Geochemical and isotopic characteristics of Early Silurian clastic sequences in Antigonish Highlands, Nova Scotia, Canada: constraints on the accretion of Avalonia in the Appalachian – Caledonlde Orogen

1996 ◽  
Vol 33 (3) ◽  
pp. 379-388 ◽  
Author(s):  
J. Brendan Murphy ◽  
J. Duncan Keppie ◽  
Mary Pat Cude ◽  
Jarda Dostal ◽  
John W. F. Waldron

Avalonia is a terrane that accreted to Laurentia–Baltica during the development of the Appalachian–Caledonide Orogen. Interpretations of the timing of accretion have been constrained by comparing faunal affinities, overstep sequences, age and kinematics of inferred accretionary deformational events, and controversial paleomagnetic data. We show that the time of accretion of Avalonia may also be constrained by contrasts in the geochemical and isotopic signatures of its igneous rocks (which reflect the characteristics of the underlying continental basement and mantle) and sedimentary rocks (which reflect provenance). Early Silurian clastic sedimentary rocks of the Beechill Cove Formation, Antigonish Highlands, Nova Scotia, were deposited on Avalonian crust. The formation predominantly consists of approximately 80 m of siltstones and shales deposited in a nearshore environment and derived from the northeast. Their age is constrained by paleontological data and by directly underlying Late Ordovician – Early Silurian bimodal volcanic rocks that have typically Avalonian geochemical signatures. In comparison with typical Avalonian rocks, the Beechill Cove sediments are characterized by high SiO2, Ce/Yb, and initial 87Sr/86Sr, low Fe2O3, MgO, and TiO2, and strongly negative εNd(ur). These characteristics cannot be attributed to erosion of underlying Avalonian basement or coeval volcanic rocks and are consistent with derivation via significant transport from radiogenically enriched continental crust. εNd data are typical of Grenvillian basement compositions and suggest that the Beechill Cove sedimentary rocks were derived from an adjacent landmass with Grenvillian crust. The data, in conjunction with paleocontinental reconstructions and recent geochronological and structural data from the northern Appalachians, suggest that the Caledonide orogenic belt is the most likely source. Deposition of the Beechill Cove Formation is inferred to have occurred in an intracontinental basin associated with strike-slip tectonics during the oblique collision of the Avalon with Laurentia–Baltica.


1993 ◽  
Vol 30 (12) ◽  
pp. 2273-2282 ◽  
Author(s):  
J. Brendan Murphy ◽  
Deborah L. MacDonald

The Late Proterozoic (ca. 618–610 Ma) Georgeville Group of northern mainland Nova Scotia lies within the Avalon Composite Terrane and consists of subgreenschist- to greenschist-facies mafic and felsic volcanic rocks overlain by volcaniclastic turbidites that were deposited in an ensialic basin within a rifted volcanic arc. Geochronological data indicate that the volcanic and sedimentary rocks are coeval. The geochemical and isotopic signatures of the sedimentary rocks are attributed to erosion of the coeval Avalonian volcanic rocks that flank the basin and are consistent with synorogenic deposition. There is no evidence of significant chemical contribution from Avalonian basement.Knowledge of the tectonic setting facilitates the testing of published geochemical discriminant diagrams for clastic sedimentary rocks. Discrimination diagrams using ratios such as K2O/Na2O and Al2O3/(CaO + Na2O) give inconclusive results, probably due to elemental mobility during secondary processes. Plots involving MgO, TiO2, and Fe2O3 detect the chemical contribution of mafic detritus, give much tighter clusters of data, and plot between Aleutian- and Cascade-type arc-derived sediments, suggesting a moderate thickness of continental crust beneath the arc.The arc-related signature of the Georgeville sedimentary rocks is clearly recognizable on ternary plots involving inter-element ratios of high field strength elements (e.g., Ti–Y–Zr, Nb–Y–Zr, and Hf–Ta–Th) in which the samples plot as mixing trends between mafic and felsic end members. Diagrams of this type may have widespread application to tectonic discrimination of sedimentary rocks because in most suites these ratios are relatively insensitive to sedimentary and metamorphic processes.



1992 ◽  
Vol 29 (7) ◽  
pp. 1430-1447 ◽  
Author(s):  
J. A. Winchester ◽  
C. R. van Staal ◽  
J. P. Langton

An investigation of the geology and chemistry of the basic igneous rocks in the Elmtree and Belledune inliers in northern New Brunswick shows that the bulk of the Middle Ordovician rocks of the ophiolitic Fournier Group are best interpreted as the products of volcanism and sedimentation in an extensive ensimatic back-arc basin southeast of a volcanic arc. The oceanic back-arc-basin igneous rocks form the basement to renewed arc-related basaltic volcanism in late Middle to Late Ordovician time. The Fournier Group is separated from the structurally-underlying, shale-dominated Elmtree Formation of the Tetagouche Group by an extensive tectonic melange, which incorporates lenses of serpentinite, mafic volcanic rocks, and sedimentary rocks of both the Tetagouche and Fournier groups. The mafic volcanic rocks in the Elmtree Formation correlate best with those intercalated with the lithologically similar sediments of the Llandeilian–Caradocian Boucher Brook Formation in the northern Miramichi Highlands. The melange and the present structural amalgamation of the Tetagouche and Fournier groups result from closure of the marginal basin by northward-directed subduction at the end of the Ordovician. Most mafic suites in the Elmtree and Belledune inliers can be chemically correlated with similar suites in the northern Miramichi Highlands, showing that the two areas are not separated by a terrane boundary.



1987 ◽  
Vol 24 (4) ◽  
pp. 752-759 ◽  
Author(s):  
J. B. Murphy

Upper Ordovician to Lower Silurian rocks in the Antigonish Highlands consist of interlayered basalts, rhyodacites, arkoses, and conglomerates overlain by a thick sequence of marine clastic rocks and minor rhyolites. The stratigraphy documents a marine transgression. The volcanic rocks were deposited in a within-plate, continental, extensional environment. The basalts display alkalic and tholeiitic affinities, and the rhyodacites were formed by anatexis of the crust. The origin of the younger rhyolites is not clear: they are compositionally distinct from the rhyodacites but may be related to them as late-stage differentiates. At present, it is not possible to evaluate whether the tectonic setting and magmatic affinities are regionally or locally controlled.The geological history is very similar to that of Lower Silurian rocks immediately north of the Antigonish Highlands at Arisaig. In the simplest sense, this indicates these areas may have been juxtaposed prior to the Late Ordovician and limits cumulative post-Silurian movement on the boundary (Hollow) fault to about 40 km.



1974 ◽  
Vol 11 (9) ◽  
pp. 1325-1329 ◽  
Author(s):  
R. F. Cormier

The lower Paleozoic Browns Mountain Group of volcanic and sedimentary rocks underlies much of the Antigonish Highlands on the northern mainland of Nova Scotia. The rocks are apparently unfossiliferous and pre-Lower Silurian in age. Volcanic rocks belonging to the Keppoch Formation give a Rb–Sr whole-rock isochron age of 528 ± 40 m.y.; the indicated value for the initial ratio 87Sr/86Sr is 0.7032 ± 0.0020. The apparent stratigraphic age of the lower part of the Browns Mountain Group then is Cambrian with a middle Cambrian age favored.



GFF ◽  
2006 ◽  
Vol 128 (4) ◽  
pp. 311-320 ◽  
Author(s):  
Peter Dahlqvist ◽  
Leif Johansson ◽  
Ulf Söderlund


1987 ◽  
Vol 24 (6) ◽  
pp. 1175-1184 ◽  
Author(s):  
G. R. Dunning ◽  
B. F. Kean ◽  
J. G. Thurlow ◽  
H. S. Swinden

Volcanic groups of the Central Mobile Belt of the Newfoundland Appalachians have previously been subdivided into "early" and "late" arc sequences, separated in time by a quiescent Caradocian stage defined in some areas by fossil-bearing black shales.New U–Pb zircon ages of [Formula: see text] and 473 ± 2 Ma for rhyolites of the Buchans and Roberts Arm groups, respectively, show them to be correlative early Ordovician sequences. These ages serve to refute both the previous Rb–Sr whole-rock isochron ages of 447 Ma and the idea that these groups were "late arc" sequences. These new ages corroborate evidence from late Arenig – early Llanvirn conodonts in the Buchans Group and calibrate this fossil occurrence.A new U–Pb zircon age of 479 ± 3 Ma from plagiogranite of the Mansfield Cove Complex immediately west of the Roberts Arm Group shows that this plutonic body is only slightly older than the adjacent volcanic rocks and not Hadrynian as previously supposed. Local field relationships suggest this body may represent part of a disrupted ophiolite. It is coeval with the ophiolitic Annieopsquotch Complex along a strike to the south and may form part of a belt of rocks derived from early Ordovician ocean floor that is discontinuously exposed along the western boundary of the Buchans – Roberts Arm Belt.Zircons from rhyolite at the northeast termination of the Tulks Hill volcanics, part of the extensive Victoria Lake Group, give an age of [Formula: see text]. This dated sequence contains limestone previously dated as Llanvirn–Llandeilo by conodonts. This part of the group is therefore younger than the Buchans Group, and the designations "early" and "late" arc are not appropriate. The thrusting that juxtaposed these groups is no longer constrained to be of Silurian age but could have been middle to late Ordovician. Precambrian zircons included in the Victoria Lake Group rhyolite could have been incorporated from associated sedimentary rocks and suggest that the group may have formed in a tectonic setting transitional between oceanic and continental and received detritus from several sources.



1995 ◽  
Vol 132 (5) ◽  
pp. 485-501 ◽  
Author(s):  
J. D. Johnston ◽  
W. E. A. Phillips

AbstractThe Caledonides of the west of Ireland provide a well-exposed and well-mapped example of an oblique collision zone. The east-northeast trending Deer Park and Achill Beg Fault system is a crustal scale ductile sinistral strike-slip duplex of late Ordovician age, imbricating late Precambrian granulite facies lower crustal rocks, near eclogite facies supracrustal rocks, up to amphibolite facies Dalradian metasedimentary rocks and greenschist facies Cambro-Ordovician rocks. This fault system is correlated with a pre-Devonian component of the Highland Boundary Fault system in southern Scotland. In the Clew Bay area, the high pressure-low temperature facies metamorphic rocks, in tectonic contact with greenschist facies Cambro-Ordovician rocks, are together interpreted as an accretionary prism complex related to northwestward directed subduction. Both of these are allocthonous terrains with respect to the Dalradian terrane to the north (North West Mayo). To the south, the Cambro-Ordovician rocks docked with a probable Dalradian block containing ultramafic intrusives (Deer Park Complex) during the late Ordovician. The Deer Park Complex and South Mayo Trough linked earlier, during the Arenig.Silurian and Lower-Middle Devonian redbed successions sit unconformably on the metamorphic rocks. Deposition and deformation of these cover rocks was controlled by oblique strike-slip movements on the Leek Fault whose strike swings from west-northwest to north-northeast, following earlier basement trends, as it is traced eastwards from Clew Bay. The Leek Fault System may be correlated with the Leannan Fault of northwest Donegal, a splay of the Great Glen Fault system of central Scotland. East of Clew Bay, this sinistral shear generated local dilation on the more northerly trending bend of the Leek Fault. Lower and Middle Old Red Sandstone redbeds were developed here. The west-northwest trend of the Leek Fault in Clew Bay acted as a compressional bend during these sinistral movements and transpressional southwest directed thrusting developed in Silurian rocks. Post-Middle Old Red Sandstone pre-late Tournaisian dextral displacement on the Leek Fault reversed this pattern with transtension in Clew Bay allowing intrusion of small carbonated peridotite bodies into Silurian rocks and easterly directed thrusting of Middle Old Red Sandstone rocks east of the Bay on the transpressional north-south bend.A tectonic model for the region is presented here. This model involves a northwestward directed subduction system, 150 to 750 km of Arenig sinistral strike slip movement, and eastwards insertion of the Connemara block with formation of the Ordovician South Mayo Trough as a pull-apart basin. Subsequently, a further 130 to 650 km eastward displacement of rocks took place south of the Deer Park Fault in later Ordovician times. The magnitudes of these estimates are directly proportional to an assumed maximum wavelength of 1500 km for promontories on the original Laurentian margin, and using the current juxtaposition of terranes, a minimum wavelength of 300 km is inferred.



2017 ◽  
Vol 54 (1) ◽  
pp. 33-51 ◽  
Author(s):  
Dan-Cezar Dutuc ◽  
Georgia Pe-Piper ◽  
David J.W. Piper

Jurassic and Cretaceous sandstones in the Shelburne subbasin and Fundy Basin offshore Nova Scotia, are poorly known but are of current interest for petroleum exploration. The goal of this study is to determine the provenance of sandstones and shales, which will contribute to a better understanding of regional tectonics and paleogeography in the study area. Mineral and lithic clast chemistry was determined from samples from conventional cores and cuttings from exploration wells, using scanning electron microscopy and an electron microprobe. Whole-rock geochemical composition of shales was used to test the hypotheses regarding provenance of Mesozoic clastic sedimentary rocks in the SW Scotian Basin. Lower Jurassic clastic sedimentary rocks in the Fundy Basin contain magnetite, biotite, and chlorite, suggesting local supply from the North Mountain Basalt and Meguma Terrane, whereas pyrope and anthophyllite suggest small supply from distant sources. In the SW Scotian Basin, detrital minerals, lithic clasts, and shale geochemistry from Middle Jurassic to Early Cretaceous indicate a predominant Meguma Terrane source and transport by local rivers. Rare spinel and garnet grains of meta-ultramafic rocks, only in the Middle Jurassic at the Mohawk B-93 well, suggest minor supply from the rising Labrador rift, via the same river that transported distant sediments to the Fundy Basin. Lower Cretaceous sandstones from the Mohican I-100 well contain minor garnet, spinel, and tourmaline from meta-ultramafic rocks, characteristic of sediment supplied to the central Scotian Basin at that time. The dominant Meguma Terrane provenance precludes thick deep-water sandstones in the eastern part of the Shelburne subbasin, but the evidence of Middle Jurassic distant river supply through the Fundy Basin is encouraging for deep-water reservoir quality in the western part.



2010 ◽  
Vol 47 (10) ◽  
pp. 1347-1366 ◽  
Author(s):  
E. H. Brown ◽  
G. E. Gehrels ◽  
V. A. Valencia

The Chilliwack composite terrane in northwest Washington is part of an assemblage of mid-Paleozoic arc terranes extending from California to Alaska. Some terranes bear evidence of exotic origin, whereas others apparently formed proximal to western Laurentia, posing a complex problem in unraveling the Paleozoic accretionary history of the Cordillera. In our proposed broader definition, the Chilliwack composite terrane includes the volcanic and sedimentary East Sound and Chilliwack groups, and the plutonic and metamorphic Turtleback and Yellow Aster complexes. New zircon ages indicate that the plutonic and volcanic rocks are mutually related as parts of the same arc complex and that its inception was as old as Late Ordovician to Silurian, older than most other parts of the mid-Paleozoic terrane assemblage. Basement to the arc complex is a passive margin assemblage of metamorphosed quartzose sandstone and calc-silicate rock of the Yellow Aster Complex, bracketed in age by ca. 1000 Ma detrital zircons and 418 Ma intrusive rocks. This association of paragneiss basement and overlying and (or) intruding arc resembles that of older parts of the extensive Yukon–Tanana terrane in the northern Cordillera. Detrital zircon ages support a western Laurentian pericratonic origin for the paragneiss basement and the overlying arc. However, an early to mid-Paleozoic connection of this assemblage to the exotic outboard Alexander terrane is also indicated, based on (1) Mesoproterozoic and early Paleozoic detrital zircons in Devonian sedimentary rocks of the arc, and also in certain other pericratonic Devonian terranes and strata of the miogeocline; (2) Late Ordovician – Silurian igneous ages; and (3) an earliest Devonian or older metamorphic age of the basement paragneiss.



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