The objective of this paper is to show that explosives may potentially be detected by passive standoff FTIR radiometry. It is demonstrated that many explosives exhibit a signature (fingerprint) in the longwave infrared (LWIR) region (i.e., 8 – 14 μm). Simulations using the radiative transfer model, MODTRAN4, clearly suggest that such materials can be identified when a thermal contrast exists between the material and its environment. The explosives considered in this study include octogen (HMX), trinitrotoluene (TNT), cyclonite (RDX), and the plastic explosives, C-4 and Detasheet-C. In addition, passive FTIR measurements of HMX have been performed in the field at standoff distances up to 60 m. The development of a passive standoff detection capability based on FTIR radiometry may be a potentially useful addition to the arsenal of measurement techniques that currently exist for the detection and identification of explosive threats.