scholarly journals Carbonic fluids in the Hamadi gold deposit, Sudan: origin and contribution to gold mineralization

2017 ◽  
Vol 54 (5) ◽  
pp. 494-511 ◽  
Author(s):  
Xi-hui Cheng ◽  
Jiu-hua Xu ◽  
Jian-xiong Wang ◽  
Qing-po Xue ◽  
Hui Zhang
Keyword(s):  
Gold Deposit ◽  
Melting Temperature ◽  
Fluid Inclusions ◽  
Gold Mineralization ◽  
Narrow Range ◽  
Shear Zones ◽  
Quartz Veins ◽  
Wide Range ◽  
Homogenization Temperatures ◽  
Gold Bearing

The Hamadi gold deposit is located in North Sudan, and occurs in the Neoproterozoic metamorphic strata of the Arabian–Nubian Shield. Two types of gold mineralization can be discerned: gold-bearing quartz veins and altered rock ores near ductile shear zones. The gold-bearing quartz veins are composed of white to gray quartz associated with small amounts of pyrite and other polymetallic sulfide minerals. Wall-rock alterations include mainly beresitization, epidotization, chloritization, and carbonatization. CO2-rich inclusions are commonly seen in gold-bearing quartz veins and quartz veinlets from gold-bearing altered rocks; these include mainly one-phase carbonic (CO2 ± CH4 ± N2) inclusions and CO2–H2O inclusions with CO2/H2O volumetric ratios of 30% to ∼80%. Laser Raman analysis does not show the H2O peak in carbonic inclusions. In quartz veins, the melting temperature of solid CO2 (Tm,CO2) of carbonic inclusions has a narrow range of −59.6 to −56.8 °C. Carbonic inclusions also have CO2 partial homogenization temperatures (Th,CO2) of −28.3 to +23.7 °C, with most of the values clustering between +4.0 and +20 °C; all of these inclusions are homogenized into the liquid CO2 state. The densities range from 0.73 to 1.03 g/cm3. XCH4 of carbonic fluid inclusions ranges from 0.004 to 0.14, with most XCH4 around 0.05. In CO2–H2O fluid inclusions, Tm,CO2 values are recorded mostly at around −57.5 °C. The melting temperature of clathrate is 3.8–8.9 °C. It is suggested that the lowest trapping pressures of CO2 fluids would be 100 to ∼400 MPa, on the basis of the Th,CO2 of CO2-bearing one-phase (LCO2) inclusions and the total homogenization temperatures (Th,tot) of paragenetic CO2-bearing two-phase (LCO2–LH2O) inclusions. For altered rocks, the Tm,CO2 of the carbonic inclusions has a narrow range of −58.4 to ∼−57.0 °C, whereas the Th,CO2 varies widely (−19 to ∼+29 °C). Most carbonic inclusions and the carbonic phases in the CO2–H2O inclusions are homogenized to liquid CO2 phases, which correspond to densities of 0.70 to ∼1.00 g/cm3. Fluid inclusions in a single fluid inclusion assemblage (FIA) have narrow Tm,CO2 and Th,CO2 values, but they vary widely in different FIAs and non-FIAs, which indicates that there was a wide range of trapping pressure and temperature (P–T) conditions during the ore-forming process in late retrograde metamorphism after the metamorphism peak period. The carbonic inclusions in the Hamadi gold deposit are interpreted to have resulted from unmixing of an originally homogeneous aqueous–carbonic mixture during retrogress metamorphism caused by decreasing P–T conditions. CO2 contributed to gold mineralization by buffering the pH range and increasing the gold concentration in the fluids.

scholarly journals Quartz Rb-Sr Isochron Ages of Two Type Orebodies from the Nibao Carlin-type Gold Deposit, Guizhou, China

Minerals ◽  
2019 ◽  
Vol 9 (7) ◽  
pp. 399 ◽  
Author(s):  
Zheng ◽  
Yang ◽  
Gao ◽  
Chen ◽  
Liu ◽  
...  
Keyword(s):  
Low Temperature ◽  
Gold Deposit ◽  
Fluid Inclusions ◽  
Large Scale ◽  
Gold Mineralization ◽  
Gold Deposits ◽  
Quartz Veins ◽  
Golden Triangle ◽  
Mineralization Age ◽  
Gold Bearing

The Nibao gold deposit, which includes both fault-controlled and strata-bound gold orebodies, constitutes an important part of the Yunnan–Guizhou–Guangxi “Golden Triangle” region. Defining the mineralization age of these gold orebodies may provide additional evidence for constraining the formation ages of low-temperature orebodies and their metallogenic distribution in South China. Petrographic studies of gold-bearing pyrites and ore-related quartz veins indicate that these pyrites coexist with quartz or filled in vein-like quartz, which suggests a possible genetic relationship between the two from Nibao gold deposit. Minerals chemistry shows that Rb and Sr are usually hosted in fluid inclusions in quartz ranging from 0.0786 to 2.0760 ppm and 0.1703 to 2.1820 ppm, respectively. The Rb–Sr isotopic composition of gold-bearing quartz-hosted fluid inclusions from the Nibao gold deposit were found to have Rb–Sr isochron ages of 142 ± 3 and 141 ± 2 Ma for both fault-controlled and strata-bound orebodies, respectively, adding more evidence to previous studies and thus revealing a regional gold mineralization age of 148–134 Ma. These results also confirm the Middle-Late Yanshanian mineralizing events of Carlin-type gold deposits in Yunnan, Guizhou, and Guangxi Provinces of Southwest China. In addition, previous studies indicated that antimony deposits in the region which were formed at ca. 148–126 Ma have a close affinity with gold deposits. This illustrates that the regional low-temperature hydrothermal gold mineralization is related in space and time to the Yanshanian (ca. 146–115 Ma) magmatic activity. Specifically, the large-scale gold and antimony mineralization are considered to be inherently related to mantle-derived mafic and ultramafic magmatic rocks associated with an extensional tectonic environment. Based on the initial 87Sr/86Sr ratios of 0.70844 ± 0.00022 (2σ) and 0.70862 ± 0.00020 (2σ) for gold-bearing quartz veins from fault-controlled and strata-bound gold orebodies, respectively, at the Nibao gold deposit, as well as the C, H, O, and S isotopic characteristics of gold deposits located in the Golden Triangle region, we suggest that the mantle-derived material can be involved in the formation of the Nibao gold deposit and that the ore-forming fluid can be derived from a mixed crust–mantle source.

scholarly journals Ore-Fluid Evolution of the Sizhuang Orogenic Gold Deposit, Jiaodong Peninsula, China

Minerals ◽  
2019 ◽  
Vol 9 (3) ◽  
pp. 190 ◽  
Author(s):  
Yu-Ji Wei ◽  
Li-Qiang Yang ◽  
Jian-Qiu Feng ◽  
Hao Wang ◽  
Guang-Yao Lv ◽  
...  
Keyword(s):  
Fluid Inclusion ◽  
Gold Deposit ◽  
Late Stage ◽  
Gold Mineralization ◽  
Early Stage ◽  
Main Stage ◽  
Jiaodong Peninsula ◽  
Wide Range ◽  
Homogenization Temperatures

The Sizhuang gold deposit with a proven gold resource of >120 t, located in northwest Jiaodong Peninsula in China, lies in the southern part of the Jiaojia gold belt. Gold mineralization can be divided into altered rock type, auriferous quartz vein type, and sulfide-quartz veinlet in K-feldspar altered granite. According to mineral paragenesis and mineral crosscutting relationships, three stages of metal mineralization can be identified: early stage, main stage, and late stage. Gold mainly occurs in the main stage. The petrography and microthermometry of fluid inclusion shows three types of inclusions (type 1 H2O–CO2 inclusions, type 2 aqueous inclusions, and type 3 CO2 inclusions). Early stage quartz-hosted inclusions have a trapped temperatures range 303–390 °C. The gold-rich main stage contains a fluid-inclusion cluster with both type 1 and 2 inclusions (trapped between 279 and 298 °C), and a wide range of homogenization temperatures of CO2 occurs to the vapor phase (17.6 to 30.5 °C). The late stage calcite only contains type 1 inclusions with homogenization temperatures between 195 and 289 °C. With evidences from the H–O isotope data and the study of water–rock interaction, the metamorphic water of the Jiaodong Group is considered to be the dominating source for the ore-forming fluid. The ore-fluid belonged to a CO2–H2O–NaCl system with medium-low temperature (160–360 °C), medium-low salinity (3.00–11.83 wt% NaCl eq.), and low density (1.51–1.02 g/cm3). Fluid immiscibility caused by pressure fluctuation is the key mechanism in inducing gold mineralization in the Sizhuang gold deposit.

scholarly journals Metamorphic rock-hosted orogenic gold deposit style at Bombana (Southeast Sulawesi) and Buru Island (Maluku): Their key features and significances for gold exploration in Eastern Indonesia

2017 ◽  
Vol 2 (2) ◽  
pp. 124 ◽  
Author(s):  
Arifudin Idrus ◽  
Sukamandaru Prihatmoko ◽  
Ernowo Harjanto ◽  
Franz Michael Meyer ◽  
Irzal Nur ◽  
...  
Keyword(s):  
Fluid Inclusions ◽  
Metamorphic Rock ◽  
Gold Mineralization ◽  
Gold Deposits ◽  
High Grade ◽  
Quartz Veins ◽  
Gold Exploration ◽  
Eastern Indonesia ◽  
Key Features ◽  
Gold Bearing

In Indonesia, gold is commonly mined from epithermal-, porphyry-, and skarn-type deposits that are commonly found in volcanic belts along island arcs or active continental margin settings. Numerous gold prospects, however, were recently discovered in association with metamorphic rocks. This paper focuses on metamorphic rock-hosted gold mineralization in Eastern Indonesia, in particular the Bombana (SE Sulawesi) and Buru Island (Maluku) prospects. At Bombana, gold-bearing quartz-veins are hosted by the Pompangeo metamorphic complex. Sheared, segmented veins vary in thickness from 2 cm to 2 m. Gold is mainly present in the form of ‘free gold’ among silicate minerals and closely related to cinnabar, stibnite, tripuhyite, and in places, minor arsenopyrite. The gold distribution is erratic, however, ranging from below detection limit up to 134 g/t. At least three generations of veins are identified. The first is parallel to the foliation, the second crosscuts the first generation of veins as well as the foliation, and the late-stage laminated deformed quartz-calcite vein represents the third mineralization stage. The early veins are mostly massive to crystalline, occasionally brecciated, and sigmoidal, whereas the second-stage veins are narrower than the first ones and less subjected to brecciation. Gold grades in the second- and third-stage veins are on average higher than that in the earlier veins. Microthermometric and Raman spectrometric studies of fluid inclusions indicate abundant H2O-NaCl and minor H2O-NaCl-CO2 fluids. Homogenization temperatures and salinities vary from 114 to 283 ºC and 0.35 to 9.08 wt.% NaCl eq., respectively. Crush-leach analysis of fluid inclusions suggests that the halogen fluid chemistry is not identical to sea water, magmatic or epithermal related fluids, but tends to be similar to fluids in mesothermal-type gold deposits. In Buru Island (Gunung Botak and Gogorea prospects), two distinct generations of quartz veins are identified. Early quartz veins are segmented, sigmoidal discontinuous and parallel to the foliation of the host rock. This generation of quartz veins is characterized by crystalline relatively clear quartz, and weakly mineralized with low sulfide and gold contents. The second type of quartz veins occurs within the ‘mineralized zone’ of about 100 m in width and ~1,000 m in length. Gold mineralization is intensely overprinted by argillic alteration. The mineralization-alteration zone is probably parallel to the mica schist foliation and strongly controlled by N-S or NE-SW-trending structures. Gold-bearing quartz veins are characterized by banded texture particularly following host rock foliation and sulphide banding, brecciated and rare bladed-like texture. Alteration types consist of propylitic (chlorite, calcite, sericite), argillic and carbonation represented by graphite banding and carbon flakes. Ore mineral comprises pyrite, native gold, pyrrhotite, and arsenopyrite. Cinnabar and stibnite are present in association with gold. Ore chemistry indicates that 11 out of 15 samples yielded more than 1 g/t Au, in which 6 of them graded in excess of 3 g/t Au. All high-grade samples are composed of limonite or partly contain limonitic material. This suggests the process of supergene enrichment. Interestingly, most of the high-grade samples contain also high concentrations of As (up to 991ppm), Sb (up to 885ppm), and Hg (up to 75ppm). Fluid inclusions in both quartz vein types consist of 4 phases including L-rich, V-rich, L-V-rich and L1-L2-V (CO2)-rich phases. The mineralizing hydrothermal fluid typically is CO2-rich, of moderate temperature (300-400 ºC), and low salinity (0.36 to 0.54 wt.% NaCl eq). Based on those key features, gold mineralization in Bombana and Buru Island tends to meet the characteristics of orogenic, mesothermal types of gold deposit. Metamorphic rock-hosted gold deposits could represent the new targets for gold exploration particularly in Eastern Indonesia.

The Saidu Gold Deposit of Southern Altai, China: Mineralizing Stages and Ore-Forming Fluids Evolution

2013 ◽  
Vol 734-737 ◽  
pp. 215-218
Author(s):  
Guo Rui Zhang ◽  
Jiu Hua Xu ◽  
Li Hua Shan ◽  
Hui Zhang ◽  
Xiao Feng Wei
Keyword(s):  
Gold Deposit ◽  
Gold Mineralization ◽  
Early Stage ◽  
Shear Zones ◽  
Ductile Shear Zone ◽  
Tectonic Zone ◽  
Low Salinity ◽  
Ore Bodies ◽  
Evolution Characteristics ◽  
Homogenization Temperatures

The Saidu gold deposit is located in the northwest part of Ertix Tectonic Zone in Xinjiang. The ore bodies occur in altered mylonite zones within the Mar-kakol giant fault zone and are controlled by the ductile shear zone. The structural-metallogenic fluids of the early stage are characterized by mesothermal-hydrothermal CO2-N2-rich fluids, with homogenization temperatures of fluid inclusions being 252~408°C. The tectonic-metallogenic fluids at the middle stage are characterized by CO2-H2O fluids, with homogenization temperatures being 203~326°C. The fluids at the late stage were epithermal-mesothermal low salinity aqueous solutions, with homogenization temperatures being 120~221°C. The main gold mineralization was related to the post-orogenic extension environment, with the evolution characteristics corresponding to the evolution of shear zones.

scholarly journals Origin and Characteristics of the Shwetagun Deposit, Modi Taung-Nankwe Gold District and the Kunzeik and Zibyaung Deposits, Kyaikhto Gold District in Mergui Belt, Myanmar: Implications for Fluid Source and Orogenic Gold Mineralization

2021 ◽  
Vol 9 ◽  
Author(s):  
Myo Kyaw Hlaing ◽  
Kotaro Yonezu ◽  
Khin Zaw ◽  
Aung Zaw Myint ◽  
May Thwe Aye ◽  
...  
Keyword(s):  
Native Gold ◽  
Gold Mineralization ◽  
Shear Zones ◽  
Wall Rock ◽  
Gold Deposits ◽  
Orogenic Gold ◽  
Salinity Range ◽  
Quartz Veins ◽  
Economic Significance ◽  
Gold Bearing

The Mergui Belt of Myanmar is endowed with several important orogenic gold deposits, which have economic significance and exploration potential. The present research is focused on two gold districts, Modi Taung-Nankwe and Kyaikhto in the Mergui Belt comparing their geological setting, ore and alteration mineralogy, fluid inclusion characteristics, and ore-forming processes. Both of the gold districts show similarities in nature and characteristics of gold-bearing quartz veins occurring as sheeted veins, massive veins, stockworks to spider veinlets. These gold deposits are mainly hosted by the mudstone, slaty mudstone, greywacke sandstone, slate, and slaty phyllite of Mergui Group (dominantly of Carboniferous age). The gold-bearing quartz veins generally trend from NNE to N-S, whereas some veins strike NW-SE in all deposits. The gold-bearing quartz veins are mainly occurred within the faults and shear zones throughout the two gold districts. Wall-rock alterations at Shwetagun are mainly silicification, chloritization, and sericitization, whereas in Kyaikhto, silicification, carbonation, as well as chloritization, and sericitization are common. At Shwetagun, the gold occurred as electrum grains in fractures within the veins and sulfides. In Kyaikhto, the quartz-carbonate-sulfide and quartz-sulfide veins appeared to have formed from multiple episodes of gold formation categorizing mainly as free native gold grains in fractures within the veins or invisible native gold and electrum within sulfides. At Shwetagun, the ore minerals in the auriferous quartz veins include pyrite, galena, and sphalerite, with a lesser amount of electrum, chalcopyrite, arsenopyrite, chlorite, and sericite. In Kyaikhto, the common mineralogy associated with gold mineralization is pyrite, chalcopyrite, sphalerite, galena, pyrrhotite, arsenopyrite, marcasite, magnetite, hematite, ankerite, calcite, chlorite, epidote, albite, and sericite. At Shwetagun, the mineralization occurred at a varying temperature from 250 to 335°C, with a salinity range from 0.2 to 4.6 wt% NaCl equivalent. The Kyaikhto gold district was formed from aqueous–carbonic ore fluids of temperatures between 242 and 376°C, low to medium salinity (<11.8 wt% NaCl equivalent), and low CO2 content. The ore-forming processes of the Shwetagun deposit in the Modi Taung-Nankwe gold district and the Kyaikhto gold district are remarkably comparable to those of the mesozonal orogenic gold systems.

scholarly journals Re–Os Pyrite Geochronological Evidence of Three Mineralization Styles within the Jinchang Gold Deposit, Yanji–Dongning Metallogenic Belt, Northeast China

Minerals ◽  
2018 ◽  
Vol 8 (10) ◽  
pp. 448 ◽  
Author(s):  
Shun-Da Li ◽  
Zhi-Gao Wang ◽  
Ke-Yong Wang ◽  
Wen-Yan Cai ◽  
Da-Wei Peng ◽  
...  
Keyword(s):  
Gold Deposit ◽  
Northeast China ◽  
Gold Mineralization ◽  
Metallogenic Belt ◽  
Isotopic Analyses ◽  
Mantle Sources ◽  
Stage 1 ◽  
Geochronological Evidence ◽  
Gold Bearing

The Jinchang gold deposit is located in the eastern Yanji–Dongning Metallogenic Belt in Northeast China. The orebodies of the deposit are hosted within granite, diorite, and granodiorite, and are associated with gold-mineralized breccia pipes, disseminated gold in ores, and fault-controlled gold-bearing veins. Three paragenetic stages were identified: (1) early quartz–pyrite–arsenopyrite (stage 1); (2) quartz–pyrite–chalcopyrite (stage 2); and (3) late quartz–pyrite–galena–sphalerite (stage 3). Gold is hosted predominantly within pyrite. Pyrite separated from quartz–pyrite–arsenopyrite cement within the breccia-hosted ores (Py1) yield a Re–Os isochron age of 102.9 ± 2.7 Ma (MSWD = 0.17). Pyrite crystals from the quartz–pyrite–chalcopyrite veinlets (Py2) yield a Re–Os isochron age of 102.0 ± 3.4 Ma (MSWD = 0.2). Pyrite separated from quartz–pyrite–galena–sphalerite veins (Py3) yield a Re–Os isochron age of 100.9 ± 3.1 Ma (MSWD = 0.019). Re–Os isotopic analyses of the three types of auriferous pyrite suggest that gold mineralization in the Jinchang Deposit occurred at 105.6–97.8 Ma (includes uncertainty). The initial 187Os/188Os values of the pyrites range between 0.04 and 0.60, suggesting that Os in the pyrite crystals was derived from both crust and mantle sources.

Microthermometric and stable isotopic (O and H) characteristics of fluid inclusions in the porphyry related Çöpler (İliç - Erzincan) gold deposit, central eastern Turkey

2014 ◽  
Vol 6 (2) ◽  
Author(s):  
Oktay Canbaz ◽  
Ahmet Gökce
Keyword(s):  
Gold Deposit ◽  
Fluid Inclusions ◽  
Native Gold ◽  
Homogenization Temperature ◽  
Early Mesozoic ◽  
Wide Range ◽  
Stable Isotopic ◽  
Water Field ◽  
Two Phases ◽  
Opaque Minerals

AbstractThe Çöpler gold deposit occurs within the stockwork of quartz hosted by the Çöpler granitoid (Eosen) and by surrounding metasediments of Keban metamorphic (Late Paleozoic - Early Mesozoic) and the Munzur limestones (Late Carboniferous - Early Cretaceous).Native gold accompanied by small amounts of chalcopyrite, pyrite, magnetite, maghemite, hematite, fahlerz, marcasite, bornite, galena, sphalerite, specular hematite, goethite, lepidochrosite and bravoitic pyrite within the stockwork ore veinlets. In addition, epidote (pistazite - zoisite), garnet, scapolite, chlorite, tremolite/actinolite, muscovite and opaque minerals were determined within the veinlets occurred in skarn zones.The study of fluid inclusions in quartz veinlets showed that the hydrothermal fluids contain CaCl2, MgCl2 and NaCl and the salinities of the two phases (L+V) inclusions range from 1.7 to 20.6% NaCl equivalent. Salinity values up to 44% were determined within the halite bearing three phases inclusions. Their homogenization temperature values have a wide range from 145.0 to 380.0°C, indicative of catathermal/hypothermal to epithermal conditions. The δ 18O and δD values of the fluid inclusion waters from the Çöpler granitoid correspond to those assigned to Primary Magmatic Water, those from the metasediments of Keban metamorphics fall outside of the Primary Magmatic and are within the Metamorphic Water field. A sample from a quartz vein within the skarn zone hosted by the Munzur limestones has a particularly low δD value.The results suggest that fluids derived from the granitoids were mixed with those derived from the metasediments of Keban metamorphics and the the Munzur limestones and resulting in quartz veinlets in these lithologies and the formation of stockwork ores. In view of the occurrence, the features described and processes envisaged for this study area may be applicable in similar settings.

scholarly journals Genesis of the Longmendian Ag–Pb–Zn Deposit in Henan (Central China): Constraints from Fluid Inclusions and H–C–O–S–Pb Isotopes

Geofluids ◽  
2020 ◽  
Vol 2020 ◽  
pp. 1-21
Author(s):  
Xinglin Chen ◽  
Yongjun Shao ◽  
Chunkit Lai ◽  
Cheng Wang
Keyword(s):  
Fluid Inclusions ◽  
Central China ◽  
Granitic Magma ◽  
Two Phase ◽  
Quartz Veins ◽  
The North ◽  
Granitic Magmatism ◽  
Polymetallic Sulfides ◽  
Homogenization Temperatures ◽  
Stage 1

The Longmendian Ag–Pb–Zn deposit is located in the southern margin of the North China Craton, and the mineralization occurs mainly in quartz veins, altered gneissic wallrocks, and minor fault breccias in the Taihua Group. Based on vein crosscutting relations, mineral assemblages, and paragenesis, the mineralization can be divided into three stages: (1) quartz–pyrite, (2) quartz–polymetallic sulfides, and (3) quartz–carbonate–polymetallic sulfides. Wallrock alteration can be divided into three zones, i.e., chlorite–sericite, quartz–carbonate–sericite, and silicate. Fluid inclusions in all Stage 1 to 3 quartz are dominated by vapor-liquid two-phase aqueous type (W-type). Petrographic and microthermometric analyses of the fluid inclusions indicate that the homogenization temperatures of Stages 1, 2, and 3 are 198–332°C, 132–260°C, and 97–166°C, with salinities of 4.0–13.3, 1.1–13.1, and 1.9–7.6 wt% NaCleqv, respectively. The vapor comprises primarily H2O, with some CO2, H2, CO, N2, and CH4. The liquid phase contains Ca2+, Na+, K+, SO42−, Cl−, and F−. The sulfides have δ34S=–1.42 to +2.35‰ and 208Pb/204Pb=37.771 to 38.795, 207Pb/204Pb=15.388 to 15.686, and 206Pb/204Pb=17.660 to 18.101. The H–C–O–S–Pb isotope compositions indicate that the ore-forming materials may have been derived from the Taihua Group and the granitic magma. The fluid boiling and cooling and mixing with meteoric water may have been critical for the Ag–Pb–Zn ore precipitation. Geological and geochemical characteristics of the Longmendian deposit indicate that the deposit is best classified as medium- to low-temperature intermediate-sulfidation (LS/IS) epithermal-type, related to Cretaceous crustal-extension-related granitic magmatism.

Gold-bismuth-telluride-sulphide assemblages at the Viceroy Mine, Harare-Bindura-Shamva greenstone belt, Zimbabwe

2008 ◽  
Vol 72 (4) ◽  
pp. 953-970 ◽  
Author(s):  
T. Oberthür ◽  
T. W. Weiser
Keyword(s):  
Native Gold ◽  
Gold Mineralization ◽  
Close Association ◽  
Shear Zones ◽  
Gold Deposits ◽  
Orogenic Gold ◽  
Main Stage ◽  
Melting Temperatures ◽  
Native Bismuth ◽  
Gold Bearing

AbstractGold mineralization at the Viceroy Mine is hosted in extensional veins in steep shear zones that transect metabasalts of the Archaean Arcturus Formation. The gold mineralization is generally made up of banded or massive quartz carrying abundant coarse arsenopyrite. However, most striking is a distinct suite of Au-Bi-Te-S minerals, namely joseite-A (Bi4TeS2), joseite-B (Bi4Te2S), hedleyite (Bi7Te3), ikunolite (Bi4S3), ‘protojoseite’ (Bi3TeS), an unnamed mineral (Bi6Te2S), bismuthinite (Bi2S3), native Bi, native gold, maldonite (Au2Bi), and jonassonite (AuBi5S4). The majority of the Bi-Te-S phases is characterized by Bi/(Se+Te) ratios of >1. Accordingly, this assemblage formed at reduced conditions at relatively low fS2 and fTe2. Fluid-inclusion thermometry indicates depositional temperatures of the main stage of mineralization of up to 342°C, in the normal range of mesothermal, orogenic gold deposits worldwide. However, melting temperatures of Au-Bi-Te phases down to at least 235°C (assemblage (Au2Bi + Bi + Bi7Te3)) imply that the Au-Bi-Te phases have been present as liquids or melt droplets. Furthermore, the close association of native gold, native bismuth and other Bi-Te-S phases suggests that gold was scavenged from the hydrothermal fluids by Bi-Te-S liquids or melts. It is concluded that a liquid/melt-collecting mechanism was probably active at Viceroy Mine, where the distinct Au-Bi-Te-S assemblage either formed late as part of the main, arsenopyrite-dominated mineralization, or it represents a different mineralization event, related to rejuvenation of the shear system. In either case, some of the gold may have been extracted from pre-existing, gold-bearing arsenopyrite by Bi-Te-S melts, thus leading to an upgrade of the gold ores at Viceroy. The Au-Bi-Te-S assemblage represents an epithermal-style mineralization overprinted on an otherwise mesothermal (orogenic) gold mineralization.

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