is found to be most durable, followed by the Sn3.5Ag solder and finally the baseline Sn37Pb eutectic alloy, under the test conditions investigated. However, tests at high load levels show a greater difference in durability than tests at low load levels. This trend is the opposite of that reported in the literature for thermal cycling durability. A hypothesis is put forward to explain the observed differences between mechanical cycling and thermal cycling, based on the energy-partitioning damage model.


2018 ◽  
Vol 28 (4) ◽  
pp. 1-5 ◽  
Author(s):  
Marian Drienovsky ◽  
Eva Michalcova ◽  
Marcela Pekarcikova ◽  
Marian Palcut ◽  
Lubomir Frolek ◽  
...  

Author(s):  
Balint Medgyes ◽  
Sandor Adam ◽  
Lajos Tar ◽  
Vadimas Verdingovas ◽  
Rajan Ambat ◽  
...  

2016 ◽  
Vol 5 (4) ◽  
pp. 266-274
Author(s):  
Takeharu HAYASHI ◽  
Hirohiko WATANABE ◽  
Masaaki TAKABE ◽  
Yoshinori EBIHARA ◽  
Tatsuhiko ASAI ◽  
...  

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