Determination of individual sulfur-containing compounds in liquid hydrocarbon raw materials and their processing products by gas chromatography

2017 ◽  
Vol 72 (5) ◽  
pp. 473-489 ◽  
Author(s):  
S. A. Arystanbekova ◽  
M. S. Lapina ◽  
A. B. Volynskii
2017 ◽  
Vol 72 (10) ◽  
pp. 1095-1101 ◽  
Author(s):  
I. P. Afanas’ev ◽  
T. A. Gorshkova ◽  
S. A. Arystanbekova ◽  
M. S. Lapina ◽  
A. B. Volynskii

2012 ◽  
Vol 67 (7) ◽  
pp. 669-676 ◽  
Author(s):  
S. A. Arystanbekova ◽  
M. S. Lapina ◽  
A. B. Volynskii ◽  
V. S. Ustyugov ◽  
A. I. Almametov

Author(s):  
K. Сhevchenko ◽  
A. Grigorov ◽  
I. Sinkevich

The article proposes to determine the corrosion effect on fuel metals under dynamic conditions, when washing the prepared copper plate of a certain size, a significant amount of fuel at a certain speed and temperature of the study. This approach will significantly reduce the duration of the study (up to 100 minutes) and is closer to the real conditions of contact of the fuel with a metal surface, in comparison with the standardized method, which is widely used today. Using the proposed laboratory setup, the study was subjected to fuel (200–360 °C), which was obtained by thermal destruction of secondary polymer raw materials, in particular polypropylene. The obtained results showed that the investigated fuel, despite the temperature, the amount of circulating fuel and its water content, does not have a corrosive effect on the copper plate, which can be explained by the absence of corrosive substances in the fuel: water-soluble mineral acids and alkalis, active sulfur compounds and organic acids. However, it should be kept in mind that in polyolefin raw materials, in the form of contamination, there may be products made of other materials, such as rubber and polyvinyl chloride. This can happen when the sorting technology is violated or during the preliminary preparation of raw materials and, in turn, will contribute to the increase in sulfur-containing and chlorine-containing compounds in the fuel, which are characterized by high corrosion activity and should be necessarily removed from the fuel. Note that the fuel obtained from secondary polymer raw materials, in the absence of sulfur-containing and chlorine-containing compounds, is quite promising for the creation on its basis of modern synthetic fuels, analogues of classic petroleum products.


Author(s):  
Dahryn A. Augustine ◽  
Grace-Anne Bent

Acrylamide, a known neurotoxin, reproductive toxin, genotoxin, probable carcinogen, hepatotoxin, and immunotoxin, has sparked intense curiosity due to its prominent presence in thermally processed, carbohydrate-rich foods. Acrylamide formation occurs via the Maillard reaction at temperatures ≥100ºC. Thorough investigations on acrylamide mitigation through the application of sulfur-containing compounds to raw materials, and during food processing have been conducted. Although prominent results in acrylamide reduction have been observed, limitations are considered. These limitations involve the social and economic challenges of a population, such as the Caribbean. This study seeks to answer just how effective the application of sulfur-containing compounds is in reducing acrylamide exposure, especially when this applies to a developing region.


2020 ◽  
Vol 12 (8) ◽  
pp. 1094-1106 ◽  
Author(s):  
Siyabonga Shoba ◽  
Owolabi M. Bankole ◽  
Adeniyi S. Ogunlaja

Prepared GCE/PAni/Ag characterized via spectroscopic techniques (UV-Vis, XRD, XPS) and microscopic techniques (TEM and SEM), was employed for the quantification of benzothiophene, dibenzothiophene and 4,6-dimethyldibenzothiophene in model fuel.


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