Methyl mercury in pristine and impounded boreal peatlands, Experimental Lakes Area, Ontario

2000 ◽  
Vol 57 (11) ◽  
pp. 2211-2222 ◽  
Author(s):  
A Heyes ◽  
T R Moore ◽  
J WM Rudd ◽  
J J Dugoua
Keyword(s):  
Surface Water ◽  
Methyl Mercury ◽  
Important Variable ◽  
Mehg Concentration ◽  
Experimental Lakes Area ◽  
Riparian Wetland ◽  
Near Surface ◽  
Boreal Peatlands ◽  
Northwestern Ontario ◽  
Peat Surface

Methyl mercury (MeHg) concentrations were measured in peat and peat porewater of pristine wetlands and an impounded riparian wetland at the Experimental Lakes Area in northwestern Ontario, Canada. In pristine wetlands, MeHg concentrations in peat ranged from 0.1 to 60 ng·g-1 and in peat porewater from 0.02 (the detection limit) to 7.3 ng·L-1, with higher concentrations in wetlands that received upland runoff. Impoundment increased the average MeHg concentration in the near-surface peat porewater from 0.2 to 1.0 ng·L-1. As the increase was most dramatic near the peat - surface water interface, we suggest that the elevated MeHg concentrations resulted from an increase in net MeHg production associated with the decomposition of inundated vegetation. Impoundment increases the area of potential Hg methylation by imposing anoxia over the entire wetland surface and by facilitating the exchange of nutrients and MeHg between the peat surface and the surface water. No clear chemical control on MeHg concentration was observed among the pristine wetlands or in the impounded wetland. However, in laboratory incubations of peat, porewater MeHg concentration increased upon the addition of sulfate. We propose that sulfate availability is an important variable in Hg methylation in pristine northern wetlands.

Methyl mercury in aquatic insects from an experimental reservoir

1998 ◽  
Vol 55 (9) ◽  
pp. 2036-2047 ◽  
Author(s):  
B D Hall ◽  
D M Rosenberg ◽  
A P Wiens
Keyword(s):  
Aquatic Insects ◽  
Methyl Mercury ◽  
Fold Increase ◽  
Fish Tissue ◽  
Functional Feeding Groups ◽  
Experimental Lakes Area ◽  
Major Pathway ◽  
Natural Lakes ◽  
Northwestern Ontario ◽  
Before And After

Our objective was to study the effects of experimental flooding of a small wetland lake on the methyl mercury (MeHg) concentrations in aquatic insects and to compare MeHg concentrations in insects with those in water and fish from the same system. Insects were collected from the shorelines of the experimental reservoir before and after flooding, an undisturbed wetland lake, and an oligotrophic lake, all in the Experimental Lakes Area in northwestern Ontario. Samples were identified to the lowest possible taxon and categorized into functional feeding groups (FFGs; predators or collector/shredders). The insects were analyzed for MeHg and total Hg using clean techniques. Contamination was not a problem because levels of MeHg in insects were much higher than background concentrations. Odonata, Corixidae, Gerridae, Gyrinidae, and Phryganeidae/Polycentropodidae exhibited increases in MeHg concentrations in response to flooding. When data were grouped into FFGs, increases were observed in predators. There were insufficient numbers of collector/shredders collected to make a definitive conclusion on MeHg increases. Predators exhibited an approximately threefold increase in MeHg concentrations after flooding compared with a 20-fold increase in water concentrations and a four- to five-fold increase in fish concentrations. Trends in MeHg concentrations in aquatic insects from reservoirs and natural lakes in Finland and northern Québec were similar to ours. Evidence of an increase in MeHg concentrations in the lower food web helps explain increases in MeHg concentrations in fish from reservoirs because food is the major pathway of MeHg uptake in fish tissue.

Measurements of Specific Rates of Net Methyl Mercury Production in the Water Column and Surface Sediments of Acidified and Circumneutral Lakes

1987 ◽  
Vol 44 (4) ◽  
pp. 750-757 ◽  
Author(s):  
Luying Xun ◽  
N. E. R. Campbell ◽  
John W. M. Rudd
Keyword(s):  
Water Column ◽  
Water Samples ◽  
Methyl Mercury ◽  
Lake Acidification ◽  
Sediment Surface ◽  
Mercury Methylation ◽  
Experimental Lakes Area ◽  
Northwestern Ontario ◽  
Decreasing Ph ◽  
Mercury Production

Specific rates of mercury methylation and demethylation were determined for water and surficial sediment samples taken from several lakes located in the Experimental Lakes Area, northwestern Ontario. Specific rates of mercury methylation were found to increase with decreasing pH in epilimnetic water samples in which pH was adjusted prior to incubation and in epilimnetic water samples taken from lakes of different pH. Reduction of pH also increased methyl mercury production at the sediment surface. Both increases and decreases in pH reduced specific rates of mercury demethylation. However, these changes were smaller than for methylation. Proportionally, specific rates of methylation increased faster than increasing concentrations of Hg2+, while specific rates of mercury demethylation increased linearly with increasing concentrations of methyl mercury. Overall, this study predicts that the net rate of methyl mercury production in the water column and at the sediment–water surface will increase as a result of lake acidification, and this may at least partially explain why the mercury concentration of fish appears to increase during lake acidification.

The Effect of pH on Methyl Mercury Production and Decomposition in Lake Sediments

1985 ◽  
Vol 42 (4) ◽  
pp. 685-692 ◽  
Author(s):  
P. S. Ramial ◽  
John W. M Rudd ◽  
Akira Furutam ◽  
Luying Xun
Keyword(s):  
Lake Sediments ◽  
Methyl Mercury ◽  
Inorganic Mercury ◽  
Mercury Methylation ◽  
Surficial Sediments ◽  
Experimental Lakes Area ◽  
Effect Of Ph ◽  
Northwestern Ontario ◽  
Acidified Lakes ◽  
Mercury Production

Mercury methylation was measured in surficial sediments taken from unacidified and experimentally acidified lakes in the Experimental Lakes Area, northwestern Ontario. A reduction in the pH of sediments lowered the rate of 203Hg methylation. Methylation was undetectable at pH <5.0. This decrease in mercury methylation was probably related to a shortage of available inorganic mercury when the pH of the sediment porewater was reduced. Below pH 6.0, inorganic mercury concentrations in porewater, measured with 203Hg, were reduced to less than 20% of that found at unaltered pH. A comparison of methylation and demethylation rates was made at various pH's. The rate of demethylation decreased to a lesser extent than methylation as the pH was lowered. This research indicates that enhanced mercury methylation in the sediment is not responsible for the observed increase in mercury levels in fish from acidified lakes.

Changes in methyl mercury concentrations in zooplankton from four experimental reservoirs with differing amounts of carbon in the flooded catchmentsThis paper is part of the series “Forty Years of Aquatic Research at the Experimental Lakes Area”.

2009 ◽  
Vol 66 (11) ◽  
pp. 1910-1919 ◽  
Author(s):  
Britt D. Hall ◽  
Katharine A. Cherewyk ◽  
Michael J. Paterson ◽  
R. (Drew) A. Bodaly
Keyword(s):  
Food Web ◽  
Methyl Mercury ◽  
Dry Weight ◽  
Experimental Lakes Area ◽  
Organic C ◽  
Dissolved Organic C ◽  
Northwestern Ontario ◽  
Highly Correlated ◽  
Source Waters

Methyl mercury (MeHg) concentrations in zooplankton were compared from four experimental reservoirs at the Experimental Lakes Area in northwestern Ontario, Canada, to test the hypothesis that increases in concentrations of MeHg in zooplankton would be proportional to C availability. The experimental reservoirs included three upland reservoirs flooded between 1999 and 2003 that differed in amounts of flooded organic terrestrial C (high, medium, and low C) and an experimental reservoir created over a wetland–peatland complex in 1993. After flooding, MeHg in zooplankton increased from <100 ng·g dry weight–1 in inflow source waters to >500 ng·g dry weight–1 in all reservoirs. In the first two years of flooding, MeHg in zooplankton was not correlated with amounts of flooded C, but the rates of decline in mean annual concentrations were negatively correlated with the amount of C stored in flooded catchments. Concentrations of MeHg in zooplankton were highly correlated with MeHg concentrations in unfiltered water, with reductions in bioaccumulation associated with increases in dissolved organic C and decreases in pH. Overall, our results suggest that reservoir designs that minimize the amount of flooded terrestrial C should result in shorter periods of elevated MeHg in the food web.

scholarly journals Semi-Automatic Fractional Snow Cover Monitoring from Near-Surface Remote Sensing in Grassland

2021 ◽  
Vol 13 (11) ◽  
pp. 2045
Author(s):  
Anaí Caparó Bellido ◽  
Bradley C. Rundquist
Keyword(s):  
Snow Cover ◽  
Near Infrared ◽  
Accuracy Assessment ◽  
Important Variable ◽  
Field Station ◽  
Near Surface ◽  
Fractional Snow Cover ◽  
Rgb Images ◽  
Phenological Metrics

Snow cover is an important variable in both climatological and hydrological studies because of its relationship to environmental energy and mass flux. However, variability in snow cover can confound satellite-based efforts to monitor vegetation phenology. This research explores the utility of the PhenoCam Network cameras to estimate Fractional Snow Cover (FSC) in grassland. The goal is to operationalize FSC estimates from PhenoCams to inform and improve the satellite-based determination of phenological metrics. The study site is the Oakville Prairie Biological Field Station, located near Grand Forks, North Dakota. We developed a semi-automated process to estimate FSC from PhenoCam images through Python coding. Compared with previous research employing RGB images only, our use of the monochrome RGB + NIR (near-infrared) reduced pixel misclassification and increased accuracy. The results had an average RMSE of less than 8% FSC compared to visual estimates. Our pixel-based accuracy assessment showed that the overall accuracy of the images selected for validation was 92%. This is a promising outcome, although not every PhenoCam Network system has NIR capability.

scholarly journals An evaluation of water quality at Sandhill Wetland: implications for reclaiming wetlands above soft tailings deposits in northern Alberta, Canada

2021 ◽  
Author(s):  
Jeremy A. Hartsock ◽  
Jessica Piercey ◽  
Melissa K. House ◽  
Dale H. Vitt
Keyword(s):  
Water Quality ◽  
Electrical Conductivity ◽  
Surface Water ◽  
Water Chemistry ◽  
Water Quality Monitoring ◽  
Total Alkalinity ◽  
Near Surface ◽  
Water Quality Guidelines ◽  
Quality Guidelines ◽  
Annual Water

AbstractThe experimental Sandhill Wetland is the first permanent reclamation of a composite tailings deposit, and annual water quality monitoring is of specific interest for evaluating and predicting long-term reclamation performance. Here, we present water chemistry monitoring data obtained from Sandhill Wetland (years 2009–2019) and compare results to twelve natural reference wetlands and to environmental quality guidelines for Alberta surface waters. By comparing water quality at Sandhill Wetland and natural sites to established guidelines, we can begin to document the natural background water quality of wetlands in the region and examine if guideline exceedances are seen in natural undisturbed environments, or appear only at active reclamation sites. At Sandhill Wetland the dominant ions in near-surface water were bicarbonate, sulfate, chloride, sodium, calcium, and magnesium. Since the first growing season concentrations for these ions have increased annually, causing concurrent increases in electrical conductivity. In year 2019, water chemistry at Sandhill Wetland was most comparable to regional saline fens, systems that exhibit elevated electrical conductivity and high sodicity. Near-surface water at Sandhill Wetland exceeded water quality guidelines for three substances/properties (dissolved chloride, iron, and total alkalinity) in the most recent year of monitoring. The saline fen natural sites also exceeded water quality guidelines for the same chemical substances/properties, suggesting guideline exceedances are a norm for some natural wetland site types in the region. Of note, in each year of monitoring at Sandhill Wetland, dissolved organic compounds evaluated in sub- and near-surface water were below detection limits.

Land water linkages: influences of riparian deforestation on lake thermocline depth and possible consequences for cold stenotherms

1997 ◽  
Vol 54 (6) ◽  
pp. 1299-1305 ◽  
Author(s):  
Robert France
Keyword(s):  
Thermal Stratification ◽  
Lake Trout ◽  
Salvelinus Namaycush ◽  
Thermocline Depth ◽  
Experimental Lakes Area ◽  
Northwestern Ontario ◽  
Riparian Trees ◽  
Tree Removal ◽  
Riparian Tree ◽  
Land Water

The purpose of the present study was to determine if riparian deforestation would expose lake surfaces to stronger winds and therefore bring about deepening of thermoclines and resulting habitat losses for cold stenotherms such as lake trout (Salvelinus namaycush). Removal of protective riparian trees through wind blowdown and two wildfires was found to triple the overwater windspeeds and produce thermocline deepening in two lakes at the Experimental Lakes Area. A survey of thermal stratification patterns in 63 northwestern Ontario lakes showed that lakes around which riparian trees had been removed a decade before through either clearcutting or by a wildfire were found to have thermocline depths over 2 m deeper per unit fetch length compared with lakes surrounded by mature forests. Riparian tree removal will therefore exacerbate hypolimnion habitat losses for cold stenotherms that have already been documented to be occurring as a result of lake acidification, eutrophication, and climate warming.

Overburden geochemical signature of the Lac des Iles platinum group element deposit, northwestern Ontario, Canada

2007 ◽  
Vol 44 (8) ◽  
pp. 1151-1168 ◽  
Author(s):  
Peter J Barnett
Keyword(s):  
Mineral Exploration ◽  
Shallow Groundwater ◽  
Soil System ◽  
Near Surface ◽  
Rock Fragments ◽  
The North ◽  
Northwestern Ontario ◽  
Airborne Contamination ◽  
The Many ◽  
Lac Des Iles

Many previously published studies of the behaviour of Pt and Pd in till and soils have been done in areas of complex stratigraphy or very thin overburden cover, making the interpretation of soil results difficult because of the many variables associated with these settings. At the Lac des Iles mine site in northwestern Ontario, there are excellent exposures of the overburden in a series of exploration trenches. Glacial dispersal trains can be observed in till (C horizon) geochemistry (e.g., Ni, Cr, Cu, and Co). Regional geochemical dispersal trains of elements, such as Ni, Cr, Mg, and Co associated with the North Lac des Iles intrusion, can be detected for about 4 km beyond the western margin of the Mine Block intrusion. Entire dispersal trains range from 5 to 7 km in length and about 1 to 2 km in width. The dispersal of North Lac des Iles intrusion rock fragments tends to mask the response of the Mine Block intrusion. Dispersal trains of Pt and Pd are not well defined and tend to be very short, <1 km in length, due to the initial low concentrations of these elements in C-horizon till samples from the Lac Des Iles area. An exception to this is the Pd dispersal train originating from the high-grade zone that is up to 3 km long. Pd, Pt, Ni, and Cu appear to be moving both within and out of the soil system downslope into surface and shallow groundwater. It is suggested that these elements, to varying degrees, are moving in solution. Airborne contamination from mine operations of the humus has adversely affected the ability to determine the effectiveness of humus sampling for mineral exploration at Lac des Iles. The airborne contamination likely influences the geochemical results from surface water, shallow groundwater, and near-surface organic bog samples, particularly for the elements Pd and Pt.

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