Solubility Equations of Boron Compounds under Coolant Conditions in VVER-Type Reactor Plants

2021 ◽  
Vol 68 (10) ◽  
pp. 743-751
Author(s):  
N. L. Kharitonova ◽  
Sh. A. Gurbanova
Keyword(s):  
Boron Compounds ◽  
Type Reactor

Catalytic Fluorination of Boron Compounds at a Bismuth Redox Platform

2019 ◽  
Author(s):  
Oriol Planas ◽  
Feng Wang ◽  
Markus Leutzsch ◽  
Josep Cornella
Keyword(s):  
Transition Metal ◽  
Main Group ◽  
Group Element ◽  
Oxidation States ◽  
Boron Compounds ◽  
Main Text ◽  
Main Group Element ◽  
Rational Ligand Design ◽  
Supplementary Material

The ability of bismuth to maneuver between different oxidation states in a catalytic redox cycle, mimicking the canonical organometallic steps associated to a transition metal, is an elusive and unprecedented approach in the field of homogeneous catalysis. Herein we present a catalytic protocol based on bismuth, a benign and sustainable main-group element, capable of performing every organometallic step in the context of oxidative fluorination of boron compounds; a territory reserved to transition metals. A rational ligand design featuring hypervalent coordination together with a mechanistic understanding of the fundamental steps, permitted a catalytic fluorination protocol based on a Bi(III)/Bi(V) redox couple, which represents a unique example where a main-group element is capable of outperforming its transition metal counterparts.<br>A main text and supplementary material have been attached as pdf files containing all the methodology, techniques and characterization of the compounds reported.<br>

Effect of draft tube diameter on nitrogen removal from domestic sewage in a draft tube type reactor

1998 ◽  
Vol 38 (1) ◽  
pp. 319-326
Author(s):  
Taku Fujiwara ◽  
Iso Somiya ◽  
Hiroshi Tsuno ◽  
Yoshio Okuno
Keyword(s):  
Flow Rate ◽  
Nitrogen Removal ◽  
Draft Tube ◽  
Domestic Sewage ◽  
Tube Diameter ◽  
Continuous Treatment ◽  
Anoxic Zone ◽  
Type Reactor ◽  
Tube Type ◽  
Volumetric Loading

The effect of the ratio of draft tube diameter to reactor diameter (Di/Do) on the efficiency of nitrogen removal from domestic sewage is discussed based on liquid-circulating flow rate and continuous treatment data. More than 2.5 minutes of circulation time in the annulus part, which is required to create an anoxic zone, could be maintained under operating conditions in which air flow rate per reactor volume was 2 m3/(m3 · hr) and Di/Do was 0.19. When Di/Do was set at 0.19, the average total organic carbon (TOC), total nitrogen (TN) and dissolved nitrogen (DN) removal efficiencies were 83.2%, 72.1% and 71.6%, respectively, which were higher than those when Di/Do was at 0.26 or 0.36. From these results, it is concluded that 0.19 is the best Di/Do for nitrogen removal in a draft-tube type reactor with an effective depth of 4.0m under the treatment condition in which the BOD volumetric loading rate is in the range 0.22 to 0.46 kgBOD/(m3 · day). More than 80% nitrification and denitrification efficiencies can be achieved simultaneously when both conditions, the aerobic zone ratio being more than 0.2, and the anoxic zone ratio being more than 0.3, are satisfied.

Investigation of irradiated metal of WWER-type reactor internals after 45 years of operation. Part 1. Research program and cutting out of samples from pressure vessel internals

2020 ◽  
pp. 135-143
Author(s):  
B. Z. Margolin ◽  
A. Ya. Varovin ◽  
A. J. Minkin ◽  
D. A. Gurin ◽  
V. A. Glukhov
Keyword(s):  
Research Program ◽  
Pressure Vessel ◽  
The Core ◽  
Type Reactor ◽  
Cutting Out ◽  
Cylindrical Samples ◽  
Reactor Internals

The program is presented for investigations of the metal of the most irradiated elements of the WWER-440 reactor of the Novovoronezh NPP Unit 3 decommissioned after 45 years of operation. The fragments (cylindrical samples) were cut out from various zones of the core baffle and segment of forming ring of core barrel.

scholarly journals Synthesis and Characterisation of a Boron-Rich Symmetric Triazine Bearing a Hypoxia-Targeting Nitroimidazole Moiety

Symmetry ◽  
2021 ◽  
Vol 13 (2) ◽  
pp. 202
Author(s):  
Tobias Hartwig Bünning ◽  
Luigi Panza ◽  
Abdel Kareem Azab ◽  
Barbara Muz ◽  
Silvia Fallarini ◽  
...  
Keyword(s):  
Tumor Tissue ◽  
High Ratio ◽  
Neutron Capture Therapy ◽  
Boron Compounds ◽  
The Core ◽  
Boron Neutron Capture ◽  
Starting Point ◽  
Primary Fibroblasts ◽  
Normal Human ◽  
Hypoxia Markers

Boron Neutron Capture Therapy (BNCT) is a binary therapy that promises to be suitable in treating many non-curable cancers. To that, the discovery of new boron compounds able to accumulate selectively in the tumour tissue is still required. Hypoxia, a deficiency of oxygen in tumor tissue, is a great challenge in the conventional treatment of cancer, because hypoxic areas are resistant to conventional anticancer treatments. 2-Nitroimidazole derivatives are known to be hypoxia markers due to their enrichment by bioreduction in hypoxic cells. In the present work, 2-nitroimidazole was chosen as the starting point for the synthesis of a new boron-containing compound based on a 1,3,5-triazine skeleton. Two o-carborane moieties were inserted to achieve a high ratio of boron on the molecular weight, exploiting a short PEG spacer to enhance the polarity of the compound and outdistance the active part from the core. The compound showed no toxicity on normal human primary fibroblasts, while it showed noteworthy toxicity in multiple myeloma cells together with a consistent intracellular boron accumulation.

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