Seasonal changes of dissolved organic carbon photo-oxidation rates in a tropical humic lagoon: the role of rainfall as a major regulator

2007 ◽  
Vol 64 (9) ◽  
pp. 1266-1272 ◽  
Author(s):  
Albert Luiz Suhett ◽  
André Megali Amado ◽  
Alex Enrich-Prast ◽  
Francisco de Assis Esteves ◽  
Vinicius Fortes Farjalla
Keyword(s):  
Organic Carbon ◽  
Dissolved Organic Carbon ◽  
Rainy Season ◽  
Annual Rainfall ◽  
Rainfall Regime ◽  
Photo Oxidation ◽  
Oxidation Rates ◽  
Doc Concentration ◽  
In The Beginning

In this paper, we report the seasonal variation of photo-oxidation rates in a tropical humic lagoon and its relation to annual rainfall regime. Photo-oxidation rates ranged from 8.96 to 415.06 µmol C·L–1·day–1, being higher in the beginning to middle of the rainy season and declining throughout the year. Although dissolved organic carbon (DOC) concentration, water color, and sunlight incidence were generally higher in the rainy season, photo-oxidation rates were not significantly related to any of these parameters. Photo-oxidation seems to be influenced mainly by changes in DOC photoreactivity, which was up to threefold higher early in the rainy season, when inputs of fresh allochthonous DOC take place. In the following months, in addition to being continuously degraded by sunlight, DOC is also removed from the water column by processes such as microbial degradation and sedimentation, leading to a decline in DOC concentration and photoreactivity throughout the year until the next rainy season. Thus, the dynamics of DOC inputs caused by the rainfall regime in Comprida Lagoon lead to a yearly pulse of DOC photoreactivity and photo-oxidation rates. We believe this pulse model also fits other aquatic ecosystems subject to similar seasonal inputs of allochthonous DOC, although rainfall would not necessarily be the driving factor.

scholarly journals Three representative UK moorland soils show differences in decadal release of dissolved organic carbon in response to environmental change

2011 ◽  
Vol 8 (12) ◽  
pp. 3661-3675 ◽  
Author(s):  
M. I. Stutter ◽  
D. G. Lumsdon ◽  
A. P. Rowland
Keyword(s):  
Organic Carbon ◽  
Dissolved Organic Carbon ◽  
Environmental Change ◽  
Soil Properties ◽  
Process Models ◽  
Environmental Drivers ◽  
Specific Response ◽  
Soil C ◽  
Doc Concentration ◽  
Mineral Soils

Abstract. Moorland carbon reserves in organo-mineral soils may be crucial to predicting landscape-scale variability in soil carbon losses, an important component of which is dissolved organic carbon (DOC). Surface water DOC trends are subject to a range of scaling, transport and biotic processes that disconnect them from signals in the catchment's soils. Long-term soil datasets are vital to identify changes in DOC release at source and soil C depletion. Here we show, that moorland soil solution DOC concentrations at three key UK Environmental Change Network sites increased between 1993–2007 in both surface- and sub- soil of a freely-draining Podzol (48 % and 215 % increases in O and Bs horizons, respectively), declined in a gleyed Podzol and showed no change in a Peat. Our principal findings were that: (1) considerable heterogeneity in DOC response appears to exist between different soils that is not apparent from the more consistent observed trends for streamwaters, and (2) freely-draining organo-mineral Podzol showed increasing DOC concentrations, countering the current scientific focus on soil C destabilization in peats. We discuss how the key solubility controls on DOC associated with coupled physico-chemical factors of ionic strength, acid deposition recovery, soil hydrology and temperature cannot readily be separated. Yet, despite evidence that all sites are recovering from acidification the soil-specific responses to environmental change have caused divergence in soil DOC concentration trends. The study shows that the properties of soils govern their specific response to an approximately common set of broad environmental drivers. Key soil properties are indicated to be drainage, sulphate and DOC sorption capacity. Soil properties need representation in process-models to understand and predict the role of soils in catchment to global C budgets. Catchment hydrological (i.e. transport) controls may, at present, be governing the more ubiquitous rises in river DOC concentration trends, but soil (i.e. source) controls provide the key to prediction of future C loss to waters and the atmosphere.

scholarly journals The effect of dissolved organic carbon on pelagial and near-sediment water traits in lakes

2011 ◽  
Vol 74 (2) ◽  
pp. 133-139 ◽  
Author(s):  
Krzysztof Banaś
Keyword(s):  
Organic Carbon ◽  
Dissolved Organic Carbon ◽  
Redox Potential ◽  
Environmental Conditions ◽  
Calcium Concentration ◽  
Total Hardness ◽  
Sediment Layer ◽  
Ph Values ◽  
Doc Concentration ◽  
Good Transparency

The effect of dissolved organic carbon (DOC) on the environmental conditions of macrophytes has been studied in 35 lakes divided into soft- and hardwater: oligohumic (&lt;4.0 mg C dm<sup>-3</sup>), α-mesohumic (4.0-8.0 mg C dm<sup>-3</sup>), β-mesohumic (8.1-16.0 mg C dm<sup>-3</sup>) and polihumic (&gt;16.0 mg C dm<sup>-3</sup>). The optimum environmental conditions for macrophytes have been found in oligohumic lakes, characterised by low water colour and its good transparency. In soft- and hardwater lakes increasing concentration of DOC is accompanied with an increase in the colour (r=0.95), while the visibility decreases. With increasing DOC in the near-sediment layer the pH values decrease while the concentration of nitrogen increases and the concentration of phosphorus slightly increases. In hardwater lakes with increasing DOC concentration, the redox potential, conductivity, total hardness and calcium concentration in the near-sediment water decrease, whereas the content of CO<sup>2</sup> remains at a very low level.

scholarly journals Fluxes and retention of nutrients and organic carbon in Manko estuary, Okinawa, Japan: influence of river discharge variations

2014 ◽  
Vol 5 (2) ◽  
pp. 141 ◽  
Author(s):  
D. Shilla
Keyword(s):  
Organic Carbon ◽  
Dissolved Organic Carbon ◽  
River Water ◽  
Rainy Season ◽  
River Discharge ◽  
Geochemical Processes ◽  
Dissolved Nutrients ◽  
Transport And Transformation ◽  
Organic Nutrients ◽  
Annual Transport

Estuaries are often considered important filters for inorganic and organic nutrients, as they are located between the land and sea. This study reports on the fluvial fluxes and estuarine transformations and retention of dissolved nutrients (total oxidized nitrogen [TON = NO<sub>2</sub><sup>−</sup> and NO<sub>3</sub><sup>−</sup>]), NH<sub>4</sub><sup>+</sup>, PO<sub>4</sub><sup>3−</sup>, and dissolved organic carbon (DOC) in Manko estuary, Okinawa, Japan. The transport and transformation of dissolved nutrients and DOC varied widely among the eight conducted surveys due to variations in freshwater discharge and subsequent flushing times. Under high fluvial discharge, particularly during the May–June rainy season, the transport of nutrients and DOC accounted for up to 70%, 88%, 93%, and 53% of the annual transport of TON, NH<sub>4</sub><sup>+</sup>, PO<sub>4</sub><sup>3−</sup>, and DOC, respectively. The flushing times of river water into the estuary, which varied from 0.5 to 46 days, were important in determining the degree to which fluvial nutrients were transformed and retained within the estuary. The effect of long flushing times was evident during the dry months (December–March), when biological and geochemical processes within the estuary removed most of the fluvial nutrients and DOC.

The Role of Allochthonous Inputs of Dissolved Organic Carbon on the Hypolimnetic Oxygen Content of Reservoirs

Ecosystems ◽  
2008 ◽  
Vol 11 (7) ◽  
pp. 1035-1053 ◽  
Author(s):  
Rafael Marcé ◽  
Enrique Moreno-Ostos ◽  
Pilar López ◽  
Joan Armengol
Keyword(s):  
Organic Carbon ◽  
Dissolved Organic Carbon ◽  
Oxygen Content ◽  
Allochthonous Inputs ◽  
Hypolimnetic Oxygen

Humic Colloid Generation of Transuranic Elements in Groundwater and Their Migration Behaviour

1986 ◽  
Vol 84 ◽  
Author(s):  
J.I. Kim ◽  
G. Buckau ◽  
W. Zhuang
Keyword(s):  
Heavy Metal ◽  
Humic Acid ◽  
Organic Carbon ◽  
Dissolved Organic Carbon ◽  
Metal Ions ◽  
Fulvic Acid ◽  
Photoacoustic Spectroscopy ◽  
Heavy Metal Ions ◽  
Colloidal Form ◽  
Doc Concentration

AbstractThe generation of humic colloids of Am(III) has been investigated in Gorleben groundwaters containing different amounts of humic substances. Dissolved organic carbon (DOC) in these groundwaters consists mainly of humic acid and fulvic acid, which is present in a colloidal form through aggregation with trace heavy metal ions of groundwater constituents. Concentrations of these heavy metal ions are proportional to the DOC concentration. The generation of Am(III) pseudocolloids through geochemical interactions with humic colloids in different groundwaters is quantified by ultrafiltration as well as ultracentrifugation by the aid of radiometric concentration measurements. The speciation of dissolved Am(III) species in groundwaters is carried out by laser induced photoacoustic spectroscopy (LPAS).

scholarly journals Representation of dissolved organic carbon in the JULES land surface model (vn4.4_JULES-DOCM)

2018 ◽  
Vol 11 (2) ◽  
pp. 593-609 ◽  
Author(s):  
Mahdi Nakhavali ◽  
Pierre Friedlingstein ◽  
Ronny Lauerwald ◽  
Jing Tang ◽  
Sarah Chadburn ◽  
...  
Keyword(s):  
Organic Carbon ◽  
Dissolved Organic Carbon ◽  
Land Surface ◽  
Soil Column ◽  
River System ◽  
Terrestrial Ecosystems ◽  
Surface Model ◽  
Organic C ◽  
C Cycle ◽  
Doc Concentration

Abstract. Current global models of the carbon (C) cycle consider only vertical gas exchanges between terrestrial or oceanic reservoirs and the atmosphere, thus not considering the lateral transport of carbon from the continents to the oceans. Therefore, those models implicitly consider all of the C which is not respired to the atmosphere to be stored on land and hence overestimate the land C sink capability. A model that represents the whole continuum from atmosphere to land and into the ocean would provide a better understanding of the Earth's C cycle and hence more reliable historical or future projections. A first and critical step in that direction is to include processes representing the production and export of dissolved organic carbon in soils. Here we present an original representation of dissolved organic C (DOC) processes in the Joint UK Land Environment Simulator (JULES-DOCM) that integrates a representation of DOC production in terrestrial ecosystems based on the incomplete decomposition of organic matter, DOC decomposition within the soil column, and DOC export to the river network via leaching. The model performance is evaluated in five specific sites for which observations of soil DOC concentration are available. Results show that the model is able to reproduce the DOC concentration and controlling processes, including leaching to the riverine system, which is fundamental for integrating terrestrial and aquatic ecosystems. Future work should include the fate of exported DOC in the river system as well as DIC and POC export from soil.

Stability and aggregation of silver and titanium dioxide nanoparticles in seawater: Role of salinity and dissolved organic carbon

2014 ◽  
Vol 33 (5) ◽  
pp. 1023-1029 ◽  
Author(s):  
Huanhua Wang ◽  
Robert M. Burgess ◽  
Mark G. Cantwell ◽  
Lisa M. Portis ◽  
Monique M. Perron ◽  
...  
Keyword(s):  
Titanium Dioxide ◽  
Organic Carbon ◽  
Dissolved Organic Carbon ◽  
Titanium Dioxide Nanoparticles
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