Carbonyl Compounds in Salted Cod.: II. Separation and Identification of Volatile Monocarbonyl Compounds from Heavily Salted Cod

1965 ◽  
Vol 22 (1) ◽  
pp. 27-32 ◽  
Author(s):  
M. Yurkowski ◽  
M.A. Bordeleau
Keyword(s):  
Melting Point ◽  
Thin Layer ◽  
Thin Layer Chromatography ◽  
Chain Length ◽  
Carbonyl Compounds ◽  
Gadus Morhua ◽  
Unknown Compound ◽  
Layer Chromatography

Volatile monocarbonyl compounds were isolated from heavily salted cod (Gadus morhua) as the 2,4-dinitrophenylhydrazones. These compounds were separated by thin-layer chromatography first into classes and then according to chain length. n-Alkanals C1–5 and n-alk-2-enals C5–6 were conclusively identified. n-Alkanals C8,10 and n-alk-2-enals C4,7,8 were tentatively identified. An unknown compound corresponding to n-hexanal, except in the melting point, was isolated. Formaldehyde, and to a lesser extent, acetaldehyde and propanal, were the major monocarbonyls present in salted cod.

scholarly journals SINTESIS CALKON ((E)-1,3-DI(NAPHTHALEN-2-YL)PROP-2-EN-1-ONE) DAN AKTIVITASNYA SEBAGAI ANTIOKSIDAN

2012 ◽  
Vol 3 (1) ◽  
pp. 7-14
Author(s):  
Rahmiwati Hilma ◽  
Jasril ◽  
Hilwan Yuda Teruna
Keyword(s):  
Free Radical ◽  
Melting Point ◽  
Thin Layer ◽  
Thin Layer Chromatography ◽  
Room Temperature ◽  
Intermediate Compound ◽  
Alkaline Condition ◽  
Point Measurement ◽  
Anti Inflammatory ◽  
Layer Chromatography

Study on chalcone calkon (E)-1,3-di(naphthalen-2-yl)prop-2-en-1-one synthesis have been carried out with stirrer methode. These compounds can be used as intermediate compound to synthesize others compounds which was reported having antimicrobial, anti-inflammatory, anti-depressant, anti-tumour. The of chalcones synthesis vatives were reported in acid and alkali condition. In this study, chalcone and its derivates were synthesized by using stirrer method in alkaline condition in room temperature. the compounds subjected to somes analyses including melting point measurement, thin layer chromatography and HPLC. Scavenging free radical by using DPPH methode showed Scavenging free radical with LC50 >80 μg/ml min potent activity while the ascorbat acid LC50 89,79 μg/ml.

Alkylresorcinol Homologs in Pisum sativum L. Varieties

1999 ◽  
Vol 54 (1-2) ◽  
pp. 44-48 ◽  
Author(s):  
Robert Zarnowski ◽  
Arkadiusz Kozubek
Keyword(s):  
Pisum Sativum ◽  
Thin Layer ◽  
Thin Layer Chromatography ◽  
Chain Length ◽  
Homologous Series ◽  
Chromatographic Mobility ◽  
Fast Blue ◽  
Pisum Sativum L ◽  
Acetone Extracts ◽  
Layer Chromatography

Acetone extracts from the seeds of Pisum sativum L. sensu lato (Leguminoseae) separated by thin layer chromatography revealed the occurrence of hands with chromatographic mobility and color reaction with Fast Blue B characteristic for 1,3-dihydroxy-5-alkyIbenzenes. These polyketide metabolites have been isolated and identified by Spectroscopic means. The occurrence of homologous series of saturated (approximately 70%) and enoic (mono and diunsaturated) homologs with chain length of C15 to C25 has been revealed with C17 as the main homolog

Carbonyl Compounds in Salted Cod.: I. Thin-Layer Chromatography of Aliphatic Monocarbonyl 2,4-Dinitrophenylhydrazones

1965 ◽  
Vol 22 (1) ◽  
pp. 17-25 ◽  
Author(s):  
M. Yurkowski
Keyword(s):  
Thin Layer ◽  
Thin Layer Chromatography ◽  
Propylene Glycol ◽  
Silica Gel ◽  
Carbonyl Compounds ◽  
Two Dimensional ◽  
Layer Chromatography

Methods are described for the separation of 2,4-dinitrophenylhydrazones of normal aliphatic monocarbonyl compounds by thin-layer chromatography. Magnesia-cellulose thin-layer plates are used to separate mixtures of these compounds into classes (n-alkanals, n-alkan-2-ones, n-alk-2-enals, and n-alka-2,4-dienal). Propylene glycol- and petrolatum-impregnated silica gel plates were also used to separate each class into homologues. The former impregnant resolved the compounds with less than seven carbons and the latter with more than six carbons. Two-dimensional separation was accomplished by resolving a mixture of these compounds into classes on magnesia-cellulose in the first dimension and the classes into homologues on either petrolatumor propylene glycol-impregnated silica gel plates in the second dimension.

A PRACTICAL METHOD FOR ESTIMATION OF URINARY PREGNANEDIOL AND ALLOPREGNANEDIOL USING THIN LAYER CHROMATOGRAPHY

1965 ◽  
Vol 49 (1) ◽  
pp. 97-106 ◽  
Author(s):  
S. Sulimovici ◽  
B. Lunenfeld ◽  
M. C. Shelesnyak
Keyword(s):  
Melting Point ◽  
Thin Layer ◽  
Thin Layer Chromatography ◽  
Practical Method ◽  
Melting Point Determination ◽  
Uv Absorption Spectra ◽  
Infra Red ◽  
Point Determination ◽  
Layer Chromatography ◽  
Hydrolysis Of

ABSTRACT A method is described for the assay of urinary pregnanediol and allopregnanediol which employs acid hydrolysis of pregnanediol glucuronide, ascending thin-layer chromatography and spectrophotometric quantitation of the eluted pregnanediol and allopregnanediol. The reliability of the method was established by analysis of infra-red and UV absorption spectra, melting point determination, recovery experiments, duplicate assays and comparison with the Klopper method. The method has advantages in that it is rapid and requires small urine samples.

Sterols produced by Cryptotnonas ovata var. palustris

1968 ◽  
Vol 14 (8) ◽  
pp. 837-839 ◽  
Author(s):  
R. P. Collins ◽  
K. Kalnins
Keyword(s):  
Infrared Spectroscopy ◽  
Melting Point ◽  
Thin Layer ◽  
Thin Layer Chromatography ◽  
Mass Spectroscopy ◽  
Layer Chromatography

Cholesterol and stigmasterol were isolated from C. ovata var. palustris. The compounds were identified by thin-layer chromatography, mass spectroscopy, infrared spectroscopy, derivative formation, and melting point determinations.

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