The 2D Spring Splines Procedure Application With Prescribed Accuracy for Determination of the Global (Pipe Centerline) as Well as the Local (Dent) Curvatures

Author(s):  
I. V. Orynyak ◽  
A. V. Bohdan ◽  
I. V. Lokhman

The problem of smoothing the spatial line based on position measurements of discrete points exists in cases where a) the positions of points are determined with some errors, b) the goal of smoothing is not a continuous position itself but the higher derivatives of it. It is a very common problem in many engineering applications. With respect to the pipeline industry this problem is very prominent at least in two cases but regretfully many researchers do not pay due attention to it at all. First, the Geopigs are widely used for the determination of spatial position of the pipe centerline points. This information inter alia may be (and in fact are widely) used for the calculation of the global centerline curvatures which are proportional to the global bending strains. Second, the maximum strain levels of the dents are calculated based on the local geometry of the dent as determined by radial sensor measurements from the in line inspection survey. Note, that in both cases mathematically the curvatures are the second derivatives of the function of global (pipeline) or local (dent) positions. The input information about the global X–Y–Z position of each consecutive point of axis line as well as the local radial position of the dent points are given with some error. This leads to a huge noise in predicted curvatures which can overrun the useful information. The amplitude of errors of calculation is inversely proportional to the squared distance between the points of measurement. The application of any smoothing procedure may lead to the loss of the useful information about real curvatures. Thus tradeoff between the smoothing of the noise and the loss of accuracy presents a big problem in the pipeline industry. Two quantitative parameters are introduced here to allow performing such a tradeoff. First parameter characterizes the standard deviation (also referred to as standard in the following) of the random value of the position measurement accuracy by the devices, ρ. Second parameter is the requested accuracy of the curvature determination and is defined in terms of the standard deviation of the bending stress, σ or strain, ε. The spatial beam on elastic foundation model is used to fit the measured point positions to the spatial curve. Its main characteristic is the specific compliance of the foundation α which is determined based on two above root-mean-square errors ρ and σ. The corresponding formulas and tables based on the solution for the elastic beam are obtained. The bigger the allowed error in bending stress σ the lesser is required compliance of the foundation, α. In turn this leads to the smaller value of characteristic wave length of solution and the possibility to retain more useful information about the actual short length stresses in the pipeline. Some practical examples of applications of the procedure are given.

Author(s):  
P.F. Collins ◽  
W.W. Lawrence ◽  
J.F. Williams

AbstractA procedure for the automated determination of ammonia in tobacco has been developed. Ammonia is extracted from the ground tobacco sample with water and is determined with a Technicon Auto Analyser system which employs separation of the ammonia through volatilization followed by colourimetry using the phenate-hypochlorite reaction. The procedure has been applied to a variety of tobaccos containing from 0.02 to 0.5 % ammonia with an overall relative standard deviation of 2 %. The accuracy of the procedure as judged by recovery tests and by comparison to a manual distillation method is considered adequate


1983 ◽  
Vol 48 (1) ◽  
pp. 52-59 ◽  
Author(s):  
Vlastimil Kubáň ◽  
Miroslav Macka

The composition, optical characteristics, molar absorption coefficients and equilibrium constants of the reactions of formation of the ML and ML2 complexes of both reagents with cadmium(II) ions were determined by graphical analysis and numerical interpretation of the absorbance-pH curves by the modified SQUAD-G program. Optimal conditions were proposed for the spectrophotometric determination of Cd in 10% v/v ethanol medium in the presence of 0.1% w/v Triton X-100 or 1% w/v Brij 35. BrPADAP and ClPADAP are the most sensitive spectrophotometric reagents for the determination of cadmium(II) ions (ε = 1.28-1.44 . 105 mmol-1 cm2 at 560 nm and pH 8.0-9.5) with a high colour contrast in the reaction (Δλmax ~117 nm) and a selectivity similar to that of other N-heterocyclic azodyes (PAR, PAN, etc.).


1982 ◽  
Vol 47 (10) ◽  
pp. 2676-2691 ◽  
Author(s):  
Miroslav Macka ◽  
Vlastimil Kubáň

The optical and acid-base characteristics of BrPADAP and ClPADAP were studied in mixed water-ethanol and water-DMF media and in 10% ethanol medium in the presence of cationic, anionic and nonionic tensides. The composition, optical characteristics, molar absorption coefficients and equilibrium constants of the ML and ML2 complexes with zinc(II) ions were found by graphical analysis and numerical interpretation of the absorbance curves by the modified SQUAD-G program. Optimal conditions were found for the spectrophotometric determination of Zn(II) in the presence of 0.1% Triton X-100 or 1% Brij 35 in alkaline media with pH = 6.5-10. BrPADAP and ClPADAP are the most sensitive reagents (ε = 1.3-1.6 . 105 mmol-1 cm2 at 557 and 560 nm, respectively) for the determination of zinc with high colour contrast of the reaction (Δλ = 104 nm) and selectivity similar to that for the other N-heterocyclic azodyes (PAN, PAR, etc.).


1982 ◽  
Vol 47 (7) ◽  
pp. 1973-1978 ◽  
Author(s):  
Jiří Karhan ◽  
Zbyněk Ksandr ◽  
Jiřina Vlková ◽  
Věra Špatná

The determination of alcohols by 19F NMR spectroscopy making use of their reaction with hexafluoroacetone giving rise to hemiacetals was studied on butanols. The calibration curve method and the internal standard method were used and the results were mutually compared. The effects of some experimental conditions, viz. the sample preparation procedure, concentration, spectrometer setting, and electronic integration, were investigated; the conditions, particularly the concentrations, proved to have a statistically significant effect on the results of determination. For the internal standard method, the standard deviation was 0.061 in the concentration region 0.032-0.74 mol l-1. The method was applied to a determination of alcohols in the distillation residue from an oxo synthesis.


2021 ◽  
Vol 73 (1) ◽  
Author(s):  
Rüdiger Haas ◽  
Eskil Varenius ◽  
Saho Matsumoto ◽  
Matthias Schartner

AbstractWe present first results for the determination of UT1-UTC using the VLBI Global Observing System (VGOS). During December 2019 through February 2020, a series of 1 h long observing sessions were performed using the VGOS stations at Ishioka in Japan and the Onsala twin telescopes in Sweden. These VGOS-B sessions were observed simultaneously to standard legacy S/X-band Intensive sessions. The VGOS-B data were correlated, post-correlation processed, and analysed at the Onsala Space Observatory. The derived UT1-UTC results were compared to corresponding results from standard legacy S/X-band Intensive sessions (INT1/INT2), as well as to the final values of the International Earth Rotation and Reference Frame Service (IERS), provided in IERS Bulletin B. The VGOS-B series achieves 3–4 times lower formal uncertainties for the UT1-UTC results than standard legacy S/X-band INT series. The RMS agreement w.r.t. to IERS Bulletin B is slightly better for the VGOS-B results than for the simultaneously observed legacy S/X-band INT1 results, and the VGOS-B results have a small bias only with the smallest remaining standard deviation.


1998 ◽  
Vol 81 (4) ◽  
pp. 763-774 ◽  
Author(s):  
Joanna M Lynch ◽  
David M Barbano ◽  
J Richard Fleming

Abstract The classic method for determination of milk casein is based on precipitation of casein at pH 4.6. Precipitated milk casein is removed by filtration and the nitrogen content of either the precipitate (direct casein method) or filtrate (noncasein nitrogen; NCN) is determined by Kjeldahl analysis. For the indirect casein method, milk total nitrogen (TN; Method 991.20) is also determined and casein is calculated as TN minus NCN. Ten laboratories tested 9 pairs of blind duplicate raw milk materials with a casein range of 2.42- 3.05℅ by both the direct and indirect casein methods. Statistical performance expressed in protein equivalents (nitrogen ⨯ 6.38) with invalid and outlier data removed was as follows: NCN method (wt%), mean = 0.762, sr = 0.010, SR = 0.016, repeatability relative standard deviation (RSDr) = 1.287℅, reproducibility relative standard deviation (RSDR) = 2.146%; indirect casein method (wt℅), mean = 2.585, repeatability = 0.015, reproducibility = 0.022, RSDr = 0.560℅, RSDR = 0.841; direct casein method (wt℅), mean = 2.575, sr = 0.015, sR = 0.025, RSDr = 0.597℅, RSDR = 0.988℅. Method performance was acceptable and comparable to similar Kjeldahl methods for determining nitrogen content of milk (Methods 991.20, 991.21,991.22, 991.23). The direct casein, indirect casein, and noncasein nitrogen methods have been adopted by AOAC INTERNATIONAL.


1972 ◽  
Vol 9 (1) ◽  
pp. 36-42 ◽  
Author(s):  
Calvert C. Bristol

X-ray powder diffraction methods, successful in quantitative determination of silicate minerals in fine-grained rocks, have been applied to the determination of calcite, dolomite, and magnesite in greenschist facies meta-volcanic rocks. Internal standard graphs employing two standards (NaCl and Mo) have been determined.Carbonate mineral modes (calcite and dolomite) for 6 greenschist facies meta-volcanic rocks obtained by the X-ray powder method have been compared to normative carbonate mineral contents calculated for the same rocks. This comparison showed a maximum variation of 7.7 wt.% between the X-ray modes and the normative carbonate mineral contents of the rocks. Maximum standard deviation for the X-ray modes of these rocks was equivalent to 4.4 wt.%.


2011 ◽  
Vol 4 (3) ◽  
pp. 259-263 ◽  
Author(s):  
Yousry M. Issa ◽  
Sayed I.M. Zayed ◽  
Ibrahim H.I. Habib

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