Kinetics of decomposition of the liquid phase of the ternary system LiOH-H2O2-H2O in the presence of the solid phase of Li2O2 · H2O

2008 ◽  
Vol 81 (1) ◽  
pp. 26-29 ◽  
Author(s):  
Yu. A. Ferapontov ◽  
M. A. Ul’yanova ◽  
T. V. Sazhneva ◽  
N. P. Kozlova
2000 ◽  
Vol 2000 ◽  
pp. 144-144
Author(s):  
A.J. Ayala-Burgos ◽  
F.D.DeB. Hovell ◽  
R.M. Godoy ◽  
Hamana S. Saidén ◽  
R. López ◽  
...  

Cattle in the tropics mostly depend on pastures. During dry periods the forage available is usually mature, constraining both intake and digestion. These constraints need to be understood, for intake and digestibility define productivity. Intake depends on the rumen space made available by fermentation and outflow. Markers such as PEG (liquid phase), and chromium mordanted fibre (solid phase) can be used to measure rumen volume and outflow, but have limitations. The objective of this experiment was to measure intake, digestibility, and rumen kinetics of cattle fed ad libitum forages with very different degradation characteristics, and also to compare rumen volumes measured with markers with those obtained by manual emptying.


2007 ◽  
Vol 280-283 ◽  
pp. 1403-1408 ◽  
Author(s):  
Ren Li Fu ◽  
He Ping Zhou ◽  
Ke Xin Chen ◽  
José Maria F. Ferreira

AlN whiskers have been successfully synthesized by carbothermal reduction. The thermodynamics and growth kinetics of AlN whiskers were studied at 1600°C using CaCO3 as a catalyst. The research indicated that AlN whiskers are more easily nucleated from the liquid phase than at the surface of solid phase. AlN whiskers are nucleated by VLS mechanism and the liquid, which plays a dominant role in the VLS mechanism, is formed by Al-Ca interphases, such as CaO×2Al2O3 and CaO×6Al2O3. Kinetic studies suggest that the catalyst reacts with Al2O3 to form a low melting point eutectic (1390°C). The liquid phase formed at this low melting point eutectic provides good conditions for nucleation of AlN whiskers. At the synthesis temperature, the liquid phase vaporizes, thus creating suitable conditions for the subsequent growing of whiskers by the VLS mechanism. This growing mechanism conforms to thermodynamics and a lot of proof indicates that screw dislocations play an important role in the process of the whiskers' formation.


1995 ◽  
Vol 10 (4) ◽  
pp. 200-205 ◽  
Author(s):  
A. Murray ◽  
J. F. R. Robertson ◽  
M. R. Price

The aim of this study was to investigate whether immunoassays for circulating MUC1 antigen in breast cancer could be compressed in time so that serum level results would be made available during the time of the patient's visit to clinic. Two assays were used: - The EMCA (Euro DPC) is a liquid phase immunoassay and the ELSA CA15-3 (CIS) is a double determinant solid phase immunoradiometric assay. The effects of shortened incubation times were investigated by assaying standards and unknown samples and comparing the results with those using the standard kit protocols. The binding kinetics of the monoclonal antibodies employed in the assays were analysed separately. We conclude that the EMCA assay can be shortened to 35 min and we have attributed this to the fast binding kinetics inherent in a liquid phase assay. This shortened assay may produce the basis for a useful “near patient” assay. By comparison, the solid phase ELSA CA15-3 assay cannot be compressed without loss in assay performance.


2011 ◽  
Vol 689 ◽  
pp. 355-360
Author(s):  
Qiu Guo Xiao ◽  
Gang Cheng Ding ◽  
Tang Zhong Long ◽  
Shao Hua Shen

This paper has put forward a high-temperature quantitative X-ray powder diffraction analysis method for the determination of an isothermal section of a ternary system in comparison with a conventional method. In a three-phase region of the isothermal section at 1150 °C of Cu2O(CuO)-Al2O3-SiO2 pseudo-ternary system, the compositions of the solid phase points of three system points are determined according to the quantitative analysis of the crystalline phases in the samples carried out by Rietveld method. Then the liquid phase point of the three-phase region is determined according to the crosspoints of the tie lines of every pair of system point and solid phase point. The precisions of the analytical results have reached to be 0.1 ~ 5.0 %. By comparison, a good result is obtained for the determination of the liquid phase point of the three-phase region in the isothermal section at 1150 °C when the analytical results of high-temperature RQA analysis are used in determination of the isothermal section of the pseudo-ternary system.


2014 ◽  
Vol 38 (5) ◽  
pp. 506-514 ◽  
Author(s):  
Vinicius Pimentel Silva ◽  
Fernando Queiroz de Almeida ◽  
Róbson Ricardo Moreira Pimentel ◽  
Fernanda Nascimento de Godoi ◽  
Tiago Marques dos Santos ◽  
...  

This study was conducted to evaluate the kinetics, physicochemical characteristics and particle size of digesta in the right ventral colon (RVC) of horses fed coastcross hay ground to different degrees. Four horses fitted with cannulae in the RVC were used and were fed the following forms of hay: long, chopped, ground to 5 mm and ground to 3 mm. A Latin Square 4x4 study design was used. Each experimental period included 10 days for diet adaptation, four days for feces collection and one day for digesta collection. The kinetics of the particulate and solute phases of digesta were evaluated based on the mean retention time (MRT), passage rate (k) and transit time (TT) using two external markers: Cr-NDF and Co-EDTA. The TT of solid phase digesta was 3 hours longer (P<0.05) for ground hay than with the other physical forms of hay. There was no difference (P>0.05) in k or MRT in either the liquid or solid phase of digesta as a function of the different degrees of hay grinding. However, the liquid phase of digesta presented a higher k than the solid phase, with values of 3.28 and 2.73 h-1 being obtained, respectively. The smallest particle size and the lowest neutral detergent fiber contents in colon digesta were observed when hay ground to 3 mm was offered, leading to values of 0.51 mm and 53.46%, respectively. Grinding the hay increased the transit time of the liquid phase in the digestive tract of the horses, whereas no change in the kinetics of the solid phase digesta was observed. The grinding of hay reduced the NDF and the average particle size in the right ventral colon.


Author(s):  
C.D. Humphrey ◽  
T.L. Cromeans ◽  
E.H. Cook ◽  
D.W. Bradley

There is a variety of methods available for the rapid detection and identification of viruses by electron microscopy as described in several reviews. The predominant techniques are classified as direct electron microscopy (DEM), immune electron microscopy (IEM), liquid phase immune electron microscopy (LPIEM) and solid phase immune electron microscopy (SPIEM). Each technique has inherent strengths and weaknesses. However, in recent years, the most progress for identifying viruses has been realized by the utilization of SPIEM.


Author(s):  
N. A. Bulychev

In this paper, the plasma discharge in a high-pressure fluid stream in order to produce gaseous hydrogen was studied. Methods and equipment have been developed for the excitation of a plasma discharge in a stream of liquid medium. The fluid flow under excessive pressure is directed to a hydrodynamic emitter located at the reactor inlet where a supersonic two-phase vapor-liquid flow under reduced pressure is formed in the liquid due to the pressure drop and decrease in the flow enthalpy. Electrodes are located in the reactor where an electric field is created using an external power source (the strength of the field exceeds the breakdown threshold of this two-phase medium) leading to theinitiation of a low-temperature glow quasi-stationary plasma discharge.A theoretical estimation of the parameters of this type of discharge has been carried out. It is shown that the lowtemperature plasma initiated under the flow conditions of a liquid-phase medium in the discharge gap between the electrodes can effectively decompose the hydrogen-containing molecules of organic compounds in a liquid with the formation of gaseous products where the content of hydrogen is more than 90%. In the process simulation, theoretical calculations of the voltage and discharge current were also made which are in good agreement with the experimental data. The reaction unit used in the experiments was of a volume of 50 ml and reaction capacity appeared to be about 1.5 liters of hydrogen per minute when using a mixture of oxygen-containing organic compounds as a raw material. During their decomposition in plasma, solid-phase products are also formed in insignificant amounts: carbon nanoparticles and oxide nanoparticles of discharge electrode materials.


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